Sandip Munshi, Arup Sinha, Solomon Yiga, Sridhar Banerjee, Reena Singh, Md. Kamal Hossain, Matti Haukka, Andrei Felipe Valiati, Ricardo Dagnoni Huelsmann, Edmar Martendal, Rosely Peralta, Fernando Xavier, Ola F. Wendt, Tapan K. Paine and Ebbe Nordlander

Dalton Trans., 2022, 51, 870
DOI: 10.1039/D1DT03381F

C(sp3)–H oxidation and chlorination catalysed by a bioinspired pincer iron(iii) complex

Jian Han, Liming Tan, Yanjun Wan, Gang Li and Stephen N. Anderson

Dalton Trans., 2022, 51, 11620
DOI: 10.1039/D2DT02005J

Oxidative C–C/C–X coupling in organometallic nickel complexes: insights from DFT

Gopal Sabapathi and Ponnambalam Venuvanalingam

New J. Chem., 2022, 46, 14992
DOI: 10.1039/D2NJ02480B

Oxidative dehalogenation of halophenols by high-valent nonheme iron(iv)-oxo intermediates

Umesh Kumar Bagha, Jagnyesh Kumar Satpathy, Gourab Mukherjee, Prasenjit Barman, Devesh Kumar, Sam P. de Visser and Chivukula V. Sastri

Faraday Discuss., 2022, 234, 58
DOI: 10.1039/D1FD00064K

C–H bond chlorination and bromination using water soluble nickel(ii) guanidine complexes

Jaipriya Khatri, Vasanthapandiyan Mari, Aniruddha Sarkar, Naiwrit Karmodak and Basab Bijayi Dhar

Dalton Trans., 2025, 54, 503
DOI: 10.1039/D4DT02783C

Bioinspired models for an unusual 3-histidine motif of diketone dioxygenase enzyme

Ramamoorthy Ramasubramanian, Karunanithi Anandababu, Nadia C. Mösch-Zanetti, Ferdinand Belaj and Ramasamy Mayilmurugan

Dalton Trans., 2019, 48, 14326
DOI: 10.1039/C9DT02518A

C–H bond chlorination using nickel(ii) complexes of tetradentate amido-quinoline ligands

Sanjay Adhikari, Aniruddha Sarkar and Basab Bijayi Dhar

Chem. Commun., 2022, 58, 4075
DOI: 10.1039/D2CC00639A

Deciphering the origin of million-fold reactivity observed for the open core diiron [HO–FeIII–O–FeIVO]2+species towards C–H bond activation: role of spin-states, spin-coupling, and spin-cooperation

Mursaleem Ansari, Dhurairajan Senthilnathan and Gopalan Rajaraman

Chem. Sci., 2020, 11, 10669
DOI: 10.1039/D0SC02624G

Oxygenase mimicking immobilised iron complex catalysts for alkane hydroxylation with H2O2

Seiya Sakakura, Ryunosuke Kitamoto, Kazuki Goto, Seito Miura, Takamasa Takeda, Masaya Okamura, Arisa Fukatsu, Shinobu Itoh and Shiro Hikichi

Catal. Sci. Technol., 2023, 13, 4839
DOI: 10.1039/D3CY00698K

Can you break the oxo-wall? A multiconfigurational perspective

Asmita Sen and Gopalan Rajaraman

Faraday Discuss., 2022, 234, 175
DOI: 10.1039/D1FD00072A

Regioselectivity of hyoscyamine 6β-hydroxylase-catalysed hydroxylation as revealed by high-resolution structural information and QM/MM calculations

Anna Kluza, Zuzanna Wojdyla, Beata Mrugala, Katarzyna Kurpiewska, Przemyslaw J. Porebski, Ewa Niedzialkowska, Wladek Minor, Manfred S. Weiss and Tomasz Borowski

Dalton Trans., 2020, 49, 4454
DOI: 10.1039/D0DT00302F

Determining the inherent selectivity for carbon radical hydroxylation versus halogenation with high-spin oxoiron(iv)–halide complexes: a concerted rebound step

Yaping Tao, Zixian Li, Yiman Zhang, kexi Sun and Zhaojun Liu

RSC Adv., 2022, 12, 9891
DOI: 10.1039/D2RA01384C

An artificial nickel chlorinase based on the biotin–streptavidin technology

Kun Yu, Kailin Zhang, Roman P. Jakob, Timm Maier and Thomas R. Ward

Chem. Commun., 2024, 60, 1944
DOI: 10.1039/D3CC05847F

Sluggish reactivity by a nonheme iron(iv)-tosylimido complex as compared to its oxo analogue

Gourab Mukherjee, Fabián G. Cantú Reinhard, Umesh Kumar Bagha, Chivukula V. Sastri and Sam P. de Visser

Dalton Trans., 2020, 49, 5921
DOI: 10.1039/D0DT00018C

A catalyst- and solvent-free visible-light-promoted bromination and chlorination of tertiary C(sp3)–H bonds

Quanjin Rong, Zhe Zhang, Jingyu Meng, Fan Wang and Zhong-Quan Liu

Org. Chem. Front., 2025, 12, 786
DOI: 10.1039/D4QO01997K

Heteroleptic and Homoleptic Iron(III) Complexes with a Tris(N‐Heterocyclic Carbene) Borate Ligand: Synthesis, Characterization, and Catalytic Application

Yuna Sato, Masaya Okamura and Shiro Hikichi

Eur J Inorg Chem, 2023, 26
DOI: 10.1002/ejic.202200728

Nonheme FeIV═O Complexes Supported by Four Pentadentate Ligands: Reactivity toward H- and O- Atom Transfer Processes

Yong Li, Reena Singh, Arup Sinha, George C. Lisensky, Matti Haukka, Justin Nilsson, Solomon Yiga, Serhiy Demeshko, Sophie Jana Gross, Sebastian Dechert, Ana Gonzalez, Giliandro Farias, Ola F. Wendt, Franc Meyer and Ebbe Nordlander

Inorg. Chem., 2023, 62, 18338
DOI: 10.1021/acs.inorgchem.3c02526

Bridging the Oxo Wall: A New Perspective on High‐valent Metal‐Oxo Species and Their Reactivity in Mn, Fe, and Co Complexes

Asmita Sen, Sunita Sharma and Gopalan Rajaraman

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202419953

Effect of the Ligand Backbone on the Reactivity and Mechanistic Paradigm of Non‐Heme Iron(IV)‐Oxo during Olefin Epoxidation

Jyoti Prasad Biswas, Mursaleem Ansari, Aniruddha Paik, Sheuli Sasmal, Sabarni Paul, Sujoy Rana, Gopalan Rajaraman and Debabrata Maiti

Angewandte Chemie, 2021, 133, 14149
DOI: 10.1002/ange.202102484

Cu–ABNO Catalyst for the Synthesis of Quinolines and Pyrazines via Aerobic Double Dehydrogenation of Alcohols

Shivali Hans, Mohd Adham, Manas Khatua and Subhas Samanta

J. Org. Chem., 2024, 89, 18090
DOI: 10.1021/acs.joc.4c01906

Role of oxidation state, ferryl-oxygen, and ligand architecture on the reactivity of popular high-valent FeIV=O species: A theoretical perspective

Ravi Kumar, Bhawana Pandey, Asmita Sen, Mursaleem Ansari, Sunita Sharma and Gopalan Rajaraman

Coordination Chemistry Reviews, 2020, 419, 213397
DOI: 10.1016/j.ccr.2020.213397

Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation

Alessandro Fagnano, Federico Frateloreto, Roberta Paoloni, Carla Sappino, Osvaldo Lanzalunga, Miquel Costas, Stefano Di Stefano and Giorgio Olivo

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202401694

Probing the Origins of Puzzling Reactivity in Fe/Mn–Oxo/Hydroxo Species toward C–H Bonds: A DFT and Ab Initio Perspective

Asmita Sen, Azaj Ansari, Abinash Swain, Bhawana Pandey and Gopalan Rajaraman

Inorg. Chem., 2023, 62, 14931
DOI: 10.1021/acs.inorgchem.3c01632

Origin of Unprecedented Formation and Reactivity of FeIV═O Species via Oxygen Activation: Role of Noncovalent Interactions and Magnetic Coupling

Asmita Sen, Neethinathan Johnee Britto, Dustin Kass, Kallol Ray and Gopalan Rajaraman

Inorg. Chem., 2024, 63, 9809
DOI: 10.1021/acs.inorgchem.4c00371

Bioinspired Non‐Heme Mn Catalysts for Regio‐ and Stereoselective Oxyfunctionalizations with H2O2

Roman V. Ottenbacher, Anna A. Bryliakova, Vladimir I. Kurganskii, Petr V. Prikhodchenko, Alexander G. Medvedev and Konstantin P. Bryliakov

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302772

High‐Valent Cobalt‐Difluoride in Oxidative Fluorination of Saturated Hydrocarbons

Agnideep Das, Brendan Twamley, Oscar R. Kelly, Chakadola Panda, Paul Richardson and Aidan R. McDonald

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202421157

Interplay Between Steric and Electronic Effects: A Joint Spectroscopy and Computational Study of Nonheme Iron(IV)‐Oxo Complexes

Gourab Mukherjee, Aligulu Alili, Prasenjit Barman, Devesh Kumar, Chivukula V. Sastri and Sam P. de Visser

Chemistry A European J, 2019, 25, 5086
DOI: 10.1002/chem.201806430

Microporous cobaltporphyrin covalent polymer mediated Co3O4@PNC nanocomposites for efficient catalytic C-H bond activation

Mingyang Tan, Liang Zhu, Hao Liu, Yajun Fu, Shuang-Feng Yin and Weijun Yang

Applied Catalysis A: General, 2021, 614, 118035
DOI: 10.1016/j.apcata.2021.118035

Comparison of the stability and reactivity of achiral versus chiral nonheme oxoiron(IV) complexes supported by pentadentate N5 ligands in oxygen-atom and hydrogen-atom transfer reactions

Dóra Lakk-Bogáth, Gábor Speier and József Kaizer

Inorganic Chemistry Communications, 2019, 107, 107446
DOI: 10.1016/j.inoche.2019.107446

Mechanistic Insights into Substrate Positioning That Distinguish Non-heme Fe(II)/α-Ketoglutarate-Dependent Halogenases and Hydroxylases

David W. Kastner, Aditya Nandy, Rimsha Mehmood and Heather J. Kulik

ACS Catal., 2023, 13, 2489
DOI: 10.1021/acscatal.2c06241

Mechanistic Insights on the Formation of High‐Valent MnIII/IV=O Species Using Oxygen as Oxidant: A Theoretical Perspective

Asmita Sen, Nidhi Vyas, Bhawana Pandey, Madhavan Jaccob and Gopalan Rajaraman

Israel Journal of Chemistry, 2020, 60, 973
DOI: 10.1002/ijch.201900142

Visible‐Light‐Promoted Aliphatic C−H Chlorination and Bromination Using Haloform as the Halogen Donor and Azidobenziodoxole as the Mediator

Qin He, Zehui Cao, Yangyang Zhang, Gong Chen and Yaxin Wang

Adv Synth Catal, 2023, 365, 2711
DOI: 10.1002/adsc.202300416

Selective Radical Transfer in a Series of Nonheme Iron(III) Complexes

Vishal Yadav, Lyupeng Wen, Sudha Yadav, Maxime A. Siegler and David P. Goldberg

Inorg. Chem., 2023, 62, 17830
DOI: 10.1021/acs.inorgchem.3c02617

Revealing the Iron-Catalyzed β-Methyl Scission of tert-Butoxyl Radicals via the Mechanistic Studies of Carboazidation of Alkenes

Mong-Feng Chiou, Haigen Xiong, Yajun Li, Hongli Bao and Xinhao Zhang

Molecules, 2020, 25, 1224
DOI: 10.3390/molecules25051224

Effects of Noncovalent Interactions on High-Spin Fe(IV)–Oxido Complexes

Victoria F. Oswald, Justin L. Lee, Saborni Biswas, Andrew C. Weitz, Kaustuv Mittra, Ruixi Fan, Jikun Li, Jiyong Zhao, Michael Y. Hu, Esen E. Alp, Emile L. Bominaar, Yisong Guo, Michael T. Green, Michael P. Hendrich and A. S. Borovik

J. Am. Chem. Soc., 2020, 142, 11804
DOI: 10.1021/jacs.0c03085

Molecular Insights into Converting Hydroxide Adenosyltransferase into Halogenase

Yixun Jiang, Mingdong Yao, Jianqiang Feng, Haoran Niu, Bin Qiao, Bingzhi Li, Binju Wang, Wenhai Xiao, Min Dong and Yingjin Yuan

J. Agric. Food Chem., 2024, 72, 12685
DOI: 10.1021/acs.jafc.4c02581

Syntheses and structures of transition metal complexes of quinoline-containing multidentate amine ligands

Bronte Carr, Cassandra L. Fleming and Allan G. Blackman

Coordination Chemistry Reviews, 2024, 502, 215599
DOI: 10.1016/j.ccr.2023.215599

High‐Valent Cobalt‐Difluoride in Oxidative Fluorination of Saturated Hydrocarbons

Agnideep Das, Brendan Twamley, Oscar R. Kelly, Chakadola Panda, Paul Richardson and Aidan R. McDonald

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202421157

Inspiration from Nature: Influence of Engineered Ligand Scaffolds and Auxiliary Factors on the Reactivity of Biomimetic Oxidants

Gourab Mukherjee, Jagnyesh K. Satpathy, Umesh K. Bagha, M. Qadri E. Mubarak, Chivukula V. Sastri and Sam P. de Visser

ACS Catal., 2021, 11, 9761
DOI: 10.1021/acscatal.1c01993

Effect of Ligand Backbone on the Electrochemical Hydrogen Evolution Reaction and Hydrogen-Atom-Transfer Reactivity Using a Nickel Polypyridine Quinoline Complex

Sabarni Paul, Subhankar Sutradhar, Aniruddha Paik, Amit Biswas, Soumadip Das, Chandan Das, Rajib Maity, Alok Mahata, Siba P. Midya, Bholanath Maity and Sujoy Rana

Inorg. Chem., 2025, 64, 7988
DOI: 10.1021/acs.inorgchem.4c05512

Highly Robust Iron Catalyst System for Intramolecular C(sp3)−H Amidation Leading to γ‐Lactams

Jeonguk Kweon and Sukbok Chang

Angew Chem Int Ed, 2021, 60, 2909
DOI: 10.1002/anie.202013499

What Drives Radical Halogenation versus Hydroxylation in Mononuclear Nonheme Iron Complexes? A Combined Experimental and Computational Study

Emilie F. Gérard, Vishal Yadav, David P. Goldberg and Sam P. de Visser

J. Am. Chem. Soc., 2022, 144, 10752
DOI: 10.1021/jacs.2c01375

Spectroscopically Guided Simulations Reveal Distinct Strategies for Positioning Substrates to Achieve Selectivity in Nonheme Fe(II)/α-Ketoglutarate-Dependent Halogenases

Rimsha Mehmood, Vyshnavi Vennelakanti and Heather J. Kulik

ACS Catal., 2021, 11, 12394
DOI: 10.1021/acscatal.1c03169

Dioxygen-Derived Nonheme Mononuclear FeIII(OH) Complex and Its Reactivity with Carbon Radicals

Vishal Yadav, Jesse B. Gordon, Maxime A. Siegler and David P. Goldberg

J. Am. Chem. Soc., 2019, 141, 10148
DOI: 10.1021/jacs.9b03329

Recent Advances in First‐Row Transition‐Metal‐Mediated C−H Halogenation of (Hetero)arenes and Alkanes

Aniruddha Paik, Sabarni Paul, Sabyasachi Bhowmik, Rahul Das, Togati Naveen and Sujoy Rana

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200060

Catalytic and stoichiometric oxoiron(IV) assisted oxidation of hydrocynnamaldehyde under air

Flóra Viktória Csendes and József Kaizer

Polyhedron, 2020, 182, 114505
DOI: 10.1016/j.poly.2020.114505

Mechanistic Study of Chemoselectivity for Carbon Radical Hydroxylation versus Chlorination with FeIII(OH)(Cl) Complexes

Miao Yang, Xiahe Chen, Xingxing Su, Yuan‐Bin She and Yun‐Fang Yang

Chemistry An Asian Journal, 2023, 18
DOI: 10.1002/asia.202201311

Optical and surface properties of Schiff base ligands and Cu(II) and Co(II) complexes

Alaa Adnan Rashad, Dina A. Najeeb, Shaymaa M. Mahmoud, Evon Akram, Khalid Zainulabdeen, Salam Dulaim and Rahimi M. Yusop

Fine Chem. Technol., 2024, 19, 452
DOI: 10.32362/2410-6593-2024-19-5-452-461

Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation

Alessandro Fagnano, Federico Frateloreto, Roberta Paoloni, Carla Sappino, Osvaldo Lanzalunga, Miquel Costas, Stefano Di Stefano and Giorgio Olivo

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202401694

Copper‐Catalyzed sp3‐Carbon Radical/Halogen Radical Cross Coupling: Selective Halogenation of 1,3‐Dicarbonyl Compounds

Shuai‐Shuai Lv, Xu‐Ping Yan, Cheng‐Kun Li, Shao‐Fang Zhou, Adedamola Shoberu and Jian‐Ping Zou

ChemistrySelect, 2020, 5, 5670
DOI: 10.1002/slct.202000947

Halogen Transfer to Carbon Radicals by High-Valent Iron Chloride and Iron Fluoride Corroles

Geoffrey W. Farley, Maxime A. Siegler and David P. Goldberg

Inorg. Chem., 2021, 60, 17288
DOI: 10.1021/acs.inorgchem.1c02666

Fe-Catalyzed Aziridination Is Governed by the Electron Affinity of the Active Imido-Iron Species

Guillaume Coin, Ranjan Patra, Sujoy Rana, Jyoti Prasad Biswas, Patrick Dubourdeaux, Martin Clémancey, Sam P. de Visser, Debabrata Maiti, Pascale Maldivi and Jean-Marc Latour

ACS Catal., 2020, 10, 10010
DOI: 10.1021/acscatal.0c01427

Mechanisms of C(sp3)–H and C=C selective oxidative heterofunctionalizations by non-heme Fe and Mn mimics of oxygenase enzymes

Konstantin P. Bryliakov

Coordination Chemistry Reviews, 2024, 508, 215793
DOI: 10.1016/j.ccr.2024.215793

Photoinduced Hydrogen Evolution Catalyzed by Co(II) Complexes of N5‐Donor Ligands

Chuanshuai Li, Yong Li, Yusen Luo, Klaudia Michaliszyn, Iria Bolaño Losada, Md. Kamal Hossain, Fatma Elantabli, Meiyuan Guo, Lintang Hizbullah, Derek A. Tocher, Matti Haukka, Petter Persson, Julio Lloret‐Fillol, Benjamin Dietzek‐Ivanšić and Ebbe Nordlander

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202404499

Effect of the Ligand Backbone on the Reactivity and Mechanistic Paradigm of Non‐Heme Iron(IV)‐Oxo during Olefin Epoxidation

Jyoti Prasad Biswas, Mursaleem Ansari, Aniruddha Paik, Sheuli Sasmal, Sabarni Paul, Sujoy Rana, Gopalan Rajaraman and Debabrata Maiti

Angew Chem Int Ed, 2021, 60, 14030
DOI: 10.1002/anie.202102484

Bridging the Oxo Wall: A New Perspective on High‐valent Metal‐Oxo Species and Their Reactivity in Mn, Fe, and Co Complexes

Asmita Sen, Sunita Sharma and Gopalan Rajaraman

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202419953

Experimental and Computational Determination of a M–Cl Homolytic Bond Dissociation Free Energy: Mn(III)Cl-Mediated C–H Cleavage and Chlorination

Ananya Saju, Parami S. Gunasekera, Pierpaolo Morgante, Samantha N. MacMillan, Jochen Autschbach and David C. Lacy

J. Am. Chem. Soc., 2023, 145, 13384
DOI: 10.1021/jacs.3c03651

Influence of Cage Effects in Directing the Outcome of C–X Bond Forming Reactions

Zihang Qiu and Constanze N. Neumann

ACS Org. Inorg. Au, 2024, 4, 1
DOI: 10.1021/acsorginorgau.3c00044

Transition Metal‐Catalyzed C−H Functionalization Through Electrocatalysis

Prabhat Kumar Baroliya, Mukesh Dhaker, Subir Panja, Shaeel Ahmed Al‐Thabaiti, Soha M. Albukhari, Qana A. Alsulami, Arnab Dutta and Debabrata Maiti

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202202201

Fe–S Catalyst Generated In Situ from Fe(III)- and S3•–-Promoted Aerobic Oxidation of Terminal Alkenes

Jing-Jing Ai, Bei-Bei Liu, Jian Li, Fei Wang, Cheng-Mi Huang, Weidong Rao and Shun-Yi Wang

Org. Lett., 2021, 23, 4705
DOI: 10.1021/acs.orglett.1c01408

The Persistent Radical Effect in Organic Synthesis

Dirk Leifert and Armido Studer

Angew Chem Int Ed, 2020, 59, 74
DOI: 10.1002/anie.201903726

Iron-catalyzed aliphatic C–H functionalization to construct carbon–carbon bonds

Lulu Zhou, Hengrui Cai, Dong Xie, Kangkang Sun, Shanmei Zhu, Mengying Guo and Wei Han

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-60010-1

C–H Bond Cleavage by Bioinspired Nonheme Metal Complexes

Justin L. Lee, Dolores L. Ross, Suman K. Barman, Joseph W. Ziller and A. S. Borovik

Inorg. Chem., 2021, 60, 13759
DOI: 10.1021/acs.inorgchem.1c01754

Elucidating the Iron‐Based Ionic Liquid [C4py][FeCl4]: Structural Insights and Potential for Nonaqueous Redox Flow Batteries

Christian Balischewski, Biswajit Bhattacharyya, Josh J. Bailey, Scott D. Place, Peter Nockemann, Jiyong Kim, Armin Wedel, Shashank Gahlaut, Ilko Bald, Weiyang Li, Yann Garcia, Eric Sperlich, Christina Günter, Alexandra Kelling and Andreas Taubert

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202311571

Proton-triggered chemoselective halogenation of aliphatic C–H bonds with nonheme FeIV-oxo complexes

Neus Pagès-Vilà, Ilaria Gamba, Martin Clémancey, Jean-Marc Latour, Anna Company and Miquel Costas

Journal of Inorganic Biochemistry, 2024, 259, 112643
DOI: 10.1016/j.jinorgbio.2024.112643

Determining the Inherent Selectivity for Carbon Radical Hydroxylation versus Halogenation with FeIII(OH)(X) Complexes: Relevance to the Rebound Step in Non-heme Iron Halogenases

Vishal Yadav, Rodolfo J. Rodriguez, Maxime A. Siegler and David P. Goldberg

J. Am. Chem. Soc., 2020, 142, 7259
DOI: 10.1021/jacs.0c00493

Synthesis of Two Mononuclear Schiff Base Metal (M = Fe, Cu) Complexes: MOF Structure, Dye Degradation, H2O2 Sensing, and DNA Binding Property

Mithun Kumar Ghosh, Sayantan Pathak and Tanmay Kumar Ghorai

ACS Omega, 2019, 4, 16068
DOI: 10.1021/acsomega.9b02268

Aliphatic C H azidation by Mn based mimics of α-ketoglutarate dependent enzymes

Roman V. Ottenbacher, Dmitry P. Lubov, Denis G. Samsonenko, Andrey A. Nefedov and Konstantin P. Bryliakov

Journal of Catalysis, 2024, 429, 115275
DOI: 10.1016/j.jcat.2023.115275

Rational Design of Bioinspired Catalysts for Selective Oxidations

Laia Vicens, Giorgio Olivo and Miquel Costas

ACS Catal., 2020, 10, 8611
DOI: 10.1021/acscatal.0c02073

Der “Persistent Radical Effect” in der organischen Chemie

Dirk Leifert and Armido Studer

Angewandte Chemie, 2020, 132, 74
DOI: 10.1002/ange.201903726

Temperature-Dependent Reactivity of a Non-heme FeIII(OH)(SR) Complex: Relevance to Isopenicillin N Synthase

Vishal Yadav, Maxime A. Siegler and David P. Goldberg

J. Am. Chem. Soc., 2021, 143, 46
DOI: 10.1021/jacs.0c09688

DNA interactive and selective anticancer activity studies of copper(II) complexes decorated water‐soluble porphyrin

Qian Zhang, Bing‐jie Hou, Yan‐yan Li, Wen‐yuan Zhang and Jia‐cheng Liu

Applied Organom Chemis, 2021, 35
DOI: 10.1002/aoc.6094

Regioselective Oxybromination of Benzene and Its Derivatives by Bromide Anion with a Mononuclear Nonheme Mn(IV)–Oxo Complex

Namita Sharma, Yong-Min Lee, Xiao-Xi Li, Wonwoo Nam and Shunichi Fukuzumi

Inorg. Chem., 2019, 58, 14299
DOI: 10.1021/acs.inorgchem.9b02410

Effect of Redox-Active Quinoline on the Reactivity and Mechanism of Hydrogen Evolution Reaction (HER) with Pentadentate Polypyridyl-Quinolyl Ligand-Coordinated Cobalt Complex

Aniruddha Paik, Chandan Das, Sabarni Paul, Amit Biswas, Sakshi Mehta, Abhishake Mondal, Bholanath Maity, Arnab Dutta and Sujoy Rana

ACS Catal., 2024, 14, 15498
DOI: 10.1021/acscatal.4c03819

Defluorination of Fluorophenols by a Nonheme Iron(IV)‐Oxo Species: Observation of a New Intermediate Along the Reaction

Umesh Kumar Bagha, Rolly Yadav, Thirakorn Mokkawes, Jagnyesh Kumar Satpathy, Devesh Kumar, Chivukula V. Sastri and Sam P. de Visser

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202300478

Non‐Heme‐Iron‐Mediated Selective Halogenation of Unactivated Carbon−Hydrogen Bonds

Katharina Bleher, Peter Comba, Dieter Faltermeier, Ashutosh Gupta, Marion Kerscher, Saskia Krieg, Bodo Martin, Gunasekaran Velmurugan and Shuyi Yang

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202103452

3d Transition Metals for C–H Activation

Parthasarathy Gandeepan, Thomas Müller, Daniel Zell, Gianpiero Cera, Svenja Warratz and Lutz Ackermann

Chem. Rev., 2019, 119, 2192
DOI: 10.1021/acs.chemrev.8b00507

Chemoselectivity in the Oxidation of Cycloalkenes with a Non-Heme Iron(IV)-Oxo-Chloride Complex: Epoxidation vs. Hydroxylation Selectivity

Thibault Terencio, Erik Andris, Ilaria Gamba, Martin Srnec, Miquel Costas and Jana Roithová

J. Am. Soc. Mass Spectrom., 2019, 30, 1923
DOI: 10.1007/s13361-019-02251-1

Highly Robust Iron Catalyst System for Intramolecular C(sp3)−H Amidation Leading to γ‐Lactams

Jeonguk Kweon and Sukbok Chang

Angewandte Chemie, 2021, 133, 2945
DOI: 10.1002/ange.202013499

Highvalent 3d metal-oxo mediated C–H halogenation: Biomimetic approaches

Jyoti Prasad Biswas, Srimanta Guin and Debabrata Maiti

Coordination Chemistry Reviews, 2020, 408, 213174
DOI: 10.1016/j.ccr.2019.213174

Ag(I) Complexes of Boron–Containing Schiff Base Ligands: Synthesis, Characterization, Properties and Thermal Stability

Dilek Çanakçı

Chemistry Africa, 2024, 7, 4241
DOI: 10.1007/s42250-024-01063-5

Understanding and Predicting Post H-Atom Abstraction Selectivity through Reactive Mode Composition Factor Analysis

Mauricio Maldonado-Domínguez and Martin Srnec

J. Am. Chem. Soc., 2020, 142, 3947
DOI: 10.1021/jacs.9b12800

Efficient Photolytic Halogenation and Oxidation of Unactivated Alkyl sp3 C—H Bonds with Iodine(III)

Hao Jia, Nan Li, Chunmei Tang, Yajuan Wang, Yonghao Xi, Rongbao Liao, Wei Xu, Fufang Wu, Xiaobao Shen and Hongbin Zhai

Chin. J. Chem., 2024, 42, 505
DOI: 10.1002/cjoc.202300544

Evidence for a High-Valent Iron-Fluoride That Mediates Oxidative C(sp3)-H Fluorination

Chakadola Panda, Onyinyechukwuka Anny-Nzekwue, Lorna M. Doyle, Robert Gericke and Aidan R. McDonald

JACS Au, 2023, 3, 919
DOI: 10.1021/jacsau.3c00021

The Protein’s Role in Substrate Positioning and Reactivity for Biosynthetic Enzyme Complexes: The Case of SyrB2/SyrB1

Rimsha Mehmood, Helena W. Qi, Adam H. Steeves and Heather J. Kulik

ACS Catal., 2019, 9, 4930
DOI: 10.1021/acscatal.9b00865