Issue 6, 2017

Air-induced double addition of P(O)–H bonds to alkynes: a clean and practical method for the preparation of 1,2-bisphosphorylethanes

Abstract

An air-induced double addition of diphenyl phosphine oxide to various alkynes is reported. This reaction can proceed efficiently under metal- and solvent-free conditions, and is a clean and practically useful method for the preparation of the valuable 1,2-bisphosphorylethanes.

Graphical abstract: Air-induced double addition of P(O)–H bonds to alkynes: a clean and practical method for the preparation of 1,2-bisphosphorylethanes

Supplementary files

Article information

Article type
Communication
Submitted
24 nóv. 2016
Accepted
09 jan. 2017
First published
10 jan. 2017

Green Chem., 2017,19, 1502-1506

Air-induced double addition of P(O)–H bonds to alkynes: a clean and practical method for the preparation of 1,2-bisphosphorylethanes

H. Guo, A. Yoshimura, T. Chen, Y. Saga and L. Han, Green Chem., 2017, 19, 1502 DOI: 10.1039/C6GC03240K

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