A phenanthroline-containing covalent triazine framework metalated with Ni sites (Ni-PT-CTF) has been rationally designed and synthesized, which shows excellent photocatalytic performance for CO2 conversion into CO under visible light irradiation.
In this study, 2 to 4 nm ruthenium nanoparticles were loaded by decomposition of Ru3(CO)12 through microwave heating on thiophene containing CTFs to assess the influence of thiophene on the electrocatalytic properties in the hydrogen evolution reaction.
Schematic representation of covalent triazine framework deposited over Cu2O/SnO2 nanostructures for enhanced photocatalytic CO2 reduction to produce primarily CO and CH4.
Viologen derivatives with non-conjugated substituent groups sharply promoted photocatalytic HER performance under o-CTF photocatalysis, while viologen derivatives with conjugated substituent groups decreased the photocatalytic HER rate.
A novel pyridine-bridged covalent triazine framework (CTF), BenP-CTF, exhibited much higher photocatalytic activity for water splitting to hydrogen than benzene-bridged Ben-CTF and thiophene-bridged BenT-CTF due to enhanced built-in electric field.