Issue 7, 2019

Probing ring-opening pathways for efficient photocatalytic toluene decomposition

Abstract

The ring-opening process is the rate-determining step for photocatalytic decomposition of aromatic volatile organic compounds (VOCs). However, the ring-opening pathway has not been fully revealed, which enables efficient photocatalytic VOC degradation. Taking the photocatalytic toluene degradation as a typical case, the ring-opening pathway and regulation strategy were systematically investigated and proposed with an aim to regulate the rate-determining step and accelerate the reaction rates. Herein, BiOCl with tailored facets was designed as a model photocatalyst to clarify the mechanism of photocatalytic toluene degradation. Theoretical calculations and in situ DRIFTS technology were closely combined to dynamically predict and monitor the photocatalytic toluene degradation reactions. It is revealed that the lowest energy barrier was precisely located at the ring-opening of benzoic acid which was generated from toluene oxidation. This result implied that the benzyl must be fully oxidized to benzoic acid to elevate the ring-opening reaction rates. Moreover, the alternative charge arrangement on the {010} facet of BiOCl facilitated the benzyl oxidation and selectivity for benzoic acid ring-opening reactions, subsequently resulting in remarkably enhanced photocatalytic efficiency, exceeding that of the {001} facet by 100% towards toluene decomposition. This work demonstrates that probing and tailoring the ring-opening pathway are vital to increase the overall toluene decomposition efficiency and could provide new insights into the understanding of the photocatalytic reactions in VOC degradation.

Graphical abstract: Probing ring-opening pathways for efficient photocatalytic toluene decomposition

Supplementary files

Article information

Article type
Paper
Submitted
03 des. 2018
Accepted
15 jan. 2019
First published
16 jan. 2019

J. Mater. Chem. A, 2019,7, 3366-3374

Probing ring-opening pathways for efficient photocatalytic toluene decomposition

J. Li, X. Dong, G. Zhang, W. Cui, W. Cen, Z. Wu, S. C. Lee and F. Dong, J. Mater. Chem. A, 2019, 7, 3366 DOI: 10.1039/C8TA11627J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements