Weak intermolecular interactions in sulfonamide salts: structure of 1-ethyl-2-methyl-3-benzyl imidazolium bis[(trifluoromethyl)sulfonyl]amide

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Jacob J. Golding, Douglas R. MacFarlane, Leone Spiccia, Jacob J. Golding, Maria Forsyth, Brian W. Skelton and Alan H. White


Abstract

The crystal structure of a 1,2,3-trisubstituted imidazolium salt of the bis[(trifluoromethyl)sulfonyl)]amide ion is presented; this salt is a prototype for similar, room temperature liquid, imidazolium salts; the structure shows that the anion and cation interact weakly, with little if any hydrogen bonding present.


References

  1. P. Bonhote, A. Dias, N. Papageorgiou, K. Kalyanasundaram and M. Gratzel, Inorg. Chem., 1996, 35, 1168 CrossRef CAS.
  2. K. R. Seddon, J. Chem. Technol. Biotechnol., 1997, 68, 351 CrossRef CAS.
  3. J. Sun, D. Macfarlane and M. Forsyth, Proceedings of 5th International Symposium on Molten salt Chemistry and Technology, Dresden, in press Search PubMed; V. R. Koch, C. Nanjundah, G. Battista Appetecchi and B. Scrosati, J. Electrochem. Soc., 1995, 142, L116 Search PubMed.
  4. A. Haas, Ch. Klare, P. Betz, C. Kruger, Y.-H. Tsay and F. Aubke, Inorg. Chem., 1996, 35, 1918 CrossRef CAS.
  5. A. K. Abdul-Sada, A. M. Geenway, P. B. Hitchcock, T. J. Mohammed, K. R. Seddon and J. A. Zora, J. Chem. Soc., Chem. Commun., 1986, 1753 RSC.
  6. J. S. Wilkes and M. J. Zaworotko, J. Chem. Soc., Chem Commun., 1986, 965 RSC.
  7. J. Fuller, R. T. Carlin, H. C. De Long and D. Haworth, J. Chem. Soc., Chem. Commun., 1994, 299 RSC.
  8. F. A. Cotton and P. F. Stokely, J. Am. Chem. Soc., 1970, 92, 294 CrossRef CAS.
  9. D. W. J. Cruickshank, J. Chem. Soc., 1961, 5486 RSC.
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