Issue 42, 2015

Enhanced CO2 capture capacities and efficiencies with N-doped nanoporous carbons synthesized from solvent-modulated, pyridinedicarboxylate-containing Zn-MOFs

Abstract

This paper describes the pyrolysis of pyridinedicarboxylate-containing Zn-based metal–organic frameworks (MOFs) to form nanoporous carbons with accessible N dopants to adsorb CO2. The optimal materials were synthesized using N-heterocycle additives to control the amount of coordinated DMF in the base MOF structure, thereby increasing its thermal stability prior to pyrolysis.

Graphical abstract: Enhanced CO2 capture capacities and efficiencies with N-doped nanoporous carbons synthesized from solvent-modulated, pyridinedicarboxylate-containing Zn-MOFs

Supplementary files

Article information

Article type
Communication
Submitted
28 apr. 2015
Accepted
12 jún. 2015
First published
12 jún. 2015

CrystEngComm, 2015,17, 8015-8020

Enhanced CO2 capture capacities and efficiencies with N-doped nanoporous carbons synthesized from solvent-modulated, pyridinedicarboxylate-containing Zn-MOFs

J. Kim, A. G. Oliver and J. C. Hicks, CrystEngComm, 2015, 17, 8015 DOI: 10.1039/C5CE00828J

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