Issue 25, 2015

Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

Abstract

The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite 1(FeSe2) tetrahedral chains separated by Fe–amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.

Graphical abstract: Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

Supplementary files

Article information

Article type
Communication
Submitted
30 okt. 2014
Accepted
30 nóv. 2014
First published
01 des. 2014

Chem. Commun., 2015,51, 5355-5358

Author version available

Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

J. T. Greenfield, C. Pak, S. Kamali, K. Lee and K. Kovnir, Chem. Commun., 2015, 51, 5355 DOI: 10.1039/C4CC08608B

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