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Issue 9, 2015
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Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

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Abstract

A comparative study of the support effect in three different UiO-66-based MOFs – with TiIV supported as part of the node (UiO-66-Tiex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) – is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Tiex.

Graphical abstract: Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

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Publication details

The article was received on 04 jún. 2015, accepted on 26 jún. 2015 and first published on 30 jún. 2015


Article type: Paper
DOI: 10.1039/C5CY00825E
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Citation: Catal. Sci. Technol., 2015,5, 4444-4451

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    Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

    H. G. T. Nguyen, L. Mao, A. W. Peters, C. O. Audu, Z. J. Brown, O. K. Farha, J. T. Hupp and S. T. Nguyen, Catal. Sci. Technol., 2015, 5, 4444
    DOI: 10.1039/C5CY00825E

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