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Manipulation of interfacial charge dynamics for metal–organic frameworks toward advanced photocatalytic applications

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Defective two-dimensional layered heterometallic phosphonates as highly efficient oxygen evolution electrocatalysts

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Water-based room-temperature synthesis of Ce-BDC-MOFs using different additives: a comprehensive investigation on properties and tetracycline adsorption performance

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Ionic porous materials: from synthetic strategies to applications in gas separation and catalysis

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Exploring bimodal mesoporous aluminum MOFs: synthesis and defect analysis of rad net topology with imine-based ligand

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Mechanistic origin of charge separation and enhanced photocatalytic activity in D–π–A-functionalized UiO-66-NH2 MOFs

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Heterogeneity in enzyme/metal–organic framework composites for CO2transformation reactions

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Ligand functionalization of defect-engineered Ni-MOF-74

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Synergistic ramifications of synthesis criteria and amine functionalization of UiO-66-NH2 MOFs for the catalytic degradation of a nerve agent simulant, methyl-paraoxon

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Efficient cascade conversion of glucose to levulinic acid using a dual-functional UiO-66 catalyst

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Direct visualisation of metal–defect cooperative catalysis in Ru-doped defective MOF-808

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Recent advances on the removal of dyes from wastewater using various adsorbents: a critical review

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Mater. Adv., 2021, 2, 4497
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Controlling the molecular diffusion in MOFs with the acidity of monocarboxylate modulators

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Gas adsorption in the topologically disordered Fe-BTC framework

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Advancements in MOF-based resistive gas sensors: synthesis methods and applications for toxic gas detection

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Preparation and characterization of an edible metal–organic framework/rice wine residue composite

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Selective adsorption of malachite green (MG) and fuchsin acid (FA) by ZIF-67 hybridized polyvinylidene fluoride (PVDF) membranes

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A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

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Pore engineering of metal–organic frameworks for boosting low-pressure CO2 capture

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Metal–biomolecule frameworks (BioMOFs): a novel approach for “green” optoelectronic applications

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Modulation of the enzyme-like activity of CuAsp nanozyme by gallic acid and the selective detection of bisphenol A in infant food packaging

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Nanoconfinement and mass transport in metal–organic frameworks

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Construction of waffle-like NS-ZIF@V2CTx heterostructures for high-performance potassium-ion batteries

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Strategies for induced defects in metal–organic frameworks for enhancing adsorption and catalytic performance

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Exploring the effect of molecular size and framework functionalisation on transport in metal–organic frameworks using pulsed-field gradient nuclear magnetic resonance

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Engineering MOFs for thin-film and nanofilm nanocomposite membranes for CO2 separation

Farhang Pazanialenjareghi, Shweta Singh, Fathy Attia, Venkat Sainath Reddy Munnangi, Emmanuel M. Nsengiyumva, Yang Jiao and Haiqing Lin

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Zr4+-terephthalate MOFs with 6-connected structures, highly efficient As(iii/v) sorption and superhydrophobic properties

Anastasia D. Pournara, Sofia Rizogianni, Dimitrios A. Evangelou, Evangelos K. Andreou, Gerasimos S. Armatas and Manolis J. Manos

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In situ degradation and radiation-responsive behavior of metal organic frameworks under high-energy irradiation: implications for sensing and shielding

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Metal–organic frameworks (MOFs) toward SO2 detection

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Nanozymes for clean energy catalysis: unlocking potential, progress and perspectives

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Metal pyrazolate frameworks: crystal engineering access to stable functional materials

Xiang-Jing Kong, Guang-Rui Si, Tao He and Jian-Rong Li

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Engineering the defects of UiO-66 MOF for an improved catalytic detoxification of CWA simulant: methyl paraoxon

Selva Balasubramanian, Arockia Jayalatha Kulandaisamy and John Bosco Balaguru Rayappan

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Capture of toxic gases in MOFs: SO2, H2S, NH3 and NOx

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Chem. Sci., 2021, 12, 6772
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Vibrational spectroscopy investigation of defects in Zr- and Hf-UiO-66

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Superfast structural transformation as a naked-eye detector: conversion of quasi-HKUST to Fe(BTC) for the detection of Fe(iii)

Farzaneh Rouhani, Mahsa Ghiasvand and Nasser Safari

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Structure–activity relationships in the development of single atom catalysts for sustainable organic transformations

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Turning CO2 into treasure: the promise of metal–organic frameworks

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Size modulation of MIL-125 nanocrystals to promote the catalytic performance towards oxidative desulfurization

Na Li, Zong-Wen Zhang, Jia-Ni Zhang, Yue Ma, Xiao-Yu Chen and Yang Fan

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Defect engineering improves CO2/N2 and CH4/N2 separation performance of MOF-801

Chen-Ning Li, Wei-Guo Xu, Lin Liu and Zheng-Bo Han

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Tuning gas transport and separation in ZIF-8 membranes via point defects: insights from non-equilibrium molecular dynamics

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Phys. Chem. Chem. Phys., 2026, 28, 4943
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Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

Saba Daliran, Ali Reza Oveisi, Chung-Wei Kung, Unal Sen, Amarajothi Dhakshinamoorthy, Cheng-Hsun Chuang, Mostafa Khajeh, Mustafa Erkartal and Joseph T. Hupp

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Deciphering the behavior of a new MOF and its composites under light at ensemble and single crystal levels: relevance to its photonic applications

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J. Mater. Chem. C, 2021, 9, 6418
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Recent progress in synthesis and applications of monolithic metal–organic frameworks

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CVD-induced corrosion reconstruction of defective metal–organic frameworks boosted advanced catalytic oxidation

Lei Qin, Xiaoyan Mao, Yihui Yang, Fanghua Ren, Yingyu Tan, Wenjie Liu, Luhong Wen and Xianhui Li

J. Mater. Chem. A, 2025, 13, 28974
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Synthetic and analytical considerations for the preparation of amorphous metal–organic frameworks

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Chem. Sci., 2024, 15, 10689
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Tailoring defect-type and ligand-vacancies in Zr(iv) frameworks for CO2 photoreduction

Shi-Qing Wang, Xinzhu Wang, Xiao-Mei Cheng, Jing Ma and Wei-Yin Sun

J. Mater. Chem. A, 2022, 10, 16396
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MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

Jian Liu, Timothy A. Goetjen, Qining Wang, Julia G. Knapp, Megan C. Wasson, Ying Yang, Zoha H. Syed, Massimiliano Delferro, Justin M. Notestein, Omar K. Farha and Joseph T. Hupp

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Defect engineered Ti-MOFs and their applications

Guo-Ying Han, Mingshuo Sun, Ruixin Zhao, Qazi Mohammad Junaid, Guozhen Hou, Numan Zada Khan Mohmand, Chunmei Jia, Yiwei Liu, Pascal Van Der Voort, Lei Shi and Xiao Feng

Chem. Soc. Rev., 2025, 54, 5081
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Engineering metal-organic frameworks-based nanozymes for enhanced biomimetic catalytic sensing

Zhong Wei Jiang, Xue Gong, Yi Wang, Yuan Fang Li and Cheng Zhi Huang

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Vacancies in Metal−Organic Frameworks: Formation, Arrangement, and Functions

Qingqing Pang, Lingyi Yang and Qiaowei Li

Small Structures, 2022, 3
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Designing 2D Ti3C2Tx MXene@mixed-linker ZIF-9 composite for catalytic CO₂-epoxide cycloaddition

Yuel W. Abraha, Ernst H.G. Langner and David E. Motaung

Inorganic Chemistry Communications, 2025, 182, 115684
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Metal-organic framework-derived 2D materials: Advances and commercial prospects for chemiresistive gas sensing

Jesse Nii Okai Amu-Darko, Shahid Hussain, Guiwu Liu and Guanjun Qiao

International Materials Reviews, 2026
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Construction of defect-rich bimetallic MOF loaded on N, S-codoped MXene QDs/rGO for electrochemical detection of catechol

Ying Wang, Xinming Wang, Mingyue Chu, Jianjiao Xin, Yikun Liu, Haijun Pang, Guixin Yang and Huiyuan Ma

Analytica Chimica Acta, 2025, 1346, 343770
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Eco-Friendly Fluorine Functionalized Superhydrophobic/Superoleophilic Zeolitic Imidazolate Frameworks–Based Composite for Continuous Oil–Water Separation

Wenlong Xiang, Siyu Gong and Jiabin Zhu

Molecules, 2023, 28, 2843
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Design of Ligand‐Nonbridging Sites in Metal–Organic Frameworks for Boosting Lithium Storage Capacity

Lanju Sun, Chongzhi Zhu, Lukun Li, Rumeng Zheng, Jian Yuan, Zhiliang Li, Jikai Sun, Guan Sheng and Hao Wu

Angew Chem Int Ed, 2025, 64
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Tuning oxygen vacancy and missing linkers of defective MOF-808 for advanced adsorption of Yb(III) from aqueous solution

Chengyu Sun, Yihao Ji, Kaicheng Bi, Haipeng Tian, Chundong Wang, Fuli Deng and Yi Zhang

Separation and Purification Technology, 2024, 347, 127585
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MOF Enhanced Dielectric Barrier Discharge Plasma Decomposition of H2S in the Presence of Low Alkanes

Yingwen Li, Fei Gao, Yang Li, Chenyang Shen and Chang-jun Liu

Plasma Chem Plasma Process, 2023, 43, 2079
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Recent Advances in Catalytic Compounds Developed by Thermal Treatment of (Zr-Based) Metal–Organic Frameworks

Catarina E. S. Ferreira, Salete S. Balula and Luís Cunha-Silva

Compounds, 2024, 4, 315
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Reprogramming Porosity: The Synthetic Evolution of Pore Engineering in Metal–Organic Frameworks

Ankit Mondal, Kelechi Festus, Prapassara Muangsopa, Suman Mandal, Arnab Ghosh, Ahana Sarkar, Qingsheng Wang and Hong-Cai Zhou

ACS Materials Lett., 2026
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Metal-organic frameworks for energy: From perfect crystals to programmable defective, quasi-, and post-MOFs

Qi Zhao, Yulin Gao, Nengxiu Zhu, Fei Wang, Dan Zhao and John Wang

Matter, 2026, 9, 102711
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La‐Promoted Conversion of Reaction Intermediates Over H3BTC‐Modified ZrOX/Cu Catalysts for Methanol Synthesis From CO2 Hydrogenation

Jiangwei Yang, Jiayi Zhang, Jinhai Yang, Yan Song, Wenjun Yan, Shoujie Liu, Qiang Wang, Fukui Xiao, Tengfei Gao and Ning Zhao

Adv Funct Materials, 2026
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Nonflammable, robust and recyclable hydrophobic zeolitic imidazolate frameworks/sponge with high oil absorption capacity for efficient oil/water separation

Wenlong Xiang and Zanru Guo

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 650, 129570
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Highly Efficient Hydrogenation of α,β-Unsaturated Aldehydes to Unsaturated Alcohols over Defective MOF-808 with Constructed Frustrated Lewis Pairs

Linhao Zhong, Xiaoqing Liao, Haishuai Cui, He’an Luo, Yang Lv and Pingle Liu

ACS Catal., 2024, 14, 857
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A novel one-step strategy for deep treatment of phosphite‑nickel wastewater using defective metal-organic framework-chitosan composite biosorbent

Yanhong Zhang, Tianhao Gao, Guangbing Liu, Yong Guo, Lu Zhang, Hancheng Cao, Haibo Xu, Weijing Liu and Yexin Lan

Journal of Water Process Engineering, 2025, 69, 106849
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Dual-mechanism defect engineering of multi-enzyme embedded ZIF-8 for efficient anthocyanin extraction from black rice

Mengyuan Cao, Bicong Wang, Yuchao Deng, Da-Wei Pan, Xiao-Jie Ju, Rui Xie, Zhuang Liu, Xing-Long Zhou, Mao-Jie Zhang, Wei Wang and Liang-Yin Chu

Chemical Engineering Journal, 2025, 526, 171234
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ZIFs@chitosan Derived Efficient Bimetallic Carbon-Based Catalyst for Oxygen Reduction

Xiaojun Zhao, Lijuan Liu, Weiting Yang and Qinhe Pan

Ind. Eng. Chem. Res., 2022, 61, 6156
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Mind the Gap: The Role of Mass Transfer in Shaped Nanoporous Adsorbents for Carbon Dioxide Capture

Margot F. K. Verstreken, Nicolas Chanut, Yann Magnin, Héctor Octavio Rubiera Landa, Joeri F. M. Denayer, Gino V. Baron and Rob Ameloot

J. Am. Chem. Soc., 2024, 146, 23633
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The Role of Defects in Metal–Organic Frameworks for Nitrogen Reduction Reaction: When Defects Switch to Features

Islam E. Khalil, Cong Xue, Wenjing Liu, Xiaohan Li, Yu Shen, Sheng Li, Weina Zhang and Fengwei Huo

Adv Funct Materials, 2021, 31
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Different applications, same story: Inspiring nanomedicine from photothermal catalysis to modulate the photothermal activity of nanomaterials through defects engineering

Leonardo Francisco Gonçalves Dias and Ali Abou-Hassan

Coordination Chemistry Reviews, 2024, 507, 215751
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Morphology-controlled metal-organic frameworks for enhanced photocatalytic performance

Hamid Ali, Obaid Iqbal, Basem Al Alwan, Amal Abdulrahman, Yasin Orooji, Eida S. Al-Farraj, Muhammad Sadiq, Sajid Imran, Ahmed M. Abu-Dief, Dewu Yue and Asif Hayat

Coordination Chemistry Reviews, 2025, 541, 216822
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Histidine-engineered metal-organic frameworks with enhanced peroxidase-like activity for sensitive detection of metallothioneins

Meng Sha, Weiqing Xu, Yu Wu, Lei Jiao, Yifeng Chen, Jiajia Huang, Yinjun Tang, Wenling Gu and Chengzhou Zhu

Sensors and Actuators B: Chemical, 2022, 366, 131927
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Room Temperature Hydroxyl Group‐Assisted Preparation of Hydrophobicity‐Adjustable Metal‐Organic Framework UiO‐66 Composites: Towards Continuous Oil Collection and Emulsion Separation

Wenlong Xiang, Huiwen Liu, Jiabin Zhu, Hongyang Gong and Qizheng Cao

Chemistry A European J, 2023, 29
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Cu2O/UiO-66-NH2 composite photocatalysts for efficient hydrogen production from ammonia borane hydrolysis

Jing-Ping Chang, Chien-Yi Wang, Yung-Jung Hsu and Cheng-Yu Wang

Applied Catalysis A: General, 2023, 650, 119005
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Switching on photocatalytic NO oxidation and proton reduction of NH2-MIL-125(Ti) by convenient linker defect engineering

Youzhou He, Yuwei Tan, Mengyu Song, Qingli Tu, Min Fu, Liangjun Long, Jie Wu, Mengmeng Xu and Xingyan Liu

Journal of Hazardous Materials, 2022, 430, 128468
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A new phosphonate based Mn-MOF in recognising arginine over lysine in aqueous medium and other bio-fluids with “Sepsis” disease remediation

Debabrata Chakraborty, Sourav Bej, Rupak Chatterjee, Priyabrata Banerjee and Asim Bhaumik

Chemical Engineering Journal, 2022, 446, 136916
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Metal Organic Frameworks: Synthesis, Characterization and Drug Delivery Applications

Prachi Mhettar, Rasika Patil, Dipti Patil, Jidnyasa Pantwalawalkar and Namdeo Jadhav

NANOASIA, 2024, 14
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Crystal‐size‐dependent Optical Properties of H‐atoms on the Nodes of Ti‐based Metal‐organic Framework

Nazmiye Gökçe Altınçekiç, Matthew Alexander Achemire and Hyunho Noh

Chemistry An Asian Journal, 2025, 20
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Metal organic frameworks as sacrificial templates for preparation of hierarchical covalent organic frameworks enabling ultrafast sample treatment in nontargeted food safety analysis

Wei Li, Rong-Zhi Gao, Hong-Xin Jiang, Qiu-Yu Lu, An-Na Tang and De-Ming Kong

Chemical Engineering Journal, 2021, 425, 130673
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Coupling deviations in local structure to long-range functionality in MOF materials

Rachel A. Yang and Michele L. Sarazen

Chem Catalysis, 2023, 3, 100576
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Highly thermal-stable R6G@UIO-67 for the selective detection of ornidazole and white light emitting diode

Shunxin Xu, Juncai Zhang, Yaru Zhao, Yanqiong Shen, Yichun Qiu, Yuhang Bao, Kui Tang, Yanfang Peng, Yuanqin Zeng, Jinjie Qian and Qipeng Li

Journal of Molecular Structure, 2025, 1329, 141482
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Friends or Foes: Fundamental Principles of Th-Organic Scaffold Chemistry Using Zr-Analogs as a Guide

Jaewoong Lim, Kyoung Chul Park, Grace C. Thaggard, Yuan Liu, Buddhima K. P. Maldeni Kankanamalage, Donald J. Toler, An T. Ta, Preecha Kittikhunnatham, Mark D. Smith, Simon R. Phillpot and Natalia B. Shustova

J. Am. Chem. Soc., 2024, 146, 12155
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Combining Mixed‐Linker Design and Selective Etching for Precise Control of Defect Type and Distribution in Metal–Organic Frameworks

Yu Gai, Lanlan Liang, Xiaohui Hou, Mingshuo Sun, Tong Liu, Qinyi Cheng, Guoying Han, Huirong Ma, Yiwei Liu, Rui Huang and Xiao Feng

Small, 2026, 22
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Nanostructural engineering of metal-organic frameworks: Construction strategies and catalytic applications

Yutian Qin, Zhixi Li, Yulong Duan, Jun Guo, Meiting Zhao and Zhiyong Tang

Matter, 2022, 5, 3260
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Quasi-metal organic frameworks: Preparation, applications and future perspectives

Minoo Bagheri and Mohammad Yaser Masoomi

Coordination Chemistry Reviews, 2022, 468, 214643
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Advancements in Bimetallic Metal–Organic Frameworks for Oral Medicine

Yuhan Yang, Qi Zhao, Zhanhua Cao, Lingao Zhu, Bowei Wang and Zhihui Liu

International Dental Journal, 2026, 76, 109497
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Specific separation of flavonoids isomers by defect modulated metal-organic framework HKUST-1: Experiment and density functional theory analysis

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Rapidly create bimetallic defective MOFs polymer for capillary microextraction: A highly efficient enrichment approach for glyphosate and its metabolite in waters

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Theoretical investigation on the structure of mixed-metal zeolitic imidazolate framework and its interaction with CO2

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Unlocking the Potential of Cu/Ti3C2Tx MXene Catalyst in Plasma Catalytic CO2 Hydrogenation

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Design of Ligand‐Nonbridging Sites in Metal–Organic Frameworks for Boosting Lithium Storage Capacity

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Utilizing defective MIL-100(Fe) with exceptional performance in conjunction with GC–MS facilitates the efficient adsorption and detection of phthalates in beverages

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Recent advances in thermocatalytic hydrogenation of unsaturated organic compounds with Metal-Organic Frameworks-based materials: Construction strategies and related mechanisms

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Imprinting defective Fe-based metal-organic frameworks as an excellent platform for selective fenton/persulfate degradation of LEX: Removal performance and mechanism

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Defective MIL-125 Nanocrystals with Enhanced Catalytic Performance for Oxidative Denitrogenation

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Missing-linker engineering of Eu (III)-doped UiO-MOF for enhanced detection of heavy metal ions

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Defect-Engineered MOF-801/Sodium Alginate Aerogel Beads for Boosting Adsorption of Pb(II)

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Degradation of G-Type Nerve Agent Simulant with Phase-Inverted Spherical Polymeric-MOF Catalysts

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Defect Engineering of Low-Coordinated Metal–Organic Frameworks (MOFs) for Improved CO2 Access and Capture

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Fabrication of MOF@COF hybrids for dispersive solid-phase extraction and determination of aflatoxins in milk products prior to HPLC-MS analysis

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Photocatalytic degradation of organic pollutants by porphyrin metal-organic framework: Structural engineering, design strategies, and environmental applications

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Controlled synthesis of defective MOF-808 and its application in levulinic acid esterification

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A robust ultra-microporous cationic aluminum-based metal-organic framework with a flexible tetra-carboxylate linker

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