Issue 15, 2018

Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Abstract

Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.

Graphical abstract: Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Supplementary files

Article information

Article type
Communication
Submitted
31 okt. 2017
Accepted
04 jan. 2018
First published
04 jan. 2018

Chem. Commun., 2018,54, 1825-1828

Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

R. Nolla-Saltiel, A. M. Geer, W. Lewis, A. J. Blake and D. L. Kays, Chem. Commun., 2018, 54, 1825 DOI: 10.1039/C7CC08385H

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