Issue 42, 2023

High Mg2+ conduction in three-dimensional pores of a metal–organic framework under organic vapors

Abstract

We report on high Mg2+ conduction in a metal–organic framework (MOF), UiO-66, under organic vapors. We prepared a Mg2+-containing MOF, UiO-66⊃{Mg(TFSI)2}1.0 (TFSI = bis(trifluoromethanesulfonyl)imide), including Mg2+ carriers in three-dimensional pores. The compound showed a superionic conductivity above 10−4 S cm−1 under MeCN and MeOH vapors.

Graphical abstract: High Mg2+ conduction in three-dimensional pores of a metal–organic framework under organic vapors

Supplementary files

Article information

Article type
Communication
Submitted
14 mar. 2023
Accepted
21 apr. 2023
First published
22 apr. 2023
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2023,52, 15313-15316

High Mg2+ conduction in three-dimensional pores of a metal–organic framework under organic vapors

K. Aoki, K. Kato and M. Sadakiyo, Dalton Trans., 2023, 52, 15313 DOI: 10.1039/D3DT00768E

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