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A review of metal–organic framework (MOF) materials as an effective photocatalyst for degradation of organic pollutants

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Five new multifunctional inorganic–organic hybrids based on Keggin-type polyoxometalates and a 3,5-di(1H-imidazol-1-yl)benzoic acid ligand

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A Keggin-type polyoxomolybdate-based crystalline material formed by hydrothermal transformation: photo/electro-catalytic properties and mechanism study

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Modulating central metals in 2D POMOFs for enhanced photocatalytic reduction of Cr(vi), oxidation of CEES and decolorization of MB

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Facile fabrication and characterization of rare earth complexes based on Keggin-type polyoxometalate with highly efficient activity for photocatalytic degradation of MO

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Polyoxometalate-loaded reduced graphene oxide-modified metal vanadate catalysts for photoredox reactions through an indirect Z-scheme mechanism

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Polyoxometalates in environmental remediation and energy storage

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Merging the chemistry of metal–organic and polyoxometalate clusters to form enhanced photocatalytic materials

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Multi-stimuli-responsive polymer degradation by polyoxometalate photocatalysis and chloride ions

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Cu-containing polyoxometalate-based melamine in the environmental remediation of toxic organic pollutants

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Polyoxometalate-based catalysts for visible-light-driven hydrolytic hydrogen production: coordinatively unsaturated Cu-based active sites enhance performance

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Thermally-driven interface engineering of PMo12/BiOBr heterojunctions for enhanced artificial photosynthesis of CO2 in water vapor

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Study on the performance and mechanism of a p–n type In2O3/BiOCl heterojunction prepared using a sacrificial MOF framework for the degradation of PFOA

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Schiff-base ligand assisted synthesis of DyVO4/AgBr nanocomposites, characterization, and investigation of photocatalytic activity over organic dye contaminants

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Three Keggin POMs-based coordination polymers constructed by linear N-heterocyclic ligand for proton conduction, photocatalytic activity and magnetic property

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Mechanochemical synthesis of ionic solids based on phosphotungstic acid and triethylamine for photocatalytic dye degradation

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Sandwich Structured Ru@TiO2 Composite for Efficient Photocatalytic Tetracycline Degradation

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Keggin Cluster Modulated Photocatalytic Activity of Aryl Sulfonium Polyoxometalate Hybrids toward Dichromate Reduction

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Construction of Z-scheme Cs3PMo12O40/g-C3N4 composite photocatalyst with highly efficient photocatalytic performance under visible light irradiation

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Visible-Light-Responsive 2D Photocatalysts Assembled by Evans–Showell-Type POMs and Metalloviologen Frameworks for Sulfide–Sulfoxide Transformation

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Design and synthesis of novel polyoxometalate-based binary and ternary nanohybrids for energy conversion and storage

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Electrochromic polyoxometalates for sensing abiotic stress in plants

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Bandgap engineering and enhanced charge separation in Zn-modified BiW11 polyoxometalate for azo dye photodegradation

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Giant Dielectric Constant and Fast Adsorption–Sunlight Photocatalytic Properties of Al-Doped CuO–ZnO Heterostructures

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Degradation of thiosulfate ions in sodium aluminate solution photocatalyzed by Co-TiO2@ZIF-8

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Highly efficient catalysts of polyoxometalates supported on biochar for antibiotic wastewater treatment: Performance and mechanism

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Strong spin-ferromagnetic order and active dyes-depollution performance of CuO semiconductor: Gd and Gd/Mn dopants

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Large-scale with uniformly dispersed silver nanoparticles decorated poly(acrylonitrile) (PAN) membrane preparation for efficient photocatalytic reactions and antimicrobial activity

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Innovative one-step hydrothermal fabrication of MoS2/ZnIn2S4 heterojunction for efficient visible photocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran

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Two transition-metal-modified Nb/W mixed-addendum polyoxometalates for visible-light-mediated aerobic benzylic C–H oxidations

Yubin Ma, Fan Gao, Wanru Xiao, Na Li, Shujun Li, Bing Yu and Xuenian Chen

Chinese Chemical Letters, 2022, 33, 4395
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Keggin Trimetallo-POM@MIL-101(Cr), Synthesis, Characterization and Catalytic Applications

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Construction of heteropolyacid-anchored magnetic g-C3N4/Fe3O4@polyindole hybrids for efficient photocatalytic destruction of methyl orange and bacteria

Alaa Ibrahim Elaibi, Saad H. Ammar, Israa Sh. Mohammed and Zaid H. Jabbar

Journal of Photochemistry and Photobiology A: Chemistry, 2023, 444, 114923
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Interfacial modulation of α-Ag1.82Cu0.09WO4 with high active BiOClxI1−x for boosting photocatalytic activity and degradation of emerging contaminants under direct sunlight

Chinnadurai Ayappan, Surya Selvaraj, Baskaran Palanivel and Alagiri Mani

Journal of Environmental Chemical Engineering, 2023, 11, 111329
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Photocatalytic driven ‘self-cleaning’ IPN membranes infused with a ‘host-guest’ pair consisting of metal-organic framework encapsulated anionic ‘nano-clusters’ for water remediation

Soumi Dutta, B.G. Maya Patel, Yashraj Singh, Gurumurthy Hegde and Suryasarathi Bose

Journal of Membrane Science, 2024, 694, 122422
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Keggin-type Polyoxometalate-modified BiOI heterostructures for enhanced photocatalytic oxidation of hazardous organic pollutants

Nurseli Görener Erdem, Nergiz Kanmaz, Özlem Tuna and Esra Bilgin Simsek

Journal of Photochemistry and Photobiology A: Chemistry, 2026, 475, 117056
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Study on the configuration isomerism of [V6B20O50]16− cluster cage

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Three Isostructural Keggin‐Type Polyoxometalate Hybrids for Effective Dye Degradation

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Synthesis and comparison of three photocatalysts for degrading tramadol as an analgesic and widely used drug in water samples

Farshid Kazemi, Hassan Ali Zamani, Mohammad Reza Abedi and Mahmoud Ebrahimi

Environmental Research, 2023, 225, 114821
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Recent advances in the development of polyoxometalates and their composites for the degradation of toxic chemical dyes

Gajiram Murmu, Tamanna Harihar Panigrahi and Sumit Saha

Progress in Solid State Chemistry, 2024, 76, 100489
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Preyssler Polyoxometalate Supported Transition Metal Bipyridine Coordination Complexes

Anjali Tripathi, Marc Schmidtmann, Sangeeta Jatiwal and Sabbani Supriya

Inorg. Chem., 2025, 64, 16798
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Novel morphological mono-metallic substituted polyoxometalate immobilized 3-(aminopropyl)-imidazole photocatalysts for visible-light driven degradation: Anti-bacterial activity, membrane bacterial activity applications

Samannan Bharath, Alphonse Lazer, Yi-Li Lin, Praveen Peter and Jeyabalan Thavasikani

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2023, 299, 122868
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Polyoxometalate@Metal–Organic Framework Composites as Effective Photocatalysts

Yang Liu, Chensi Tang, Min Cheng, Ming Chen, Sha Chen, Lei Lei, Yashi Chen, Huan Yi, Yukui Fu and Ling Li

ACS Catal., 2021, 11, 13374
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Two New Compounds Based on Bi-Capped Keggin Polyoxoanions and Cu-Bpy Cations Contain Both CuII and CuI Complexes: Synthesis, Characterization and Properties

Yabing Liu, Wentong Zhao, Jijun Zheng, Huan Wang, Xiaobing Cui and Yaodan Chi

Molecules, 2023, 28, 4706
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Three new multifunctional materials constructed from tetranuclear molybdenum clusters and isonicotinic acid derivatives: Structures, electrochemical behavior, and catalytic oxidative desulfurization

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Construction of a g-C3N4/MnIn2S4 heterostructure with enhanced carrier separation for efficient photocatalytic degradation performance

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Journal of Alloys and Compounds, 2025, 1022, 179835
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Synthesis of Cu‐ZnO/Polyacrylic Acid Hydrogel as Visible‐Light‐Driven Photocatalyst for Organic Pollutant Degradation

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Precise construction of Anderson-type polyoxometalate-based covalent organic frameworks for photocatalytic hydrogen peroxide production

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Journal of Water Process Engineering, 2025, 80, 109149
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Efficient Photodegradation of Congo Red and Phenol Red in Wastewater Using Nanosized Cu-Polyoxometalate: A Promising UV-Active Catalyst for Environmental Treatment

Suhair A. Bani-Atta, Ahmed Ali A. Darwish, Nada M. Alatawi, Nada D. Alkhathami, Jozaa N. Al-Tweher and Eman F. M. El-Zaidia

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Novel and facile strategy for immobilization of Ag3PW12 crystals on graphitic carbon nitride (g-C3-N4) sheets, a superior photocatalyst for decomposition of organic waste

Ajmal Khan, Wenjun Li, Xiaohui Ma, Mei Dong, Liang Geng, Yanyan Li, Yueyan Fan, Shuaib Khan and Ghulam Yasin

Journal of Solid State Chemistry, 2024, 329, 124405
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In Situ Growth of ZnCo-MOF on Bi2WO6 3D-flowers for Enhancing Photocatalytic Degradation via Synergistic Charge Separation

Jiajia Cui, Yueyue Sun, Chaofan Yin, Zixuan Xue, Xiaoyu Shen, Hao Wang, Junkai Wang, Kai Wu and Jun Zhou

Solid State Sciences, 2026, 108333
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Synthesis and characterization of magnetically separable ZnFe2O4/Fe2O3/chitosan ternary nanocomposites and their application as visible nano-photocatalyst for degradation of water-soluble organic pollutants

Seyed Amirhossein Ehsanizadeh, Mina Ahmadi-Kashani, Masoud Salavati-Niasari, Forat H. Alsultany and Hadil Hussain Hamza

Appl Water Sci, 2025, 15
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Hydrogen-Bonded Framework of a Polyanionic Cluster and Its Growth from 2D to 3D for Dual-Selective Adsorption and pH-Controlled Oxidation

Fengrui Jiang, Bao Li and Lixin Wu

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Harnessing the power of single-atom catalysts: A promising solution for organic pollutant remediation under light exposure

Yongkang Cheng, Zhuozhi Ouyang, Zheyu Wang, Yu Zhang, Can He, Shiwen Zhang and Jiayuan Yu

Materials Today Sustainability, 2024, 27, 100858
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Photo-to-chemical energy transformation: Pioneering photocatalysts, surface and interface engineering

Rajiv Kumar, M.P. Chaudhary, Amir Al-Ahmed, Somnath Bhattacharyya, Svetlana von Gratowski, Jibran Iqbal and Inamuddin

Materials Research Bulletin, 2024, 180, 113046
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Tungsten and molybdenum based polyoxometalates for photo and electrocatalytic carbon dioxide conversion – A critical review

Shivangini Bhatt and Sumit Saha

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ZIF-8/graphene composite for photocatalytic degradation under low intensity UV irradiation and antibacterial applications

Calvin Manasseh Manivel, Alvin Lim Teik Zheng, Renuga Kannan, Sivasangar Seenivasagam, Taufiq Yap Yun Hin, Supakorn Boonyuen, Jacqueline Lease, Yoshito Andou and Kar Ban Tan

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Catalytic Performance of Flexible Polycationic Membrane Derived from Polyacrylonitrile for Advanced Applications

Yue Gao, Xuan Qi and Junfeng Zhang

Molecules, 2026, 31, 705
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Tungsten-based Lindqvist and Keggin type polyoxometalates as efficient photocatalysts for degradation of toxic chemical dyes

Gajiram Murmu, Soumita Samajdar, Srabanti Ghosh, K. Shakeela and Sumit Saha

Chemosphere, 2024, 346, 140576
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Advances in ZrO₂ Photocatalysis for Dye Degradation: A Review

Jiress Florez, Carlos Diaz Uribe and William Vallejo Lozada

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Highly efficient ZnCo2O4 nanospheres and ZnCo2O4/GO nanocomposites as visible light photocatalysts for degradation of organic pollutants

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Construction of Pr-modified BiFeO3 nanocubes on carbon matrix for robust degradation of sulfamethoxazole: A synergistic strategy of oxygen vacancy modulation and photo-self-Fenton degradation

J.P. Steffy, Ali H. Bahkali, B. Janani, Abdallah M. Elgorban and S. Sudheer Khan

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A Novel Tri-Functionality pH-Magnetic-Photocatalytic Hybrid Organic-Inorganic Polyoxometalates Augmented Microspheres for Polluted Water Treatment

Li Ying Yee, Qi Hwa Ng, Siti Kartini Enche Ab Rahim, Peng Yong Hoo, Pei Thing Chang, Abdul Latif Ahmad, Siew Chun Low and Siew Hoong Shuit

Membranes, 2023, 13, 174
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Multi-active photocatalysts of biochar-doped g-C3N4 incorporated with polyoxometalates for the high-efficient degradation of sulfamethoxazole

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A novel octamolybdate‐based organic–inorganic hybrid as photo‐Fenton‐like catalyst for degradation of methylene blue

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Applied Organom Chemis, 2023, 37
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Photocatalytic Degradation of Methylene Blue under Visible Light Using TiO2 Thin Films Impregnated with Porphyrin and Anderson-Type Polyoxometalates (Cu and Zn)

Alexander Sanguino, Carlos Diaz-Uribe, Freider Duran, William Vallejo, Leidy Guzman, Daniela Ruiz, Esneyder Puello, Cesar Quiñones, Eduardo Schott and Ximena Zarate

Catalysts, 2022, 12, 1169
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High responsivity and external quantum efficiency of polyoxometalate interlayered Schottky type photodiode device

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Research on the design and application of efficient catalysts based on interfacial chemistry: Molecular catalysts in gas-liquid mixed systems

Xueli Bai, Xiaomiao Guo, Feng Wang, Jing Jing, Haozhe Wang, Huifang Wang, Xiao Li, Xiaoping Zhang, Hong Chang, Xiaojian Hu, Sen Yang and Xun Wang

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