Advances in chemistry of CALF-20, a metal–organic framework for industrial gas applications

Joanna Drwęska, Kornel Roztocki and Agnieszka M. Janiak

Chem. Commun., 2025, 61, 1032
DOI: 10.1039/D4CC05744A

Efficient solvent-free mechanochemical synthesis of CALF-20 for carbon dioxide capture

Natchaya Phongsuk, Chalarat Chaemchamrat, Taya Ko Saothayanun, Nopphon Weeranoppanant and Sareeya Bureekaew

CrystEngComm, 2025, 27, 5959
DOI: 10.1039/D5CE00632E

Thermally-induced phase transformations of CALF-20: insights into its phase stability and carbon capture properties

Dong A. Kang, Navaporn Suphavilai, Amro M. O. Mohamed, Ioannis G. Economou, Manish Shetty, Jinsoo Kim and Hae-Kwon Jeong

J. Mater. Chem. A, 2025, 13, 18892
DOI: 10.1039/D5TA01729G

Hydrogen storage of commercially scalable CALF-20: a study at cryogenic and near-ambient temperatures

Ashley L. Sutton, M. Munir Sadiq, James I. Mardel and Matthew R. Hill

CrystEngComm, 2024, 26, 6003
DOI: 10.1039/D4CE00861H

Contracting pore channels of a magnesium-based metal–organic framework by decorating methyl groups for effective Xe/Kr separation

Liangjun Li, Xu Zhang, Wenli Xu, Mengwei Guo, Qingying Liu, Fangru Li, Tao Liu, Tao Xing, Zhi Li, Mingqing Wang and Mingbo Wu

Dalton Trans., 2024, 53, 5917
DOI: 10.1039/D3DT04001A

High-Throughput, Multiscale Computational Screening of Metal–Organic Frameworks for Xe/Kr Separation with Machine-Learned Parameters

Guobin Zhao, Yu Chen and Yongchul G. Chung

Ind. Eng. Chem. Res., 2023, 62, 15176
DOI: 10.1021/acs.iecr.3c02211

Uncovering the Dynamic CO2 Gas Uptake Behavior of CALF‐20 (Zn) under Varying Conditions via Positronium Lifetime Analysis

Ahmed G. Attallah, Volodymyr Bon, Eric Hirschmann, Maik Butterling, Andreas Wagner, Radosław Zaleski and Stefan Kaskel

Small, 2025, 21
DOI: 10.1002/smll.202500544

Unveiling Temperature-Induced Structural Phase Transformations and CO2 Binding Sites in CALF-20

Joanna Drwęska, Filip Formalik, Kornel Roztocki, Randall Q. Snurr, Leonard J. Barbour and Agnieszka M. Janiak

Inorg. Chem., 2024, 63, 19277
DOI: 10.1021/acs.inorgchem.4c02952

Design and optimization of VSA process for post combustion carbon capture using NbOFFiVE-1-Ni

Qi Wang, Wenqi Yang, Xiubo Min, Shubo Wang, Guangyao Wang, Baogang Zhao, Lina Wang and Tianjun Sun

Fuel, 2025, 396, 135259
DOI: 10.1016/j.fuel.2025.135259

Silver-exchanged zeolites for collecting and separating xenon directly from atmospheric air

Christophe Gueibe, Jos Rutten, Johan Camps, Dominique Moyaux, Wouter Schroeyers, Romano Plenteda, Nikolaus Hermanspahn, Daria Minta and Sonja Schreurs

Separation and Purification Technology, 2023, 323, 124433
DOI: 10.1016/j.seppur.2023.124433

Toward Optimal Xenon Adsorption Capacity at Low Pressure on Silver-Exchanged Zeolites

Celian Courtney, Arthur Millet, Gabriel Couchaux, Alban Gossard, Alain Tuel, Nicolas Bonnet, Sylvain Topin and David Farrusseng

Ind. Eng. Chem. Res., 2023, 62, 11939
DOI: 10.1021/acs.iecr.3c01354

A N-heterocyclics induced π-π interaction strategy to synthesis hyper-crosslinked polymers with enhanced porosity for xenon adsorption

Jialin Wang, Lijie Mi, Meng He, Yingzhe Du, Xiangdong Ding, Jianhui Lan, Weiqun Shi and Xue Liu

Separation and Purification Technology, 2025, 357, 130157
DOI: 10.1016/j.seppur.2024.130157

Metal-organic frameworks for xenon and krypton separation

Yuting Yang, Changzheng Tu, Licheng Guo, Li Wang, Feixing Cheng and Feng Luo

Cell Reports Physical Science, 2023, 4, 101694
DOI: 10.1016/j.xcrp.2023.101694

Fine-Tuning Microporosity of Crystalline Vanadomolybdate Frameworks for Selective Adsorptive Separation of Kr from Xe

Suchona Akter, Yong Li, Min-Bum Kim, Md Omar Faruque, Zhonghua Peng, Praveen K. Thallapally and Mohammad R. Momeni

Langmuir, 2024, 40, 24934
DOI: 10.1021/acs.langmuir.4c02910

In-situ crystallization of CALF-20 nanoparticles in poly(acrylate) with enhanced CO2 capture capability toward high-humidity flue gases

Wanru Feng, Kun Liu, Junteng Liu, Junsu Jin, Jianguo Mi, Shisen Xu and Hong Meng

Separation and Purification Technology, 2024, 343, 127102
DOI: 10.1016/j.seppur.2024.127102

Effective approaches to boost Xe/Kr separation in Metal-Organic Frameworks: A review

Jintu Francis Kurisingal, Dae Won Kim and Chang Seop Hong

Coordination Chemistry Reviews, 2024, 507, 215731
DOI: 10.1016/j.ccr.2024.215731

High yield, large-scale synthesis of calcium-based microporous metal-organic framework and examination of the long-term stability for xenon adsorption applications

Sung Ho Kim, Ate Visser, Noelle R. Catarineu, Aaron B. Bantug, Simon H. Pang, Alexandre Garenne, Erik J. Oerter, Theodore F. Baumann, Michael Heffner and Samuele Sangiorgio

Microporous and Mesoporous Materials, 2024, 366, 112915
DOI: 10.1016/j.micromeso.2023.112915

Selective capture and separation of xenon and krypton using metal organic frameworks: a review

Yilun Zhou, Jingyi Wang, Yujie Zhao, He Gu, Zhongshan Chen, Hui Yang and Xiangke Wang

Front. Chem. Sci. Eng., 2023, 17, 1895
DOI: 10.1007/s11705-023-2355-3

Scalable MOF-based mixed matrix membranes with enhanced permeation processes facilitate the scale application of membrane-based carbon capture technologies

Hao Zhang, Li Sheng, Jia Chen, Xiaolin Wang, Peipei Tao, Dongsheng Ren, Hao Cui, Kai Yang, Zhuozhuo Tang, Zhijun Zhang, Xiangming He and Hong Xu

Carbon Capture Science & Technology, 2024, 13, 100276
DOI: 10.1016/j.ccst.2024.100276

Enhancing CO2 Capture Via Fast Microwave-Assisted Synthesis of the CALF-20 Metal–Organic Framework

Daniel Pereira, Mariana Sardo, Ricardo Vieira, Ildefonso Marín-Montesinos and Luís Mafra

Inorg. Chem., 2025, 64, 3302
DOI: 10.1021/acs.inorgchem.4c04727

Green and Scalable Preparation of an Isomeric CALF‐20 Adsorbent with Tailored Pore Size for Molecular Sieving of Propylene from Propane

Zhenning Deng, Longsheng Yang, Hanting Xiong, Junhui Liu, Xing Liu, Zhenyu Zhou, Shixia Chen, Yanan Wang, Hao Wang, Jingwen Chen, Shuguang Deng, Banglin Chen and Jun Wang

Small Methods, 2025, 9
DOI: 10.1002/smtd.202400838

CO2 and H2O Sorption Induced Bulk-Phase Changes of CALF-20 Captured Using In Situ Laboratory X-ray Powder Diffraction

Sebastian Bette, Anastasia Sleptsova, Bettina V. Lotsch, Robert E. Dinnebier, Stefan Marx, Mahsa Loloei, Adebayo A. Adeleke, Nima Masoumifard and Ramanathan Vaidhyanathan

J. Am. Chem. Soc., 2025, 147, 25662
DOI: 10.1021/jacs.5c06866

Rapid synthesis of metal-organic framework CALF-20 in H2O/methanol solution under room temperature and normal pressure

Yuto Higuchi, Miki Sugita, Saki Moriya, Takahiko Takewaki and Shunsuke Tanaka

Microporous and Mesoporous Materials, 2024, 374, 113137
DOI: 10.1016/j.micromeso.2024.113137

Adsorption Equilibrium and Transport of CO2, N2, and H2O in CALF–20

Akhil Dilipkumar, Anshu Shukla, Dan Zhao and Shamsuzzaman Farooq

Langmuir, 2025, 41, 10940
DOI: 10.1021/acs.langmuir.5c00292

Engineering CALF-20/graphene oxide nanocomposites for enhancing CO2/N2 capture performance

Mina Sedighi, Mohammad Javad Azarhoosh, Hassan Alamgholiloo and Nader Noroozi Pesyan

Process Safety and Environmental Protection, 2024, 190, 1481
DOI: 10.1016/j.psep.2024.08.005

Mechanical compression-induced shaping of zinc triazolate oxalate CALF-20 for CO2 capture

Shunhong Lv, Xinlong Yan, Zhong Yan, Pengfei Liu, Guojun Kang, Shijian Lu, Xiaoyan Hu and Mengqing Hu

Chemical Engineering Research and Design, 2025, 221, 276
DOI: 10.1016/j.cherd.2025.08.013

Extremely Low Energy Penalty for Co-Removal of H2S and CO2 from IGCC Gas

Chunying Liu, Li Lv, Kun Liu, Junsu Jin, Jianguo Mi, Yongqiang Ren and Shisen Xu

Ind. Eng. Chem. Res., 2025, 64, 11032
DOI: 10.1021/acs.iecr.5c00710