Environmental applications of metal–organic framework-based three-dimensional macrostructures: a review

Cheng Chen, Liguo Shen, Boya Wang, Xinchun Lu, Saleem Raza, Jiujing Xu, Bisheng Li, Hongjun Lin and Banglin Chen

Chem. Soc. Rev., 2025, 54, 2208
DOI: 10.1039/D4CS00435C

Zeolitic imidazolate framework-enhanced conductive nanocomposite hydrogels with high stretchability and low hysteresis for self-powered multifunctional sensors

Jishuai Xu, Jingye Liang, Jingxuan Zheng, Fangying Lu, Yilian Ma, Hanbing Yu, Weiqiang Zhao, Run Wang and Zunfeng Liu

J. Mater. Chem. A, 2025, 13, 12256
DOI: 10.1039/D4TA08994D

Metal sulfide-based nanomaterials for electrochemical CO2 reduction

Anirban Mukherjee, Maryam Abdinejad, Susanta Sinha Mahapatra and Bidhan Chandra Ruidas

J. Mater. Chem. A, 2023, 11, 9300
DOI: 10.1039/D2TA08209H

Lanthanide-based metal–organic frameworks (Ln-MOFs): synthesis, properties and applications

Kankan Patra and Haridas Pal

RSC Sustainability, 2025, 3, 629
DOI: 10.1039/D4SU00271G

A self-cascade system based on Ag nanoparticle/single-walled carbon nanotube nanocomposites as an enzyme mimic for ultrasensitive detection of l-cysteine

Feifei Li, Congcong Hu, Wenen Su, Hao Liang, Fubing Xiao, Jinquan Liu, Yan Tan and Shengyuan Yang

Anal. Methods, 2023, 15, 3251
DOI: 10.1039/D3AY00445G

Mechanical, robust and conductive eco-friendly self-assembling hydrogel: a novel material for electromagnetic shielding

Yuhuan Xu, Meng Pei, Xiao Zhan, Hongwei Wang, Daohai Zhang and Shuhao Qin

New J. Chem., 2023, 47, 21475
DOI: 10.1039/D3NJ04508K

The synergy of metal–organic frameworks and biomaterials for bone tissue engineering: recent advances, challenges, and future recommendations

Luan Minh Nguyen, Yufeng Wang, Giao Thuy Quynh Vu, Qui Thanh Hoai Ta, Dieu Linh Tran, Ngoc Hoi Nguyen, Thuan Van Tran, Chao Zhang and Dai Hai Nguyen

Nanoscale Adv., 2025, 7, 5479
DOI: 10.1039/D5NA00279F

Advances in conducting nanocomposite hydrogels for wearable biomonitoring

Arpita Roy, Ronak Afshari, Saumya Jain, Yuting Zheng, Min-Hsuan Lin, Shea Zenkar, Junyi Yin, Jun Chen, Nicholas A. Peppas and Nasim Annabi

Chem. Soc. Rev., 2025, 54, 2595
DOI: 10.1039/D4CS00220B

UiO-66 (Zr)-F4 MOF reinforced anti-freezing and stretchable piezoelectric hydrogel-based triboelectric nanogenerator for self-powered epidermal electronics in sub-zero temperatures and real-time ice-cracking alarm system

Debmalya Sarkar, Nishat Kumar Das, Koushik K. Rao and Sushmee Badhulika

Chemical Engineering Journal, 2025, 521, 166528
DOI: 10.1016/j.cej.2025.166528

Recent Advances in Biomacromolecule‐Reinforced 2D Material (2DM) Hydrogels: From Interactions, Synthesis, and Functionalization to Biomedical Applications

Guanghui Gu, Zichen Cui, Xiaofan Du, Peng He, Chun Rong, Hao Tao, Gang Wei and Yongming Xi

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202408367

Design and development of metal-organic framework-based nanocomposite hydrogels for quantification of deferiprone in exhaled breath condensate

Reza Moharami, Zahra Karimzadeh, Jafar Soleymani, Vahid Jouyban-Gharamaleki, Maryam Khoubnasabjafari, Elaheh Rahimpour and Abolghasem Jouyban

BMC Chemistry, 2024, 18
DOI: 10.1186/s13065-024-01294-0

Advances in the Preparation of Hydrogels Based on Metal-Organic Frameworks and Their Applications

凤钏郭

NAT, 2025, 15, 61
DOI: 10.12677/nat.2025.153008

Recent Advances in Engineered MoS2-Based Nanomaterials for CO2 Electro-Reduction to CO and Beyond

Anirban Mukherjee, Niwesh Ojha, Kamal Kishore Pant, Aniruddha Deb, Maryam Abdinejad, Susanta Sinha Mahapatra and Bidhan Chandra Ruidas

Environ. Sci. Technol. Lett., 2025, 12, 1113
DOI: 10.1021/acs.estlett.5c00465

Highly sensitive fluorometric ammonia detection utilizing Solenostemon scutellarioides (L.) extracts in MOF-tragacanth gum hydrogel for meat spoilage monitoring

Habibeh Hashemian, Mehrorang Ghaedi, Kheibar Dashtian, Sikandar Khan, Soleiman Mosleh, Shaaker Hajati and Damoun Razmjoue

Sensors and Actuators B: Chemical, 2024, 406, 135354
DOI: 10.1016/j.snb.2024.135354

Triple microenvironment modulation of zeolite imidazolate framework (ZIF) nanocages for boosting dopamine electrocatalysis

Wang Sun, Junyan Liu, Xiaoqian Zha, Guorong Sun and Yang Wang

Journal of Colloid and Interface Science, 2024, 654, 1
DOI: 10.1016/j.jcis.2023.10.022

A core-shell heterostructured hybrid nanomaterial of bi-metallic MOFs and COFs: Improved 2,4,6-trichlorophenol charge collection

Wang Sun, Huacong Chu, Junyan Liu, Na Wang and Yang Wang

Sensors and Actuators B: Chemical, 2023, 393, 134146
DOI: 10.1016/j.snb.2023.134146

Gelatin Enhanced Gels with Superior Self-Healing and Freezing-Tolerant Properties for Multifunctional Flexible Strain Sensors

Wei Gao, Guangchao Zheng, Zhiming Yang, Xinxian Ma and Zhiqiang Wu

Ind. Eng. Chem. Res., 2024, 63, 10627
DOI: 10.1021/acs.iecr.4c01056

Recent advances in multifaceted applications of MOF-based hydrogels

Rui He, Jiajun He, Jie Shen, Huide Fu, Yabin Zhang and Ben Wang

Soft Sci, 2024, 4
DOI: 10.20517/ss.2024.32

Harnessing Cu- and Fe-based metal-organic frameworks as innovative nanocarriers for enhanced fluconazole delivery in topical management of Candida albicans

Mrunali Patel, Jigisha Panchal, Richa Dave, Jigar Nandha, Mitesh Patel, Bhavtosh Kikani, Alkesh Patel, Vanarajsinh Solanki, Mahendra Rai and Rashmin Patel

Journal of Drug Delivery Science and Technology, 2025, 107, 106854
DOI: 10.1016/j.jddst.2025.106854

Portable Electroanalytical Platform Based on Eco-Friendly Biomass-Based Hydrogels with Bimetallic MOF Composites for Trace Acetaminophen Determination

Junyan Liu, Wang Sun, Guorong Sun, Xiang Huang, Shun Lu and Yang Wang

ACS Biomater. Sci. Eng., 2025, 11, 649
DOI: 10.1021/acsbiomaterials.4c01751

Imipenem/cilastatin encapsulation in UIO-66-NH2 carrier as a new strategy for combating imipenem-resistant Pseudomonas aeruginosa isolates

Shakila Baei Lashaki, Pooria Moulavi, Fatemeh Ashrafi, Aram Sharifi and Sepideh Asadi

Journal of Global Antimicrobial Resistance, 2025, 42, 15
DOI: 10.1016/j.jgar.2025.01.010

Iron-based metal–organic frameworks and their derived materials for photocatalytic and photoelectrocatalytic reactions

Yangdan Pan, Reza Abazari, Beenish Tahir, Soheila Sanati, Yanchun Zheng, Muhammad Tahir and Junkuo Gao

Coordination Chemistry Reviews, 2024, 499, 215538
DOI: 10.1016/j.ccr.2023.215538

Improving the effectiveness of anticancer properties of capecitabine using aminocaproic acid-hyaluronic acid/sulfonamide IR-MOF nanoplatform for colon cancer treatment

Sedigheh Alavinia, Ramin Ghorbani-Vaghei, Rasool Haddadi, Khashayar Sanemar, Seyed Sepehr Uroomiye and Alireza Nourian

Carbohydrate Polymer Technologies and Applications, 2025, 10, 100827
DOI: 10.1016/j.carpta.2025.100827

Recent progress in functional metal–organic frameworks for bio-medical application

Wenwen Chai, Xiaochen Chen, Jing Liu, Liyan Zhang, Chunyu Liu, Li Li, John Robert Honiball, Haobo Pan, Xu Cui and Deping Wang

Regenerative Biomaterials, 2024, 11
DOI: 10.1093/rb/rbad115

Smart nano-hybrid metal-organic frameworks: Revolutionizing advancements, applications, and challenges in biomedical therapeutics and diagnostics

Dilip Kumar Chandra, Awanish Kumar and Chinmaya Mahapatra

Hybrid Advances, 2025, 9, 100406
DOI: 10.1016/j.hybadv.2025.100406

Nanoarchitectonics of Metal–Organic Framework and Nanocellulose Composites for Multifunctional Environmental Remediation

Ye Song, Wenkai Zhu, Chaohai Wang, Zequn Li, Ruiqi Xin, Dujuan Wu, Xiaofan Ma, Hanwei Wang, Xiangyu Wang, Song Li, Jeonghun Kim, Qingfeng Sun, Minjun Kim and Yusuke Yamauchi

Advanced Materials, 2025
DOI: 10.1002/adma.202504364

Environmental contaminant analysis: Concerns inspiring the emergence of MOF composites

Mahsa Shirkhodaie, Shahram Seidi, Farzaneh Shemirani and Farnaz Zaroudi

TrAC Trends in Analytical Chemistry, 2023, 164, 117109
DOI: 10.1016/j.trac.2023.117109

Controllable assembly of hollow interpenetrated zeolite imidazole framework nanocomposite for dopamine charge collection

Wang Sun, Junyan Liu, Huacong Chu and Yang Wang

Microchim Acta, 2024, 191
DOI: 10.1007/s00604-023-06137-8

Advances in surface functionalization of next-generation metal-organic frameworks for biomedical applications: Design, strategies, and prospects

Xu Chen, Sergio Mercado Argandona, Francesca Melle, Nakul Rampal and David Fairen-Jimenez

Chem, 2024, 10, 504
DOI: 10.1016/j.chempr.2023.09.016

Synthesis and Cytotoxicity Studies of Poly(1,4-butanediol citrate) Gels for Cell Culturing

Aleksandra Bandzerewicz, Klara Niebuda and Agnieszka Gadomska-Gajadhur

Gels, 2023, 9, 628
DOI: 10.3390/gels9080628

Fabrication of a MIP-CuMOFs@SA-CS electrochemical sensor based on CuHCF for the highly selective detection of chelerythrine

Lijun Huang, Yuliang Liu, Xingxin Sheng, Yongbo Zhu, Xinyi Li, Meng Liang, Hao Xie, Ming Zhong and Binbin Zhou

Microchemical Journal, 2025, 209, 112743
DOI: 10.1016/j.microc.2025.112743

An Injectable Nanocomposite IPN Hydrogel Based on Gelatin Methacrylate/Alginate/COF for Tissue Engineering Applications

Samin Saleki, Saied Nouri Khorasani, Shahla Khalili, Mahshid Hafezi, Mahsa Najarzadegan, Mohammad Reza Molaviyan, Mohammad Dinari and Ali Kakapour

Macro Materials & Eng, 2024, 309
DOI: 10.1002/mame.202300417

MOF–Thermogel Composites for Differentiated and Sustained Dual Drug Delivery

Xin Li, Tristan T. Y. Tan, Qianyu Lin, Chen Chuan Lim, Rubayn Goh, Ken-ichi Otake, Susumu Kitagawa, Xian Jun Loh and Jason Y. C. Lim

ACS Biomater. Sci. Eng., 2023, 9, 5724
DOI: 10.1021/acsbiomaterials.3c01103

Metal–Organic Framework and Biopolymer-Based Composite Hydrogel for Enhanced Encapsulation of Anticancer Drugs: A New Age Transdermal Drug Delivery Vehicle

Hiral Ukani, Nildhara Parsana, Sanjay Mehra, Arvind Kumar, Imran Khan, Mohammed A. Assiri and Naved Malek

ACS Appl. Eng. Mater., 2024, 2, 2583
DOI: 10.1021/acsaenm.4c00508

Development and characterization of hydrogel beads with carboxymethyl chitosan/graphene quantum dots@Pectin/MIL-88 for targeted doxorubicin delivery: An adaptable nanocomposite approach

Iman Gholamali and Mehdi Yadollahi

International Journal of Biological Macromolecules, 2025, 290, 139044
DOI: 10.1016/j.ijbiomac.2024.139044

Exploring porous hybrid metal–organic framework hydrogel as a potential platform in drug delivery systems

Kamal Essifi, Abdelqader El Guerraf, Mohamed Brahmi, Abdelouahab El Hadrami, Rachid Brahmi, Amine Moubarik and Abdesselam Tahani

Interactions, 2025, 246
DOI: 10.1007/s10751-025-02277-w

Insights into microscopic fabrication, macroscopic forms and biomedical applications of alginate composite gel containing metal-organic frameworks

Yuanke Zhang, Lvyao Yang, Min Zhou, Yanhua Mou, Dongmei Wang and Peng Zhang

Asian Journal of Pharmaceutical Sciences, 2024, 19, 100952
DOI: 10.1016/j.ajps.2024.100952

Biocompatible dually reinforced gellan gum hydrogels with selective antibacterial activity

Xixi Jin, Cuicui Wang, Zhaolong Sun, Yudong Lian, Quan Ji, Jinglong Tang and Xiaomei Ma

Carbohydrate Polymers, 2025, 351, 123071
DOI: 10.1016/j.carbpol.2024.123071

Emerging metal-organic framework (MOF)-based biosensors with high potential for point-of-care determination of biomarkers: Mechanisms and applications

Mohammad Ali Farzin, Seyed Morteza Naghib and Navid Rabiee

TrAC Trends in Analytical Chemistry, 2025, 191, 118345
DOI: 10.1016/j.trac.2025.118345

Lignin/carbon dots-embedded cellulose nanofibrils hydrogel: An effective, inexpensive and versatile platform for doxycycline adsorption and determination

Meng Liu, Xinmiao Qi, Jiayu Ouyang, Ping Jiang, Xin Guo and Yiqiang Wu

Industrial Crops and Products, 2024, 220, 119300
DOI: 10.1016/j.indcrop.2024.119300

Direct White-Light Emitting From a Single Metal–Organic Framework with Dual Phosphorescence Peaks

Xiao-Gang Yang, Ying-Jun Chen, Pei-Pei Yin, Jia-Wei Diao, Yi-Yang Cheng and Lu-Fang Ma

Inorg. Chem., 2023, 62, 19389
DOI: 10.1021/acs.inorgchem.3c03348

Three-dimensional hydrangea-like layered double hydroxide anchoring hollow metal organic-framework for efficient adsorption of 2, 4-dichlorophenoxyacetic acid

Xiaoqian Zha, Wang Sun, Junyan Liu, Guorong Sun, Shun Lu and Yang Wang

Materials Today Chemistry, 2024, 35, 101883
DOI: 10.1016/j.mtchem.2023.101883

ZIF-67 MOF-Derived Mn3O4 @ N-Doped C as a Supercapacitor Electrode in Different Alkaline Media

Amal F. Seliem, Ayeda Y. A. Mohammed, A. Attia, Salma Aman, Naseeb Ahmad and Mohamed M. Ibrahim

ACS Omega, 2024
DOI: 10.1021/acsomega.4c00676

Metal Organic Frameworks (MOFs) as Advanced Functional Materials for Food Applications

Mahmood Alizadeh Sani, Gholamreza Jahed-Khaniki, Nabi Shariatifar, Arezou Khezerlou, Amirhossein Abedini, Mohammad Rezvani-Ghalhari, Shokoufeh Hassani, Milad Tavassoli and David Julian McClements

ACS Food Sci. Technol., 2024, 4, 2272
DOI: 10.1021/acsfoodscitech.4c00354

Investigation of adsorption of Fluorouracil as anticancer drug on C82, Si82, Ti-C82 and Ti-Si82 nanocages

Ali Jihad, Jamal A. Aljabbar Attawi, Uday Abdul-Reda Hussein, Muhja Ahmed, Ahmad Ismael Saber, Sarah A. Hamood, Benien M. Ridha and Ali H. Alsalamy

Inorganic Chemistry Communications, 2023, 155, 111115
DOI: 10.1016/j.inoche.2023.111115

Rapid Preparation Triggered by Visible Light for Tough Hydrogel Sensors with Low Hysteresis and High Elasticity: Mechanism, Use and Recycle‐by‐Design

Qi Liu, Mingwei Xie, Chenghao Wang, Mingming Deng, Ping Li, Xulin Yang, Nihui Zhao, Chi Huang and Xinghua Zhang

Small, 2024, 20
DOI: 10.1002/smll.202311647

Development of sustainable polyester biocomposites using Lansium parasiticum fruit shell powder and hemp chopped fibre: mechanical, wear, hydrophobic and flammability behaviour

Kannapiran Karuppasamy and Baskaran Ranganathan

Biomass Conv. Bioref., 2024, 14, 5745
DOI: 10.1007/s13399-023-05199-1

Poly(vinyl alcohol)/Chitosan Hydrogel Containing Gallic Acid-Modified Fe, Cu, and Zn Metal–Organic Frameworks (MOFs): Preparation, Characterization, and Biological Applications

Reza Sacourbaravi, Zeinab Ansari-Asl, Elham Hoveizi and Esmaeil Darabpour

ACS Appl. Mater. Interfaces, 2024, 16, 61609
DOI: 10.1021/acsami.4c11053

Review on biomaterial applications of photoresponsive based chromophore Hydrogels: Recent developments and future perspectives

Mani Rajasekar, Venugopal Kavyashree, Elango Sangamithra, Pavithra Baskaran, Michelle Faustina Maria, Jennita Mary, Meenamigai Sivakumar and Masilamani Selvam

Results in Chemistry, 2024, 7, 101462
DOI: 10.1016/j.rechem.2024.101462

Nanocomposite hydrogel fibers in the field of diagnosis and treatment

Zhenguo Yu, Dong Wang and Zhentan Lu

AIMSMATES, 2023, 10, 1004
DOI: 10.3934/matersci.2023054

Hydrogel materials in agriculture: A review

Hanghang Wang, Guangfei Qu, Xinxin Liu, Minjie He, Chenyang Yin and Rui Xu

Journal of Environmental Chemical Engineering, 2025, 13, 116385
DOI: 10.1016/j.jece.2025.116385

In Vitro and In Vivo Evaluation of Hyaluronic Acid/PVA/Chitosan Incorporated ZiF-8 Hydrogels for Wound Healing Applications

Tooba Yasin, Hayat M. Albishi, Thamir M. Eid, Aneela Javed, Ali Zohaib, Muhammad Khalid Mansoor and Muhammad Umar Aslam Khan

J Inorg Organomet Polym, 2025
DOI: 10.1007/s10904-025-03954-7

Natural Polymer-Based Hydrogels: From Polymer to Biomedical Applications

Lingling Zhao, Yifan Zhou, Jiaying Zhang, Hongze Liang, Xianwu Chen and Hui Tan

Pharmaceutics, 2023, 15, 2514
DOI: 10.3390/pharmaceutics15102514

Tailoring Nanomaterial Cross-Linkers through Lanthanide–Ligand Pairs: Guidance for Fine-Tuning the Structures and Properties of Luminescent Nanocomposite Hydrogels

Yu-Chia Su, Li Chu Tseng, Wei-Tao Peng, Chao-Ping Hsu and Yi-Cheun Yeh

Inorg. Chem., 2025, 64, 8601
DOI: 10.1021/acs.inorgchem.5c00130

Recyclable thiol-modified Zr-based MOFs/hydrogel composite beads for effective removal of Hg (II)

Xuechun Wang, Zeming Dai, Xuan Zhou, Hao Chen, Yu Cao, Jianhua Hou and Xiaozhi Wang

Progress in Natural Science: Materials International, 2023, 33, 644
DOI: 10.1016/j.pnsc.2023.11.009

Design and optimization of WSe2@NiCo-MOF for dual-mode applications: energy storage and chemosensing

Nabeela Akhtar, Nimra Muzaffar, Muhammad Imran, Amir Muhammad Afzal, Muhammad Waqas Iqbal, Samia Safdar, Aboud Ahmed Awadh Bahajjaj, Sohail Mumtaz, Muhammad Zahir Iqbal and Muhammad Azeem

Phys. Scr., 2024, 99, 125992
DOI: 10.1088/1402-4896/ad92c1

Oriented Self‐assembly of Flexible MOFs Nanocrystals into Anisotropic Superstructures with Homogeneous Hydrogels Behaviors

Xiaoyan Mao, Xinqi Ding, Qi Wang, Xiping Sun, Lei Qin, Fei Huang, Luhong Wen and Xingwei Xiang

Small, 2024, 20
DOI: 10.1002/smll.202308739

Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs)-based prototyping of integrated sensing devices for robust analysis

Yingjia Liu, Pengfei Li, Rongwei Cui, Chunlian Qin, Linke Wu, Xunzhi Zhang, Bing Li, Jianfeng Ping, Yixian Wang, Jinming Pan, Yibin Ying, Danyang Li, Da Shi and Lizhou Xu

TrAC Trends in Analytical Chemistry, 2024, 174, 117678
DOI: 10.1016/j.trac.2024.117678

Gold nanoparticle decorated post-synthesis modified UiO-66-NH2 for A3-coupling preparation of propargyl amines

Leila Mohammadi, Reza Taghavi, Mojtaba Hosseinifard, Mohammad Reza Vaezi and Sadegh Rostamnia

Sci Rep, 2023, 13
DOI: 10.1038/s41598-023-35848-4

Design of N, O-Rich Functionalized Core–Shell Adsorbent for Efficient Extraction of Co(II) and Reuse in Oxygen Evolution Reaction

Huizhen Sun, Xiuhua Chen, Wenhui Ma, Shaoyuan Li, Chen Li, Dandan Wu, Kaixin Fu, Mingjun Xiao and Ming Wen

ACS Sustainable Chem. Eng., 2025, 13, 12469
DOI: 10.1021/acssuschemeng.5c03248

Adsorption of antibiotics in medical wastewater by MOF-based hydrogel composites: A comprehensive review

Meie Zheng, Yujia Shao, Fei Ma, Wenwen Li and Mengru Guo

Journal of Water Process Engineering, 2025, 76, 108268
DOI: 10.1016/j.jwpe.2025.108268

Application of metal-organic frameworks-based functional composite scaffolds in tissue engineering

Xinlei Yao, Xinran Chen, Yu Sun, Pengxiang Yang, Xiaosong Gu and Xiu Dai

Regenerative Biomaterials, 2024, 11
DOI: 10.1093/rb/rbae009

Metal and Covalent Organic Frameworks Meet OB‐GYN: Advancing Applications in Women's Health and Pregnancy Care

Yue Shi, Muling Zeng, Eudald Casals, Gregori Casals and Ning Liu

Small, 2025, 21
DOI: 10.1002/smll.202504366

Zinc‐based metal–organic frameworks for encapsulation and sustained release of ciprofloxacin for excellent antibacterial activities

Abdul Rauf, Mohsin Javed, Muhammad Jahangir, Mehdi Hassan, Anam Tariq, Wajahat Ali, Ali Bahadur, Shahid Iqbal, Sajid Mahmood, Khalid M Alotaibi and Matar Alshalwi

J of Chemical Tech & Biotech, 2024, 99, 2545
DOI: 10.1002/jctb.7736

Recent progress of MOF-based antibacterial hydrogels

Ting Yao, Xianxiang Zeng, Xueying Tao and Hengyi Xu

Chemical Engineering Journal, 2024, 487, 150641
DOI: 10.1016/j.cej.2024.150641

Metal-organic framework-hydrogel composites as emerging platforms for enhanced wound healing applications: Material design, therapeutic strategies, and future prospects

Fereshte Hassanzadeh Afruzi, Majid Abdouss, Ehsan Nazarzadeh Zare, Erfan Rezvani Ghomi, Shima Mahmoudi and Rasoul Esmaeely Neisiany

Coordination Chemistry Reviews, 2025, 524, 216330
DOI: 10.1016/j.ccr.2024.216330