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Issue 3, 2014
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The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties

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Abstract

Two cyanide-bridged enantiopure one-dimensional single chain complexes, [Mn((R,R)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (1) and [Mn((S,S)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (2), have been synthesized and structurally characterized. Systematically magnetic investigations show the antiferromagnetic coupling between the cyanide-bridged Mn(III)–Fe(III) centers and the interesting metamagnetic behavior at about 5.0 K resulted from the intermolecular π–π interaction.

Graphical abstract: The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties

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Publication details

The article was received on 23 okt. 2013, accepted on 08 nóv. 2013 and first published on 11 nóv. 2013


Article type: Communication
DOI: 10.1039/C3DT52996G
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Dalton Trans., 2014,43, 945-949

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    The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties

    D. Zhang, Y. Bian, J. Qin, P. Wang and X. Chen, Dalton Trans., 2014, 43, 945
    DOI: 10.1039/C3DT52996G

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