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Issue 5, 2015
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Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

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Abstract

Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

Graphical abstract: Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

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Publication details

The article was received on 20 jan. 2015, accepted on 18 feb. 2015 and first published on 06 mar. 2015


Article type: Research Article
DOI: 10.1039/C5QI00010F
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Citation: Inorg. Chem. Front., 2015,2, 448-452

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    Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

    C. J. Stephenson, J. T. Hupp and O. K. Farha, Inorg. Chem. Front., 2015, 2, 448
    DOI: 10.1039/C5QI00010F

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