Issue 39, 2023

Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity

Abstract

The doping of metal–organic frameworks (MOFs) with metal-ions has emerged as a powerful strategy for enhancing their catalytic performance. Doping allows for the tailoring of the electronic structure and local coordination environment of MOFs, thus imparting on them unique properties and enhanced functionalities. This frontier article discusses the impact of metal-ion doping on the electronic structure and local coordination of MOFs, highlighting the effects on their electrocatalytic properties in relation to the oxygen evolution reaction (OER). The fundamental mechanisms underlying these modifications are explored, while recent advances, challenges, and prospects in the field are discussed. In addition, experimental techniques that can be applied to tackle the realization of effective metal-ion doping of MOFs are also noted briefly.

Graphical abstract: Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity

Article information

Article type
Frontier
Submitted
27 júl. 2023
Accepted
10 sep. 2023
First published
25 sep. 2023

Dalton Trans., 2023,52, 13852-13857

Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity

N. K. Shrestha, S. A. Patil, A. S. Salunke, A. I. Inamdar, H. Kim and H. Im, Dalton Trans., 2023, 52, 13852 DOI: 10.1039/D3DT02405A

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