Issue 9, 2024

Recent advances in lanthanide-based POMs for photoluminescent applications

Abstract

Since the first formation of the famous “Peacock–Weakley” anions [Ln(W5O18)2]8/9−, a steady stream of breakthroughs have been made in the chemistry of multitalented lanthanide (Ln)-based polyoxometalates (POMs) for their potentially desirable properties. In particular, LnIII ions are generally recognised as the “vitamins of the modern industry” owing to their ability to cover a wide emission range, endowing Ln-based POMs with great potential for versatile and diverse luminescence-related applications. In this frontier, we discuss the synthesis strategies and intramolecular energy transfer in Ln-based POM derivatives. Then, the progressive improvements achieved with Ln-based POMs in photoluminescence applications are highlighted, focusing mainly on luminescent and fluorescent probes. Finally, the challenges for Ln-based POM materials for photoluminescence applications are discussed.

Graphical abstract: Recent advances in lanthanide-based POMs for photoluminescent applications

Article information

Article type
Frontier
Submitted
30 nóv. 2023
Accepted
18 jan. 2024
First published
19 jan. 2024

Dalton Trans., 2024,53, 3949-3958

Recent advances in lanthanide-based POMs for photoluminescent applications

K. Zheng and P. Ma, Dalton Trans., 2024, 53, 3949 DOI: 10.1039/D3DT03999D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements