Issue 14, 2018

Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

Abstract

Palladium-catalyzed regioselective electrocarboxylation of homostyrenyl acetates with CO2 has been successfully developed, providing α-aryl carboxylic acids with good selectivity and yield. In addition, the catalytic asymmetric carboxylation of cinnamyl acetate has been demonstrated, despite moderate enantioselectivity.

Graphical abstract: Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

Supplementary files

Article information

Article type
Research Article
Submitted
23 maí 2018
Accepted
15 jún. 2018
First published
22 jún. 2018

Org. Chem. Front., 2018,5, 2244-2248

Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

K. Jiao, Z. Li, X. Xu, L. Zhang, Y. Li, K. Zhang and T. Mei, Org. Chem. Front., 2018, 5, 2244 DOI: 10.1039/C8QO00507A

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