Issue 18, 2019

Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)] into [(NO)2Fe(η3-HCS2)]via reaction with CS2

Abstract

Reaction of compounds [(NO)2Fe(TMEDA)] and [BH4] affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)2Fe(η2-BH4)] (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS2 into DNIC [(NO)2Fe(η3-HCS2)], the first DNIC featuring both linear/bent NO ligands and Fe 3dz2-to-HCS2 π* backbonding interaction.

Graphical abstract: Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]− into [(NO)2Fe(η3-HCS2)]−via reaction with CS2

Supplementary files

Article information

Article type
Communication
Submitted
29 nóv. 2018
Accepted
04 jan. 2019
First published
05 jan. 2019

Dalton Trans., 2019,48, 5897-5902

Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)] into [(NO)2Fe(η3-HCS2)]via reaction with CS2

H. Huang, W. Ching, Y. Tseng, C. Chen and T. Lu, Dalton Trans., 2019, 48, 5897 DOI: 10.1039/C8DT04714F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements