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Issue 83, 2012
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Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

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Abstract

By intimate control of reaction conditions, phase-pure crystalline porous metal–organic framework materials [Zn4O(L)3] with interpenetrated and non-interpenetrated structures can be synthesised. Under certain conditions, these reactions occur with concomitant deprotection of masked alcohols located on the organic links which yield accessible ‘metal-binding’ functional groups within the frameworks.

Graphical abstract: Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

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Article information


Submitted
01 ágú. 2012
Accepted
31 ágú. 2012
First published
31 ágú. 2012

Chem. Commun., 2012,48, 10328-10330
Article type
Communication

Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

D. Rankine, A. Avellaneda, M. R. Hill, C. J. Doonan and C. J. Sumby, Chem. Commun., 2012, 48, 10328
DOI: 10.1039/C2CC35565E

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