DOI: 10.1039/A802906G
(Paper)
Reference Section for: Chem. Commun., 1998, 1577-1578
The activation of carbon disulfide by a cluster. The reaction of the µ3-CS complex [{Co(η-C5H5)}2{Fe(CO)2PPh3}(µ3-S)(µ3-CS)] with CS2
(Note: The full text of this document is currently only available in the PDF Version )
Anthony R. Manning, Anthony J. Palmer, Anthony R. Manning, John McAdam, Brian H. Robinson and Jim Simpson
Abstract
When [{Co(η-C5H5)}2{Fe(CO)2PPh3}(µ3-S)(µ3-CS)] is refluxed in CS2 solution, it is converted to [{Co(η-C5H5)}2{Fe(CO)PPh3}(µ3-S){µ3-CSC(S)S}] which contains an unusual C2S3 bridging ligand.
References
- A. R. Manning, L. O'Dwyer, P. A. McArdle and D. Cunningham, J. Chem. Soc., Chem. Commun., 1992, 897 RSC.
- A. R. Manning, L. O'Dwyer, P. A. McArdle and D. Cunningham, J. Organomet. Chem., in press, and references therein Search PubMed.
- F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen and R. Taylor, J. Chem. Soc., Perkin Trans. 2, 1987, S1 RSC.
- J. Doherty, J. Fortune, A. R. Manning and F. S. Stephens, J. Chem. Soc., Dalton Trans., 1984, 1111 RSC.
- D. Coucouvanis, Prog. Inorg. Chem., 1970, 11, 233 CAS.
- H. Werner and K. Leonhard, Angew. Chem., Int. Ed. Engl., 1979, 18, 627 CrossRef; H. Werner, K. Leonhard, O. Kolb, E. Röttinger and H. Vahrenkamp, Chem. Ber., 1980, 113, 1654 CAS.
- J. Fortune and A. R. Manning, Organometallics, 1983, 2, 1719 CrossRef CAS.
- G. M. Sheldrick, SHELXS-86, A program for the solution of crystal structures from diffraction data, University of Göttingen, Germany, 1986; G. M. Sheldrick, Acta Crystallogr., Sect. A, 1990, 46, 467 Search PubMed.
- G. M. Sheldrick, SHELXL-96, A program for the solution of crystal structures from diffraction data, University of Göttingen, Germany, 1996.