The synthesis of a (phosphino)(stannyl)carbene is documented. The combination of phosphino and stannyl substituents imparts a highly ambiphilic nature to this carbene, enabling reactions with cyanide, isocyanide, and carbon monoxide. This leads to rare stannylketenimines and a stannylketene.
R. Wei, X. Wang, C. Hu and L. L. Liu, Chem. Commun., 2024, 60, 9793 DOI: 10.1039/D4CC03275F
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