Solvation and interfacial chemistry in ionic liquid based electrolytes toward rechargeable lithium-metal batteries

Haifeng Tu, Keyang Peng, Jiangyan Xue, Jingjing Xu, Jiawei Zhao, Yuyue Guo, Suwan Lu, Zhicheng Wang, Liquan Chen, Hong Li and Xiaodong Wu

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Strategic Surface Engineering of Lithium Metal Anodes: Simultaneous Native Layer Elimination and Protective Layer Formation via Gas–Solid Reaction

Siwon Choi, Seongwook Chae, Taemin Kim, Hyeonsol Shin, Jin-Gyu Bae, Seung Geol Lee, Ji Hoon Lee and Hyeon Jeong Lee

ACS Nano, 2025, 19, 16119
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Magneto-electrochemical synergistic lithiophilic high-entropy alloy enables durable lithium metal anode

Qi Jin, Fengfeng Han, Lirong Zhang, Haoyuan Song, Leirun Feng, Lili Wu, Xitian Zhang and Feng Li

Energy Storage Materials, 2025, 83, 104717
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Topological Li‐SbF3@Cu Alloying Anode for High‐Energy‐Density Li Metal Batteries

Jiaqi Cao, Yuansheng Shi, Dilxat Muhtar, Aosong Gao, Guoyu Qian, Xueyi Lu, Fangyan Xie, Yang Sun and Xia Lu

Advanced Materials, 2025, 37
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Dynamic regulation of lithium ions eliminating the lithium dendrite formation

Li Gao, Chenyi Sun, Xuetian Li, Jiachang Li and Xiufang Bian

Chemical Engineering Journal, 2025, 510, 161452
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Creating electrostatic shielding effects through dual-salt strategy to regulate coordination environment of Li⁺ and realize high-performance all-solid-state lithium metal batteries

Li Yang, Lilian Wang, Qingxia Hu, Mou Yang, Guiquan Zhao, Yunchun Zha, Qi An, Qing Liu, Haijiao Xie, Yongjiang Sun, Lingyan Duan, Xiaoxiao Zou, Genfu Zhao and Hong Guo

Energy Storage Materials, 2025, 77, 104210
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Regulated Li+ Solvation via Competitive Coordination Mechanism of Organic Cations for High Voltage and Fast Charging Lithium Metal Batteries

Jiangtao Yu, Xinyu Ma, Xiuyang Zou, Yin Hu, Mingchen Yang, Yuanli Cai and Feng Yan

Angewandte Chemie, 2025, 137
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Electric Field‐Induced Fast Li‐Ion Channels in Ionic Plastic Crystal Electrolytes for All‐Solid‐State Batteries

Xinyu Ma, Jiangtao Yu, Xiuyang Zou, Xiaoliang Wang, Huihui Wang, Yin Hu, Minzhi Duan, Songlin Tao, Shipeng Sun, Yanbin Shen and Feng Yan

Angew Chem Int Ed, 2025, 64
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Advanced Solid‐State Polymeric Lithium Metal Batteries via Inhibiting Side Reaction of Residual Solvents

Le Zhao, Zheting Liu, Wenyao Wang, Sihan Li, Na Chen, Chao Hu, Huapeng Sun, Huanhuan Li, Yougen Tang and Haiyan Wang

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Solvation Structures Tailored by the Steric Effect of Phosphorus‐Based Eutectic Electrolytes for Stable High‐Voltage Lithium‐Metal Batteries

Jialin Wang, Lin Xie, Wanbao Wu, Erlei Zhang, Chaochao Gao, Mi Wang and Jiaheng Zhang

Small, 2026, 22
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Emerging Surface Engineering Methods for Lithium Metal Anodes: Critical Review Beyond Conventional SEI and Surface Coatings

Jaehyeong Bae, Keonwoo Choi, Jun Young Cheong, Seongcheol Ahn, Suha Cho, Sung Gap Im and Il‐Doo Kim

Advanced Materials, 2025, 37
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Dynamic covalent synthesis of highly-crystalline and fully-cyclized aromatic COF as an artificial interphase layer toward stable lithium metal batteries

Wei Shao, Da Xu, Tiantian Wang, Huanghao Pan, Ying Liu, Xue Gao, Jiahuan Luo, Jing Wang, Zhong-Kun Li, Yao Guo, Huihui Zhao, Ning Fu, Ben Yang and Zhenglong Yang

Chemical Engineering Journal, 2025, 511, 161960
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Regulating anion chemistry in electrolytes from molecular principles to interphases engineering for high energy batteries

Huipeng Zeng, Kai Yu, Ruifan Lin, Hao Zhang and Jijian Xu

Sci. China Chem., 2025, 68, 6307
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Sub‐Nano Confinement Engineering Toward Anion‐Reinforced Solvation Structure to Achieve Highly Reversible Anode‐Free Lithium Metal Batteries

Jipeng Xu, Haoyuan Gu, Yingjie Wu, Yiting Lin, Minghui Zhu, Honglai Liu, Cheng Lian, Haiping Su and Jingkun Li

Advanced Energy Materials, 2025, 15
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The Key Role of Anion – Cationic Coordination on Anode Electric‐Double‐Layer Evolution for High Performance Lithium Metal Battery

Can Zhang, Yunpeng Guo, Xiaosheng Song, Peng Zhang, Yong Zhao and Xiaobing Wang

Adv Funct Materials, 2025, 35
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Molecular isolation layer constructed by planar conjugated organic molecules for highly durable Na/K metal anodes

Xinping Tao, Xiaolong Cheng, Yihong Gao, Licheng Miao, Huili Yu, Fanfan Liu, Pengcheng Shi, Yu Shao, Fangzhi Huang and Yu Jiang

Chemical Engineering Journal, 2025, 523, 168520
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Lithium Metal Batteries Enabled by Ion Flux‐Regulating Coating on Separator

Ke Wang, Teng Zhao, Ruixin Lv, Wangming Tang, Tianyang Yu, Li Li, Feng Wu and Renjie Chen

Adv Funct Materials, 2025, 35
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Organic/Inorganic Hybrid Cross-Linked Gel Polymer Electrolyte for Optimizing the Solvation Structure of Lithium Ions

Feng Yu, Shanming Zhang, Weijie Li, Wei Hao, Qiudian Liu, Wen Chen and Yong Chen

ACS Appl. Mater. Interfaces, 2025, 17, 4951
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Urea‐Linked Covalent Organic Framework as a Li‐Ion Guided Channel Enabling Ultra‐Stable Lithium Metal Anode in Carbonate‐Based Electrolyte

Caihong Zhang, Zhen Luo, Kean Chen, Chunxing Yan, Lezhi Yi, Chengtao Gong, Yuliang Cao and Fu‐Sheng Ke

Angew Chem Int Ed, 2025, 64
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Lithium Nitrate Effects for Lithium‐Based Chemical Batteries: A Review

Xianshu Wang, Junru Wu, Huirong Wang, Xiangshao Yin, Zhuo Zhou, Yuanyuan Huang, Yelong Zhang, Weishan Li and Baohua Li

Carbon Energy, 2026, 8
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An integrated ultrathin, tip-electrostatic-shielding and inorganic interphase-promoting polymeric electrolyte design for high-performance all-solid-state lithium metal batteries

Zhaofen Wang, Xingmin Yu, Yaoyao Liu, Lequan Deng, Shuhua Wang, Hong Liu, Jian-Jun Wang and Hao Chen

Nano Energy, 2025, 134, 110582
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Unlocking dendrite growth in metal batteries

Yunxiang Chen, Keliang Wang, Hengwei Wang, Tianfu Zhang and Daiyun Zhong

Progress in Materials Science, 2026, 158, 101633
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Kinetics‐Optimized Crown Ether Engineering Enables Ultra‐Flat Lithium Metal Interface for Long‐Cycling 532 Wh Kg−1 Pouch Cells

Chuang Sun, Yong Li, Tiefeng Liu, Shangshu Qian, Jianhui Zheng, Tianpin Wu, Mengting Zheng and Jun Lu

Advanced Materials, 2026, 38
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In situ engineered organic–inorganic bilayer solid electrolyte interphase enabling lithium metal batteries over 15,000-h lifespan

Bin Zhang, Ke Yue, Ke Wang, Guohao Zhao, Wenbin Huang, Tao Li, Jianmin Luo, Ying Xu and Xinyong Tao

eScience, 2026, 6, 100479
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Revealing the Competitive Reaction Mechanism Between Solid Electrolyte Interphase and Li Deposition Processes

Houguang Wen, Maolin Zhang, Saijing Wang, Wenqi Zhao, Zhuo Zhao, Yuan Wang, Yangxi Yan, Dongyan Zhang, Zi Yang and Xiaofei Sun

ACS Sustainable Chem. Eng., 2026, 14, 8111
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Cationic Organic Polymers With Electrostatic Shielding Effect and Lithiophilic Sites for Dendrite‐Free Lithium Metal Batteries

Songling Wu, Beisha Xu, Yibo Wu, Hao Li, Muhammad Ahsan Waseem, Junaid Aslam, Yi Xu, Yifan Zhang and Yong Wang

Angew Chem Int Ed, 2026, 65
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Construct a Quasi‐High‐Entropy Interphase for Advanced Low‐Temperature Aqueous Zinc‐Ion Battery

Feifan Li, Wendi Luo, Hongwei Fu, Wenjin Zhou, Caitian Gao, Yanfang Liu, Hang Xia, Zude Shi, Hong Wang, Jiang Zhou and Bingan Lu

Adv Funct Materials, 2025, 35
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De-solvation of heteroalkali cations enabling stable solid electrolyte interphase for dendrite-free lithium metal batteries

Aoyuan Chen, Junhao Wang, Wujie Yang, Lin Wang, Liang Zhou, Yu Qiao, Ping He and Haoshen Zhou

Nat Commun, 2025, 16
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Efficient Li+ Transport through a Single-Ion-Conducting Protective Layer for Stable Lithium–Metal Batteries

Xinyuan Shan, Caiyun Wang, Zhaowei Song, Sijin Jin, Jia Tian, Lengwan Li, Xin Ma, Linming Bai, Hang Ding, Sheng Zhao, Wei Niu, Bingrui Li, Alexei P. Sokolov, Huabin Yang, Zhihong Nie and Peng-Fei Cao

ACS Appl. Mater. Interfaces, 2026, 18, 18266
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Electric Field‐Induced Fast Li‐Ion Channels in Ionic Plastic Crystal Electrolytes for All‐Solid‐State Batteries

Xinyu Ma, Jiangtao Yu, Xiuyang Zou, Xiaoliang Wang, Huihui Wang, Yin Hu, Minzhi Duan, Songlin Tao, Shipeng Sun, Yanbin Shen and Feng Yan

Angewandte Chemie, 2025, 137
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Fast charging Lithium metal battery based on Lewis Acid/Base dual-site solid electrolyte interphase

Minjian Li, Lianzhan Huang, Boyong Wu, Jinhui Liang, Jiahao Xiang, Tong Yan, Mengli Tao, Li Du, Zhiming Cui, Huiyu Song and Zhenxing Liang

Energy Storage Materials, 2025, 75, 104069
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Advances and challenges in electrolyte design for high-performance lithium batteries

Chong Xu, Rui Wu, Shuang Liu, Gong Cheng, Guang Ma, Yan Jia and Yongfeng Li

Energy Storage Materials, 2026, 88, 105112
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Strong Lewis Acid Effect in the Pores of Metal–Organic Framework Host for Dendrite‐Free Lithium Deposition and Stripping

Runhao Zhang, Jialong Jiang, Jiachen Guo, Xuelong Liao, Jingwei Liu, Huan Wang, Jun Xu, Dapeng Cao, Peng Cheng and Wei Shi

Advanced Materials, 2025, 37
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Dynamics-enhanced sandwich solid-state electrolyte separator for wide-temperature operation of lithium metal batteries

Huipeng Zeng, Qingrong Wang, Chunyu Liu, Kai Yu, Ruilin He, Xiaoqi Wu, Xu Yan, Guangzhao Zhang, Hongli Xu, Jun Wang, Chaoyang Wang, Jijian Xu, Yonghong Deng, Xiaoxiong Xu and Shang-Sen Chi

Energy Storage Materials, 2025, 82, 104614
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Tailoring Na-ion flux homogenization strategy towards long-cycling and fast-charging sodium metal batteries

Lin Zhou, Shengwei Dong, Zhuomin Qiang, Chaoqun Zhang, Anran Shi, Yanbin Ning, Ziwei Liu, Cong Chen, Yan Zhang, Dalong Li and Shuaifeng Lou

Journal of Energy Chemistry, 2025, 102, 516
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Urea‐Linked Covalent Organic Framework as a Li‐Ion Guided Channel Enabling Ultra‐Stable Lithium Metal Anode in Carbonate‐Based Electrolyte

Caihong Zhang, Zhen Luo, Kean Chen, Chunxing Yan, Lezhi Yi, Chengtao Gong, Yuliang Cao and Fu‐Sheng Ke

Angewandte Chemie, 2025, 137
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Recent progress of artificial SEI for high-energy lithium batteries: Mechanisms, fabrication strategies and structure-performance relationships

Yalin Zhang, Zewei Wei, Xuedi Yuan, Yuxuan Qiu, Yingjun Cai, Lihuan Xu and Haitao Zhang

Nano Energy, 2025, 142, 111219
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Dual-Ion Confined-Region Channels Enable Rapid Ion Transport for All-Solid-State Lithium Metal Batteries

Xinyu Ma, Jiangtao Yu, Xia Gui, Yue Liu, Yin Hu, Lening Pan, Yupo She, Yu Kuang, Tao Cheng and Feng Yan

J. Am. Chem. Soc., 2026, 148, 8784
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Regulated Li+ Solvation via Competitive Coordination Mechanism of Organic Cations for High Voltage and Fast Charging Lithium Metal Batteries

Jiangtao Yu, Xinyu Ma, Xiuyang Zou, Yin Hu, Mingchen Yang, Yuanli Cai and Feng Yan

Angew Chem Int Ed, 2025, 64
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In Situ Construction of Zinc Carbodiimides‐Derived Composite Artificial Protective Layer for High Performance Lithium Metal Batteries

Xiaoxuan Li, Jiafeng Li, Ruixiao Zhu, Yutong Zhao, Xiaobin Hui, Zhiwei Zhang, Chengxiang Wang and Longwei Yin

Small Methods, 2025, 9
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Cationic Organic Polymers With Electrostatic Shielding Effect and Lithiophilic Sites for Dendrite‐Free Lithium Metal Batteries

Songling Wu, Beisha Xu, Yibo Wu, Hao Li, Muhammad Ahsan Waseem, Junaid Aslam, Yi Xu, Yifan Zhang and Yong Wang

Angewandte Chemie, 2026, 138
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