Issue 92, 2012

Commercial metal–organic frameworks as heterogeneous catalysts

Abstract

Metal–organic frameworks (MOFs) are porous crystalline materials that have promising applications as heterogeneous catalysts. After describing the composition, textural properties and crystal structure of four commercially available MOFs, we summarize organic transformations for which these commercial MOFs exhibit higher catalytic activity than the corresponding soluble metal salts or metal ion-exchanged zeolites. In the present article, we have focused on reactions requiring Lewis-acid sites or redox centers to illustrate the potential applications and limitations of commercial MOFs. In a final section, we provide our views on future developments whose ultimate target will be the use of a commercial MOF as a heterogeneous catalyst for a real industrial process in fine chemistry, thus, realizing the advantages of these materials with respect to zeolites or other solid catalysts in liquid-phase reactions.

Graphical abstract: Commercial metal–organic frameworks as heterogeneous catalysts

Article information

Article type
Feature Article
Submitted
16 jún. 2012
Accepted
03 sep. 2012
First published
03 sep. 2012

Chem. Commun., 2012,48, 11275-11288

Commercial metal–organic frameworks as heterogeneous catalysts

A. Dhakshinamoorthy, M. Alvaro and H. Garcia, Chem. Commun., 2012, 48, 11275 DOI: 10.1039/C2CC34329K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements