Jump to main content
Jump to site search

Issue 7, 2017
Previous Article Next Article

Extended germa[N]pericyclynes: synthesis and characterization

Author affiliations

Abstract

We herein describe the syntheses and characterization of extended germa[N]pericyclynes, which are macrocycles composed of germanium–butadiyne units. The obtained novel extended germa[4]–[8]pericyclynes were characterized by X-ray crystallography, UV-Vis spectroscopy, fluorescence and phosphorescence emission spectroscopy, and cyclic voltammetry, and exhibited characteristic absorptions and emissions. Density functional theory (DFT) calculations suggested smaller HOMO–LUMO gap energy compared to that of general germapericyclynes.

Graphical abstract: Extended germa[N]pericyclynes: synthesis and characterization

Back to tab navigation

Supplementary files

Publication details

The article was received on 07 des. 2016, accepted on 16 jan. 2017 and first published on 30 jan. 2017


Article type: Paper
DOI: 10.1039/C6DT04633A
Citation: Dalton Trans., 2017,46, 2281-2288

  •   Request permissions

    Extended germa[N]pericyclynes: synthesis and characterization

    H. Tanimoto, T. Fujiwara, J. Mori, T. Nagao, Y. Nishiyama, T. Morimoto, S. Ito, K. Tanaka, Y. Chujo and K. Kakiuchi, Dalton Trans., 2017, 46, 2281
    DOI: 10.1039/C6DT04633A

Search articles by author

Spotlight

Advertisements