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Partially fluorinated MIL-101(Cr) shows high SO2 capture (up to 18.4 mmol g−1 at 298 K and up to 1 bar), chemical stability towards dry and humid SO2 and an outstanding cycling performance with facile regeneration. In situ DRIFT spectroscopy demonstrated the preferential adsorption sites within MIL-101(Cr)-4F(1%).

Graphical abstract: High and reversible SO2 capture by a chemically stable Cr(iii)-based MOF

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