AuB8−: an Au–borozene complex

Wei-Jia Chen; Yang-Yang Zhang; Wan-Lu Li; Hyun Wook Choi; Jun Li; Lai-Sheng Wang

doi:10.1039/D1CC07303F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

AuB₈⁻: an Au–borozene complex†

Wei-Jia Chen,‡^a Yang-Yang Zhang,‡^b Wan-Lu Li,^b Hyun Wook Choi,^a Jun Li

*^bc and Lai-Sheng Wang

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Brown University, Providence, RI 02912, USA
E-mail: lai-sheng_wang@brown.edu

^b Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084, China
E-mail: junli@tsinghua.edu.cn

^c Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China

Abstract

Photoelectron spectroscopy and quantum chemistry studies are used to investigate the structure and bonding of AuB₈⁻. Global minimum sturctural searches show that AuB₈⁻ possesses a chair-like structure, which can be viewed as Au⁺ bonded to the edge of the doubly-aromatic B₈²⁻ borozene, Au⁺[η²-B₈²⁻]. Chemical bonding analyses reveal that the AuB₈⁻ is a novel borozene complex with unique Au–borozene bonding.

This article is part of the themed collections: Boron Chemistry in the 21st Century: From Synthetic Curiosities to Functional Molecules and Chemical Communications HOT Articles 2022

Download options Please wait...

Supplementary files

Supplementary information PDF (1782K)

Article information

DOI: https://doi.org/10.1039/D1CC07303F
Article type: Communication
Submitted: 06 Հնվ 2022
Accepted: 09 Փտվ 2022
First published: 09 Փտվ 2022

Download Citation

Chem. Commun., 2022,58, 3134-3137

Author version available

Download author version (PDF)

Permissions

Request permissions

AuB₈⁻: an Au–borozene complex

W. Chen, Y. Zhang, W. Li, H. W. Choi, J. Li and L. Wang, Chem. Commun., 2022, 58, 3134 DOI: 10.1039/D1CC07303F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications