Additive-free N-methylation reaction synergistically catalyzed by Pt single atoms and clusters on α-MoC using methanol as a sustainable C1 source

Abstract

The synergistic effect of Pt single atoms and Pt clusters in the Pt_1+n/α-MoC catalyst plays a leading role in reductive N-methylation process, successfully realizing the green process by only using methanol as both hydrogen source and methylation reagents.

Continuous-flow reductive N-methylation with highly active heterogeneous Pd catalysts and sequential-flow synthesis of N-monomethyl amines

Abstract

We describe continuous-flow N-methylation with formaldehyde and H₂ using heterogeneous Pd catalysts as a green synthetic method to access N-methyl amines.

Exploring the reductive CO₂ fixation with amines and hydrosilanes using readily available Cu(II) NHC–phenolate catalyst precursors

Abstract

Readily available Cu(II) organometallic catalyst precursors allow the N-methylation of amines with CO₂ and hydrosilanes to be efficiently performed.

Ruthenium(II) arene complexes bearing simple dioxime ligands: effective catalysts for the one-pot transfer hydrogenation/N-methylation of nitroarenes with methanol

Abstract

Ruthenium(II) η⁶-arene complexes with easily-available dioxime ligands are efficient catalytic precursors for the selective reduction/N-methylation of aromatic nitrocompounds with methanol.

Sodium dithionite-mediated reductive N-acetylation/formylation of nitroarenes employing DMAc/DMF as acetyl/formyl surrogates

Abstract

The present report discloses a unified strategy for reductive N-acetylation/formylation directly from nitroarenes employing DMAc and DMF as the source of acetyl and formyl groups in the presence of sodium dithionite as the sole reagent.

Recent developments in homogeneous catalysis for the functionalisation of CO₂