Issue 3, 2016

Achieving remarkable mechanochromism and white-light emission with thermally activated delayed fluorescence through the molecular heredity principle

Abstract

Achieving high contrast mechanochromism (Δλem,max > 100 nm) and white-light emission under mild conditions from a single compound with a simple structure is a great challenge. Herein, we report a novel dual-emissive compound, namely SCP, with an asymmetric molecular structure that fully inherits the photophysical properties of the parent molecules SC2 and SP2. SCP shows high contrast, linearly tunable mechanochromism and bright white-light emission arising from a combination of traditional fluorescence and thermally activated delayed fluorescence (TADF). The origin of the dual-emission for SCP was demonstrated based on the analysis of the white-emitting single crystals. In addition, a mechanism of luminochromism for SCP driven by the application of mechanical force is proposed. These observations present a rational design strategy for the development of high performance multi-functional materials for white-light emission.

Graphical abstract: Achieving remarkable mechanochromism and white-light emission with thermally activated delayed fluorescence through the molecular heredity principle

Supplementary files

Article information

Article type
Edge Article
Submitted
02 nóv. 2015
Accepted
20 des. 2015
First published
11 jan. 2016
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2016,7, 2201-2206

Achieving remarkable mechanochromism and white-light emission with thermally activated delayed fluorescence through the molecular heredity principle

B. Xu, Y. Mu, Z. Mao, Z. Xie, H. Wu, Y. Zhang, C. Jin, Z. Chi, S. Liu, J. Xu, Y. Wu, P. Lu, A. Lien and M. R. Bryce, Chem. Sci., 2016, 7, 2201 DOI: 10.1039/C5SC04155D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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