Sulfide electrolytes for all-solid-state sodium batteries: fundamentals and modification strategies

Shoumeng Yang, Yi Tang, Yu Yao, Shengnan He, Zhijun Wu, Yang Yang, Hongge Pan, Xianhong Rui and Yan Yu

Mater. Horiz., 2025, 12, 1058
DOI: 10.1039/D4MH01218F

Design strategies for liquid-phase synthesis of sodium-based quaternary solid-state electrolytes

Saeed Ahmadi Vaselabadi, Brynn Benham and Colin A. Wolden

Mater. Adv., 2025, 6, 5523
DOI: 10.1039/D5MA00270B

Mechanochemical synthesis of rock salt-type Na2CaSnS4 as a sodium-ion conductor

Hamdi Ben Yahia, Atsushi Sakuda and Akitoshi Hayashi

RSC Mechanochem., 2025, 2, 159
DOI: 10.1039/D4MR00028E

Sodium-Ion Conducting Solid Electrolytes in the Na₂S–In₂S₃ System

Kota MOTOHASHI, Akira NASU, Takuya KIMURA, Chie HOTEHAMA, Atsushi SAKUDA, Masahiro TATSUMISAGO and Akitoshi HAYASHI

Electrochemistry, 2022, 90, 067009
DOI: 10.5796/electrochemistry.22-00037

Amorphous Materials for Lithium‐Ion and Post‐Lithium‐Ion Batteries

Junwei Ding, Dongfang Ji, Yuanzheng Yue and Morten M. Smedskjaer

Small, 2024, 20
DOI: 10.1002/smll.202304270

Na6Ge2S6O-ionic conductor: Synthesis, structure and ionic transportation

Hamdi Ben Yahia, Kota Motohashi, Shigeo Mori, Atsushi Sakuda and Akitoshi Hayashi

Solid State Ionics, 2023, 403, 116412
DOI: 10.1016/j.ssi.2023.116412

Unveiling the Growth Mechanism of the Interphase between Lithium Metal and Li2S‐P2S5‐B2S3 Solid‐State Electrolytes

Chengwei Gao, Jiahui Zhang, Chengmiao He, Yanqing Fu, Tianyue Zhou, Xu Li, Shiliang Kang, Linling Tan, Qing Jiao, Shixun Dai, Yuanzheng Yue and Changgui Lin

Advanced Energy Materials, 2023, 13
DOI: 10.1002/aenm.202204386

Computational screening of sodium solid electrolytes through unsupervised learning

Damdae Park, Wonsuk Chung, Byoung Koun Min, Ung Lee, Seungho Yu and Kyeongsu Kim

npj Comput Mater, 2024, 10
DOI: 10.1038/s41524-024-01392-6

Improvement of interfacial stability between Na metal and Na3PS4 family solid electrolyte for all-solid-state sodium metal batteries

Manasi Mwemezi, Woon Bae Park and Amol Bhairuba Ikhe

Electrochimica Acta, 2024, 480, 143919
DOI: 10.1016/j.electacta.2024.143919

Development of Sodium–Ion Conducting Sulfide Electrolytes

Akitoshi HAYASHI

Electrochemistry, 2023, 91, 101002
DOI: 10.5796/electrochemistry.23-00096

Optimizing conductivity in Na-V-Te-O glass through controlled heat treatment

Michalina Anna Wanat, Piotr Okoczuk, Marcin Łapiński, Barbara Kościelska, Stefania Wolff, Sharafat Ali and Natalia Anna Wójcik

Ceramics International, 2025, 51, 2441
DOI: 10.1016/j.ceramint.2024.11.228

A New Sodium Thioborate Fast Ion Conductor: Na3B5S9

Laidong Zhou, J. David Bazak, Baltej Singh, Chang Li, Abdeljalil Assoud, Nancy M. Washton, Vijayakumar Murugesan and Linda F. Nazar

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202300404

Hard Carbon–Sulfide Solid Electrolyte Interface in All-Solid-State Sodium Batteries

Wataru YOSHIDA, Akira NASU, Kota MOTOHASHI, Masahiro TATSUMISAGO, Atsushi SAKUDA and Akitoshi HAYASHI

Electrochemistry, 2023, 91, 037009
DOI: 10.5796/electrochemistry.23-00009

Mechanochemistry in Sodium Thioantimonate Solid Electrolytes: Effects on Structure, Morphology, and Electrochemical Performance

Fuwei Wen, Geng Xie, Ning Chen, Qichao Wu, Madhusudan Chaudhary, Xiang You, Vladimir K. Michaelis, Arthur Mar and Lingzi Sang

ACS Appl. Mater. Interfaces, 2023, 15, 40070
DOI: 10.1021/acsami.3c07746

LiI-Modified Glass-Ceramic Lithium Thioborate: From Fundamentals to Applications in Solid-State Batteries

Sarah E. Holmes, Jędrzej Kondek, Pu Zhang, Vasiliki Faka, Jon A. Newnham, Lara M. Gronych, Michael Ryan Hansen, Wolfgang G. Zeier and Yi Cui

Chem. Mater., 2025, 37, 2642
DOI: 10.1021/acs.chemmater.5c00224

Mechanochemical Synthesis and Structure of the Alkali Metal Magnesium Chalcogenide Na6MgS4

Hamdi Ben Yahia, Kota Motohashi, Atsushi Sakuda and Akitoshi Hayashi

Inorg. Chem., 2023, 62, 10440
DOI: 10.1021/acs.inorgchem.3c01415

Ultra-long cycling life Li2S–P2S5–B2S3 solid electrolyte via LiI doping

Yuxin Shao, Chengwei Gao, Chengmiao He, Linling Tan, Shiliang Kang, Qing Jiao and Changgui Lin

Ceramics International, 2024, 50, 31032
DOI: 10.1016/j.ceramint.2024.05.408

High-Sodium-Concentration Sodium Oxythioborosilicate Glass Synthesized via Ambient Pressure Method with Sodium Polysulfides

Tomoya Otono, Akira Nasu, Taichi Asakura, Hiroe Kowada, Kota Motohashi, Masahiro Tatsumisago, Atsushi Sakuda and Akitoshi Hayashi

Inorg. Chem., 2024, 63, 4589
DOI: 10.1021/acs.inorgchem.3c04101

Novel Sulfide‐Chloride Solid‐State Electrolytes with Tunable Anion Ratio for Highly Stable Solid‐State Sodium‐Ion Batteries

Zhi Liang Dong, Yi Gan, Vinicius Martins, Xuchun Wang, Bolin Fu, Enzhong Jin, Yingjie Gao, Yang Hu, Xiaoting Lin, Yi Yuan, Colin Turner, Xin Pang, Hamidreza Abdolvand, Yining Huang, Tsun‐Kong Sham and Yang Zhao

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202503107

Advancing solid-state sodium batteries: Status quo of sulfide-based solid electrolytes

Zhendong Yang, Bin Tang, Dehang Ren, Xinyu Yu, Yirong Gao, Yifan Wu, Yongan Yang, Zhongfang Chen and Zhen Zhou

Materials Today, 2024, 80, 429
DOI: 10.1016/j.mattod.2024.08.011

Recent progress in the development of glass and glass-ceramic cathode/solid electrolyte materials for next-generation high capacity all-solid-state sodium-ion batteries: A review

Suman Gandi, Venkata Satya Chidambara Swamy Vaddadi, Saran Srihari Sripada Panda, Nithin Kumar Goona, Saidi Reddy Parne, Motilal Lakavat and Amiya Bhaumik

Journal of Power Sources, 2022, 521, 230930
DOI: 10.1016/j.jpowsour.2021.230930

Formation of Passivate Interphases by Na3BS3-Glass Solid Electrolytes in All-Solid-State Sodium-Metal Batteries

Akira Nasu, Takeaki Inaoka, Fumika Tsuji, Kota Motohashi, Atsushi Sakuda, Masahiro Tatsumisago and Akitoshi Hayashi

ACS Appl. Mater. Interfaces, 2022, 14, 24480
DOI: 10.1021/acsami.2c05090

Low‐Cost Preparation of High‐Performance Na‐B‐H‐S Electrolyte for All‐Solid‐State Sodium‐Ion Batteries

Wei Zhou, Changsheng Song, Shuyang Li, Miao Liu, Huiwen He, Shaoyu Yang, Jin Xie, Fei Wang, Fang Fang, Dalin Sun, Jie Zhao and Yun Song

Advanced Science, 2023, 10
DOI: 10.1002/advs.202302618

Na2MgP2S6: A new solid electrolyte for sodium ion batteries

Hamdi Ben Yahia, Kota Motohashi, Shigeo Mori, Atsushi Sakuda and Akitoshi Hayashi

Journal of Alloys and Compounds, 2024, 994, 174692
DOI: 10.1016/j.jallcom.2024.174692

A New Sodium Thioborate Fast Ion Conductor: Na3B5S9

Laidong Zhou, J. David Bazak, Baltej Singh, Chang Li, Abdeljalil Assoud, Nancy M. Washton, Vijayakumar Murugesan and Linda F. Nazar

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202300404

Utilizing reactive polysulfides flux Na2S for the synthesis of sulfide solid electrolytes for all-solid-state sodium batteries

Akira Nasu, Tomoya Otono, Takuma Takayanagi, Minako Deguchi, Atsushi Sakuda, Masahiro Tatsumisago and Akitoshi Hayashi

Energy Storage Materials, 2024, 67, 103307
DOI: 10.1016/j.ensm.2024.103307

Mechanochemical synthesis of Na₃NbS₄ metastable phase as positive electrode materials for all-solid-state sodium batteries

Akira Nasu, Atsushi Sakuda, Masahiro Tatsumisago and Akitoshi Hayashi

J. Ceram. Soc. Japan, 2022, 130, 789
DOI: 10.2109/jcersj2.22056

Molten sodium batteries: advances in chemistries, electrolytes, and interfaces

Ryan C. Hill, Martha S. Gross, Stephen J. Percival, Amanda S. Peretti, Leo J. Small, Erik D. Spoerke and Yang-Tse Cheng

Front. Batter. Electrochem., 2024, 3
DOI: 10.3389/fbael.2024.1369305

The cubic and trigonal polymorphs of NaMn1/2Sn1/2S2 (Na2MnSnS4)

Hamdi Ben Yahia, Shigeo Mori, Atsushi Sakuda and Akitoshi Hayashi

Journal of Solid State Chemistry, 2024, 338, 124891
DOI: 10.1016/j.jssc.2024.124891