Issue 35, 2024

Supramolecular helix of an oligomeric azapeptide building block containing four β-turn structures

Abstract

Oligomers of benzoylalanine-based amidothioureas containing four β-turn structures spaced by meta-substituted benzenes were shown to undergo assembly in dilute CH3CN solution into supramolecular helices of enhanced supramolecular helicity, whereas those spaced by para-substituted benzene spacer(s) or those spaced by meta-substituted benzenes but with one or two β-turns exhibit a substantially decreased tendency of assembling.

Graphical abstract: Supramolecular helix of an oligomeric azapeptide building block containing four β-turn structures

Supplementary files

Article information

Article type
Communication
Submitted
30 sep. 2023
Accepted
11 mar. 2024
First published
11 mar. 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 4648-4651

Supramolecular helix of an oligomeric azapeptide building block containing four β-turn structures

Y. Zhao, X. Yan and Y. Jiang, Chem. Commun., 2024, 60, 4648 DOI: 10.1039/D3CC04859D

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