Issue 96, 2023

Intramolecular C–N bond activation by a transient boryl anion

Abstract

Using a flexible diamido framework, a bulky boron bromide has been prepared as a precusor to a boryl anion with an extremely wide N–B–N angle. Reduction of the compound with lithium metal resulted in intramolecular C–N bond activation and migration of an aryl group onto the boron centre. Reaction of the boron bromide with K[FeCp(CO)2] resulted in nucleophilic reactivity of a carbonyl oxygen and the cooperative activation of CO.

Graphical abstract: Intramolecular C–N bond activation by a transient boryl anion

Supplementary files

Article information

Article type
Communication
Submitted
21 Հկտ 2023
Accepted
09 Նյմ 2023
First published
09 Նյմ 2023

Chem. Commun., 2023,59, 14281-14284

Intramolecular C–N bond activation by a transient boryl anion

E. E. Nahon, G. R. Nelmes, P. J. Brothers and J. Hicks, Chem. Commun., 2023, 59, 14281 DOI: 10.1039/D3CC05182J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements