Issue 69, 2014

Convergent and divergent two-dimensional coordination networks formed through substrate-activated or quenched alkynyl ligation

Abstract

Metal coordination assemblies of the symmetric bi-functional 4,4′-di-(1,4-buta-1,3-diynyl)-benzoic acid are investigated by scanning tunnelling microscopy on metal surfaces. The formation of long-range ordered, short-range disordered and random phases depends on the competition between the convergent and divergent coordination motifs of the individual functional groups and is crucially influenced by the substrate.

Graphical abstract: Convergent and divergent two-dimensional coordination networks formed through substrate-activated or quenched alkynyl ligation

Supplementary files

Article information

Article type
Communication
Submitted
15 maí 2014
Accepted
11 júl. 2014
First published
11 júl. 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 9973-9976

Convergent and divergent two-dimensional coordination networks formed through substrate-activated or quenched alkynyl ligation

J. Čechal, C. S. Kley, T. Kumagai, F. Schramm, M. Ruben, S. Stepanow and K. Kern, Chem. Commun., 2014, 50, 9973 DOI: 10.1039/C4CC03723E

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