Issue 9, 2015
From the journal:

Catalysis Science & Technology

Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide†

Huong Giang T. Nguyen,a   Lily Mao,a   Aaron W. Peters,a   Cornelius O. Audu,a   Zachary J. Brown,a   Omar K. Farha,*ab   Joseph T. Hupp*a  and  SonBinh T. Nguyen*a  

* Corresponding authors

a Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA
E-mail: stn@northwestern.edu

b Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 22254, Saudi Arabia

Abstract

A comparative study of the support effect in three different UiO-66-based MOFs – with TiIV supported as part of the node (UiO-66-Tiex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) – is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Tiex.

Graphical abstract: Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

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Article information

DOI
https://doi.org/10.1039/C5CY00825E
Article type
Paper
Submitted
04 jún. 2015
Accepted
26 jún. 2015
First published
30 jún. 2015

Catal. Sci. Technol., 2015,5, 4444-4451

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Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

H. G. T. Nguyen, L. Mao, A. W. Peters, C. O. Audu, Z. J. Brown, O. K. Farha, J. T. Hupp and S. T. Nguyen, Catal. Sci. Technol., 2015, 5, 4444 DOI: 10.1039/C5CY00825E

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