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Abstract | Cited by

The structure of the commercially important polyvinylpyrrolidone–hydrogen peroxide complex can be understood by reference to the co-crystal structure of a hydrogen peroxide complex and its mixed hydrates of a two-monomer unit model compound, bisVP·2H2O2. The mixed hydrates involve selective water substitution into one of the two independent hydrogen peroxide binding sites.

Graphical abstract: Structure and hydration of polyvinylpyrrolidone–hydrogen peroxide

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