Issue 7, 2016

Selective complexation of di-n-hexylammonium salts by tailed porphyrin host

Abstract

Novel types of tailed porphyrins have been synthesized and characterized. The tail was coordinated intramolecularly to zinc porphyrin, leading to the formation of a cavity. In the cavity, tailed porphyrins formed a complex with di-n-hexylammonium salts. The binding affinities of the tailed porphyrins were studied by 1H NMR and UV-visible titration experiments. The selectivity of complexation was attributed to the induced fit and lipophilic interactions.

Graphical abstract: Selective complexation of di-n-hexylammonium salts by tailed porphyrin host

Supplementary files

Article information

Article type
Letter
Submitted
06 jan. 2016
Accepted
01 jún. 2016
First published
01 jún. 2016

New J. Chem., 2016,40, 5679-5682

Selective complexation of di-n-hexylammonium salts by tailed porphyrin host

H. Liu, J. Tu, C. Zhang, Q. Xiao, T. Wang and X. Ju, New J. Chem., 2016, 40, 5679 DOI: 10.1039/C6NJ00045B

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