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Issue 9, 2015
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Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

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Abstract

A comparative study of the support effect in three different UiO-66-based MOFs – with TiIV supported as part of the node (UiO-66-Tiex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) – is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Tiex.

Graphical abstract: Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

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Supplementary files

Article information


Submitted
04 jún. 2015
Accepted
26 jún. 2015
First published
30 jún. 2015

Catal. Sci. Technol., 2015,5, 4444-4451
Article type
Paper
Author version available

Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

H. G. T. Nguyen, L. Mao, A. W. Peters, C. O. Audu, Z. J. Brown, O. K. Farha, J. T. Hupp and S. T. Nguyen, Catal. Sci. Technol., 2015, 5, 4444
DOI: 10.1039/C5CY00825E

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