Issue 35, 2023

Structural authentication of intermediates of mechanistic significance in palladium- and nickel-catalysed cross-couplings: case studies

Abstract

This article examines a selection of case studies that highlight key strategies that have enabled the structural authentication of important species that shed light on fundamental on-cycle intermediates in palladium- and nickel-catalysed C–C, C–N, and C–O cross-coupling reactions. Particular emphasis is placed on studies in which the structures of rather intractable intermediates have been confirmed unambiguously by X-ray crystallography, while also contextualising the mechanistic insights that these reports have contributed.

Graphical abstract: Structural authentication of intermediates of mechanistic significance in palladium- and nickel-catalysed cross-couplings: case studies

Article information

Article type
Highlight
Submitted
24 feb. 2023
Accepted
31 mar. 2023
First published
31 mar. 2023

Chem. Commun., 2023,59, 5144-5155

Structural authentication of intermediates of mechanistic significance in palladium- and nickel-catalysed cross-couplings: case studies

A. Olding, C. C. Ho, D. Maiti and A. C. Bissember, Chem. Commun., 2023, 59, 5144 DOI: 10.1039/D3CC00882G

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