Issue 1, 2024

Efficient end-group functionalization and diblock copolymer synthesis via Au(iii) polymer reagents

Abstract

Herein, we describe the synthesis of bench-stable organometallic Au(III) terminated polymer reagents. These reagents mediate the chemoselective S-arylation of thiol-containing small molecules and polymers to yield functionalized mono-telechelic polymers and diblock copolymers, respectively. These transformations proceed rapidly within minutes and produce conjugates in quantitative conversion, making this strategy a robust addition to the polymer functionalization toolbox.

Graphical abstract: Efficient end-group functionalization and diblock copolymer synthesis via Au(iii) polymer reagents

Supplementary files

Article information

Article type
Communication
Submitted
31 Հկտ 2023
Accepted
29 Նյմ 2023
First published
30 Նյմ 2023

Chem. Commun., 2024,60, 79-82

Efficient end-group functionalization and diblock copolymer synthesis via Au(III) polymer reagents

G. E. Kunkel, J. W. Treacy, H. R. Montgomery, E. G. Puente, E. A. Doud, A. M. Spokoyny and H. D. Maynard, Chem. Commun., 2024, 60, 79 DOI: 10.1039/D3CC05350D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements