From synthesis to application: a review of BaZrS3 chalcogenide perovskites

Shubhanshu Agarwal, Kiruba Catherine Vincent and Rakesh Agrawal

Nanoscale, 2025, 17, 4250
DOI: 10.1039/D4NR03880K

A reliable, colloidal synthesis method of the orthorhombic chalcogenide perovskite, BaZrS3, and related ABS3 nanomaterials (A = Sr, Ba; B = Ti, Zr, Hf): a step forward for earth-abundant, functional materials

Daniel C. Hayes, Shubhanshu Agarwal, Kiruba Catherine Vincent, Izoduwa M. Aimiuwu, Apurva A. Pradhan, Madeleine C. Uible, Suzanne C. Bart and Rakesh Agrawal

Chem. Sci., 2025, 16, 1308
DOI: 10.1039/D4SC06116K

Thermodynamic insights into the Ba–S system for the formation of BaZrS3 perovskites and other Ba sulfides

Corrado Comparotto, Lucy Whalley, Kostiantyn Sopiha, Robert J. W. Frost, Tomas Kubart and Jonathan J. S. Scragg

J. Mater. Chem. A, 2025, 13, 9983
DOI: 10.1039/D5TA00798D

Opportunities and challenges for emerging inorganic chalcogenide–silicon tandem solar cells

Vijay C. Karade, Mingrui He, Zhaoning Song, Abasi Abudulimu, Yeonwoo Park, Donghoon Song, Yanfa Yan, Jin Hyeok Kim, Randy J. Ellingson, Jae Ho Yun, Xiaojing Hao, Seung Wook Shin and Mahesh P. Suryawanshi

Energy Environ. Sci., 2025, 18, 6899
DOI: 10.1039/D4EE04526B

Numerical investigation of a high-efficiency BaZrxTi1−xS3 chalcogenide perovskite solar cell

Debashish Pal, Abdulkarem H. M. Almawgani, Soumee Das, Amrindra Pal, Md. Ferdous Rahman, Adam R. H. Alhawari and Sagar Bhattarai

New J. Chem., 2024, 48, 2474
DOI: 10.1039/D3NJ04832B

Solution-phase synthesis of group 3–5 transition metal chalcogenide inorganic nanomaterials

Daniel Zilevu and Sidney E. Creutz

Chem. Commun., 2023, 59, 8779
DOI: 10.1039/D3CC01731A

Emergence of Ruddlesden–Popper phases and other pitfalls for moderate temperature solution deposited chalcogenide perovskites

Apurva A. Pradhan, Shubhanshu Agarwal, Kiruba Catherine Vincent, Daniel C. Hayes, Jonas M. Peterson, Jonathan W. Turnley, Robert M. Spilker, Madeleine C. Uible, Suzanne C. Bart, Libai Huang, Kim Kisslinger and Rakesh Agrawal

Mater. Chem. Front., 2024, 8, 3358
DOI: 10.1039/D4QM00441H

Time-resolved photoluminescence studies of perovskite chalcogenides

Kevin Ye, Boyang Zhao, Benjamin T. Diroll, Jayakanth Ravichandran and R. Jaramillo

Faraday Discuss., 2022, 239, 146
DOI: 10.1039/D2FD00047D

Solution-phase synthesis of the chalcogenide perovskite barium zirconium sulfide as colloidal nanomaterials

Daniel Zilevu, Omri O. Parks and Sidney E. Creutz

Chem. Commun., 2022, 58, 10512
DOI: 10.1039/D2CC03494H

Solution-phase synthesis of alloyed Ba(Zr1−xTix)S3 perovskite and non-perovskite nanomaterials

Daniel Zilevu, Kennedi M. Miller, Naira Arrykova, Autumn B. Locke and Sidney E. Creutz

Nanoscale, 2024, 16, 17126
DOI: 10.1039/D4NR02412E

Enhancing the inherent stability of perovskite solar cells through chalcogenide-halide combinations

Cheng Wang, Riming Nie, Yiming Dai, Huanyu Tai, Bingjian Zhu, Luyao Zhao, Yong Wu, Wanlin Guo and Sang Il Seok

Energy Environ. Sci., 2024, 17, 1368
DOI: 10.1039/D3EE03612J

A Facile Aqueous Solution Route for the Growth of Chalcogenide Perovskite BaZrS3 Films

Samyak Dhole, Xiucheng Wei, Haolei Hui, Pinku Roy, Zachary Corey, Yongqiang Wang, Wanyi Nie, Aiping Chen, Hao Zeng and Quanxi Jia

Photonics, 2023, 10, 366
DOI: 10.3390/photonics10040366

Recent progress in chalcogenide perovskites: toward low-temperature solution processing

Jaewook Lee and Wooseok Yang

Ceramist, 2023, 26, 17
DOI: 10.31613/ceramist.2023.26.1.02

Challenges and Advances in Low‐Temperature Synthesis of Lead‐Free BaZrS3 Chalcogenide Perovskite for Optoelectronics

Abhishek Swarnkar and Ujjal K. Gautam

Advanced Sustainable Systems, 2025
DOI: 10.1002/adsu.202500234

Investigating the potential of triclinic ABSe3 (A = Li, Na, K, Rb, Cs; B = Si, Ge, Sn) perovskites as a new class of lead-free photovoltaic materials

Eman Khalafalla Mahmoud, S. I. El-dek, Ahmed A. Farghali and Mohamed Taha

Sci Rep, 2024, 14
DOI: 10.1038/s41598-024-72555-0

Chalcogenide perovskites for photovoltaic applications: a review

Moh Suhail, Hasan Abbas, Mohd. Bilal Khan and Zishan H. Khan

J Nanopart Res, 2022, 24
DOI: 10.1007/s11051-022-05525-0

Exploring the Structural, Electronic, Optical, Thermoelectric and Thermodynamic Properties of Tl-based Chalcogenide Perovskites ATlS3 (A = Sc, Y, La, Lu)

Maha Naeem, Nawaz Muhammad, G. Murtaza, Hafiz Irfan Ali, Imed Boukhris, Ahmad Usman and Thamraa Alshahrani

J Inorg Organomet Polym, 2025, 35, 7028
DOI: 10.1007/s10904-025-03712-9

Chalcogenide BaZrS3 perovskite solar cells: A numerical simulation and analysis using SCAPS-1D

S. Karthick, S. Velumani and J. Bouclé

Optical Materials, 2022, 126, 112250
DOI: 10.1016/j.optmat.2022.112250

Physically Exfoliating 2D Materials: A Versatile Combination of Different Materials into a Layered Structure

Haney Lee, Eunseo Heo and Hyeonseok Yoon

Langmuir, 2023, 39, 18678
DOI: 10.1021/acs.langmuir.3c02418

Solution Deposition for Chalcogenide Perovskites: A Low-Temperature Route to BaMS3 Materials (M = Ti, Zr, Hf)

Jonathan W. Turnley, Kiruba Catherine Vincent, Apurva A. Pradhan, Isabel Panicker, Ryan Swope, Madeleine C. Uible, Suzanne C. Bart and Rakesh Agrawal

J. Am. Chem. Soc., 2022, 144, 18234
DOI: 10.1021/jacs.2c06985

Photoconductive Effects in Single Crystals of BaZrS3

Boyang Zhao, Huandong Chen, Ragib Ahsan, Fei Hou, Eric R. Hoglund, Shantanu Singh, Maruda Shanmugasundaram, Huan Zhao, Andrey V. Krayev, Han Htoon, Patrick E. Hopkins, Jan Seidel, Rehan Kapadia and Jayakanth Ravichandran

ACS Photonics, 2024, 11, 1109
DOI: 10.1021/acsphotonics.3c01563

Recent advances in BaZrS3 perovskites: Synthesis, properties, and future trends

Nikhil Thakur, K.A. Aly, M. Mohery, M.M. Ebrahium, Pawan Kumar and Pankaj Sharma

Journal of Alloys and Compounds, 2023, 957, 170457
DOI: 10.1016/j.jallcom.2023.170457

Carbon Impurity Minimization of Solution-Processed, Thin-Film Photovoltaics via Ligand Engineering of CuInS2 Nanoparticles

Daniel C. Hayes, Samantha A. Langdon, Robert M. Spilker and Rakesh Agrawal

ACS Appl. Energy Mater., 2024, 7, 885
DOI: 10.1021/acsaem.3c01922

Electrical contacts for high-performance optoelectronic devices of BaZrS3 single crystals

Huandong Chen, Shantanu Singh, Mythili Surendran, Boyang Zhao, Yan-Ting Wang and Jayakanth Ravichandran

J. Mater. Res., 2025, 40, 1796
DOI: 10.1557/s43578-025-01612-9

Synthesis of BaZrS3 and BaS3 Thin Films: High and Low Temperature Approaches

Tim Freund, Sumbal Jamshaid, Milad Monavvar and Peter Wellmann

Crystals, 2024, 14, 267
DOI: 10.3390/cryst14030267

Shape-Controlled Synthesis of Colloidal Nanorods and Nanoparticles of Barium Titanium Sulfide

Daniel Zilevu and Sidney E. Creutz

Chem. Mater., 2021, 33, 5137
DOI: 10.1021/acs.chemmater.1c01193

Synthesis of BaZrS3 Perovskite Thin Films at a Moderate Temperature on Conductive Substrates

Corrado Comparotto, Petter Ström, Olivier Donzel-Gargand, Tomas Kubart and Jonathan J. S. Scragg

ACS Appl. Energy Mater., 2022, 5, 6335
DOI: 10.1021/acsaem.2c00704

Chalcogenide Perovskites (ABS3; A = Ba, Ca, Sr; B = Hf, Sn): An Emerging Class of Semiconductors for Optoelectronics

Pooja Basera and Saswata Bhattacharya

J. Phys. Chem. Lett., 2022, 13, 6439
DOI: 10.1021/acs.jpclett.2c01337

Defect Imide Double Antiperovskites AE5AsPn(NH)2 (AE=Ca, Sr; Pn=Sb, Bi) as Potential Solar Cell Absorber Materials

Thanh G. Chau, Dan Han, Florian Wolf, Stefan S. Rudel, Yuxuan Yao, Harald Oberhofer, Thomas Bein, Hubert Ebert and Wolfgang Schnick

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202500768

Chalcogenide Perovskite Thin Films with Controlled Phases for Optoelectronics

Zhonghai Yu, Haolei Hui, Damien West, Han Zhang, Yiyang Sun, Sen Kong, Yin Zhang, Chenhua Deng, Sen Yang, Shengbai Zhang and Hao Zeng

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202309514

Influence of pressure on structural, electronic, optical, and elastic properties of lead-free chalcogen perovskite LaLuS3 via first-principles calculations: implications for optoelectronic applications

Sana Ullah, Yanqi Mu, Guancai Xie and Jian Ru Gong

Phys. Scr., 2024, 99, 075906
DOI: 10.1088/1402-4896/ad4df4

Enhancing the optical absorption of chalcogenide perovskite BaZrS3 by optimizing the synthesis and post-processing conditions

Jie Xu, Yuchao Fan, Weimin Tian, Li Ye, Yuewen Zhang, Yongtao Tian, Yanbing Han and Zhifeng Shi

Journal of Solid State Chemistry, 2022, 307, 122872
DOI: 10.1016/j.jssc.2021.122872

Advances in chalcogenide perovskites: Fundamentals and applications

Yanbing Han, Xiaosheng Fang and Zhifeng Shi

Applied Physics Reviews, 2024, 11
DOI: 10.1063/5.0203535

Epitaxial Thin Films of a Chalcogenide Perovskite

Mythili Surendran, Huandong Chen, Boyang Zhao, Arashdeep S. Thind, Shantanu Singh, Thomas Orvis, Huan Zhao, Jae-Kyung Han, Han Htoon, Megumi Kawasaki, Rohan Mishra and Jayakanth Ravichandran

Chem. Mater., 2021, 33, 7457
DOI: 10.1021/acs.chemmater.1c02202

Performance Optimization of MgHfS3 Chalcogenide Perovskite Solar Cells Using SCAPS-1D

Adeyinka D. Adewoyin, Abdulai M. Feika and Muteeu A. Olopade

East Eur. J. Phys., 2024, 456
DOI: 10.26565/2312-4334-2024-3-55

Defect Imide Double Antiperovskites AE5AsPn(NH)2 (AE=Ca, Sr; Pn=Sb, Bi) as Potential Solar Cell Absorber Materials

Thanh G. Chau, Dan Han, Florian Wolf, Stefan S. Rudel, Yuxuan Yao, Harald Oberhofer, Thomas Bein, Hubert Ebert and Wolfgang Schnick

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202500768

A First-Principles Thermodynamic Model for the Ba–Zr–S System in Equilibrium with Sulfur Vapor

Prakriti Kayastha, Giulia Longo and Lucy D. Whalley

ACS Appl. Energy Mater., 2024, 7, 11326
DOI: 10.1021/acsaem.3c03208

Emerging Earth-Abundant Solar Absorbers

Ji Woon Choi, Byungha Shin, Prashun Gorai, Robert L. Z. Hoye and Robert Palgrave

ACS Energy Lett., 2022, 7, 1553
DOI: 10.1021/acsenergylett.2c00516

Chalcogenide perovskites: enticing prospects across a wide range of compositions and optoelectronic properties for stable photodetector devices

Shilpa Mariam Samuel, Sadasivan Shaji, David Avellaneda Avellaneda and Bindu Krishnan

Nano Ex., 2025, 6, 015002
DOI: 10.1088/2632-959X/ad9b40

A Processing Route to Chalcogenide Perovskites Alloys with Tunable Band Gap via Anion Exchange

Kevin Ye, Ida Sadeghi, Michael Xu, Jack Van Sambeek, Tao Cai, Jessica Dong, Rishabh Kothari, James M. LeBeau and R. Jaramillo

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202405135

Chalcogenide Perovskites: Tantalizing Prospects, Challenging Materials

Kostiantyn V. Sopiha, Corrado Comparotto, José A. Márquez and Jonathan J. S. Scragg

Advanced Optical Materials, 2022, 10
DOI: 10.1002/adom.202101704

Chalcogenide perovskites for photovoltaics: current status and prospects

Devendra Tiwari, Oliver S Hutter and Giulia Longo

J. Phys. Energy, 2021, 3, 034010
DOI: 10.1088/2515-7655/abf41c

Fabrication of Bariumtrisulphide Thin Films as Precursors for Chalcogenide Perovskites

Tim Freund, Maria Rita Cicconi and Peter J. Wellmann

Physica Status Solidi (b), 2022, 259
DOI: 10.1002/pssb.202200094

Making BaZrS3 Chalcogenide Perovskite Thin Films by Molecular Beam Epitaxy

Ida Sadeghi, Kevin Ye, Michael Xu, Yifei Li, James M. LeBeau and Rafael Jaramillo

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202105563

Low-energy electronic structure of perovskite and Ruddlesden-Popper semiconductors in the Ba-Zr-S system probed by bond-selective polarized x-ray absorption spectroscopy, infrared reflectivity, and Raman scattering

Kevin Ye, Nathan Z. Koocher, Stephen Filippone, Shanyuan Niu, Boyang Zhao, Matthew Yeung, Sharon Bone, Adam J. Robinson, Patrick Vora, André Schleife, Long Ju, Alexey Boubnov, James M. Rondinelli, Jayakanth Ravichandran and R. Jaramillo

Phys. Rev. B, 2022, 105
DOI: 10.1103/PhysRevB.105.195203

Bandgap engineering of BaTi(O$$_{1-\text{x}}$$S$$_\text{x}$$)$$_{3}$$ as a function of sulfur concentration

R. Gómez-Rosales, E. Flores-Sigala, F. Molina-Ramírez, F. Avelar-Muñoz, H. A. Durán-Muñoz, H. Tototzintle-Huitle, J. G. Quiñones-Galván and J. J. Ortega

J Mater Sci, 2023, 58, 8720
DOI: 10.1007/s10853-023-08586-1

From data to discovery: Exploring novel photovoltaic perovskite chalcogenide crystals MgMS3 (M: Zr, Ti, Hf) via machine learning and density functional theory calculations

B.K. Mechraoui, A. Benghia, Z. Hebboul, I.K. Lefkaier, M. Halit and R. Arar

Materials Today Communications, 2025, 42, 111517
DOI: 10.1016/j.mtcomm.2025.111517

2D Heterostructures for Ubiquitous Electronics and Optoelectronics: Principles, Opportunities, and Challenges

Phuong V. Pham, Srikrishna Chanakya Bodepudi, Khurram Shehzad, Yuan Liu, Yang Xu, Bin Yu and Xiangfeng Duan

Chem. Rev., 2022, 122, 6514
DOI: 10.1021/acs.chemrev.1c00735

Theoretical insights into recombination mechanisms and design optimization of BaZrS3 chalcogenide perovskite solar cells

Naifa S. Alatawi, Abeer M. Almutairi, Sana Ahmed Khalil, Asma Obaidallah Alatawi, Wejdan Al-Anazi, Mourad Magherbi and Souheil Alimi

Appl. Phys. A, 2024, 130
DOI: 10.1007/s00339-024-07871-3

Nickel Boride (NixB) Nanocrystals: From Solid-State Synthesis to Highly Colloidally Stable Inks

Jennifer Hong, Suhas Mutalik, Matteo Miola, Dominic Gerlach, Razieh Mehrabi K., Majid Ahmadi, Bart J. Kooi, Giuseppe Portale, Petra Rudolf, Paolo P. Pescarmona and Loredana Protesescu

Chem. Mater., 2023, 35, 1710
DOI: 10.1021/acs.chemmater.2c03478

Synthesis of BaZrS3 and BaHfS3 Chalcogenide Perovskite Films Using Single‐Phase Molecular Precursors at Moderate Temperatures

Apurva A. Pradhan, Madeleine C. Uible, Shubhanshu Agarwal, Jonathan W. Turnley, Shriya Khandelwal, Jonas M. Peterson, Daria D. Blach, Ryan N. Swope, Libai Huang, Suzanne C. Bart and Rakesh Agrawal

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202301049

Performance assessment of earth-abundant Kesterite and lead-free chalcogenide-based perovskite solar cells using SCAPS-1D

Himanshu Dixit, Nitin Kumar Bansal, Shivam Porwal, Dinesh Kumar and Trilok Singh

Optik, 2023, 295, 171474
DOI: 10.1016/j.ijleo.2023.171474

Device modelling and performance analysis of chalcogenide perovskite-based solar cell with diverse hole transport materials and back contact metals

Hend I. Alkhammash and M. M. Haque

Jpn. J. Appl. Phys., 2023, 62, 012006
DOI: 10.35848/1347-4065/acb11b

Process Development and Formation Chemistry of BaZrS3 Thin Films via a Two-Stage PVD Process

Garima Aggarwal, Corrado Comparotto, Stefania Riva, Sushobhita Chawla, Olivier Donzel-Gargand, Soham Mukherjee, Robert Frost, Håkan Rensmo and Jonathan J. S. Scragg

ACS Appl. Energy Mater., 2025, 8, 12512
DOI: 10.1021/acsaem.5c00874

Exploring Exciton and Polaron Dominated Photophysical Phenomena in Ruddlesden–Popper Phases of Ban+1ZrnS3n+1 (n = 1–3) from Many Body Perturbation Theory

Deepika Gill, Arunima Singh, Manjari Jain and Saswata Bhattacharya

J. Phys. Chem. Lett., 2021, 12, 6698
DOI: 10.1021/acs.jpclett.1c01486

Synthesis of BaZrS3 and BaHfS3 Chalcogenide Perovskite Films Using Single‐Phase Molecular Precursors at Moderate Temperatures

Apurva A. Pradhan, Madeleine C. Uible, Shubhanshu Agarwal, Jonathan W. Turnley, Shriya Khandelwal, Jonas M. Peterson, Daria D. Blach, Ryan N. Swope, Libai Huang, Suzanne C. Bart and Rakesh Agrawal

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202301049

Chalcogenide perovskites—challenges, status, and future prospects

Pidugu Kesavan Kannan, Mariappan Anandkumar and Gopal Bhavani

J. Semicond., 2024, 45, 111801
DOI: 10.1088/1674-4926/24050029

Optoelectronic Properties of Chalcogenide Perovskites by Many-Body Perturbation Theory

Manish Kumar, Arunima Singh, Deepika Gill and Saswata Bhattacharya

J. Phys. Chem. Lett., 2021, 12, 5301
DOI: 10.1021/acs.jpclett.1c01034

Ti Alloying as a Route to BaZrS3 Chalcogenide Perovskite with Enhanced Photovoltaic Performance

Mohammed Benali Kanoun, Bakhtiar Ul Haq, Ahmed-Ali Kanoun and Souraya Goumri-Said

Energy Fuels, 2023, 37, 9548
DOI: 10.1021/acs.energyfuels.3c01272

Parametric study on controllable growth of SrZrS3 thin films with good conductivity for photodetectors

Yurun Liang, Yuewen Zhang, Jie Xu, Jingli Ma, Huifang Jiang, Xin Li, Baolin Zhang, Xu Chen, Yongtao Tian, Yanbing Han and Zhifeng Shi

Nano Res., 2023, 16, 7867
DOI: 10.1007/s12274-023-5412-9

Optoelectronics’ quantum leap: Unveiling the breakthroughs driving high-performance devices

Lina M. Shaker, Ahmed Al-Amiery and Wan Nor Roslam Wan Isahak

Green Technologies and Sustainability, 2024, 2, 100111
DOI: 10.1016/j.grets.2024.100111

Breaking Barriers in Chalcogenide Perovskite Synthesis: A Generalized Framework for Fabrication of BaMS3 (M═Ti, Zr, Hf) Materials

Shubhanshu Agarwal, Kiruba Catherine Vincent, Jonathan W. Turnley, Daniel C. Hayes, Madeleine C. Uible, Inés Durán, Alison Sofia Mesa Canizales, Shriya Khandelwal, Isabel Panicker, Zion Andoh, Robert M. Spilker, Qiushi Ma, Libai Huang, Sooyeon Hwang, Kim Kisslinger, Simon Svatek, Elisa Antolin, Suzanne C. Bart and Rakesh Agrawal

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202405416

Ultrafast carrier dynamics and transient nonlinear absorption in chalcogenide perovskite BaZrS3

Pengxian You, Yadong Han, Junhong Yu, Yunfan Yang, Yakun Cao, Xiangyin Zhou, Liang Qiao and Jianbo Hu

Applied Physics Letters, 2024, 125
DOI: 10.1063/5.0228009

Exploring photocatalytic and photovoltaic applications of chalcogenide Perovskites, ABS3 (A = Li, Na, K, Rb, Cs; B = Si, Ge, Sn): A First-Principles investigation using the HSE-06 hybrid functional

Eman Khalafalla Mahmoud, S.I. El-dek, Ahmed A. Farghali and Mohamed Taha

Inorganic Chemistry Communications, 2025, 172, 113650
DOI: 10.1016/j.inoche.2024.113650

Highly Stable BaZrS3 Chalcogenide Perovskites for Photoelectrochemical Water Oxidation

Aparajita Das, Jigar Shaileshkumar Halpati, Vidya Raj and Aravind Kumar Chandiran

Energy Fuels, 2024, 38, 22527
DOI: 10.1021/acs.energyfuels.4c03175

P-type conductive BaZrS3 thin film and its band gap tunning via Ruddlesden-Popper Ba3Zr2S7 and titanium alloying

Yanbing Han, Jie Xu, Yurun Liang, Xu Chen, Mochen Jia, Jibin Zhang, Linyuan Lian, Ying Liu, Xinjian Li and Zhifeng Shi

Chemical Engineering Journal, 2023, 473, 145351
DOI: 10.1016/j.cej.2023.145351

Octahedral Tilt-Driven Phase Transitions in BaZrS3 Chalcogenide Perovskite

Prakriti Kayastha, Erik Fransson, Paul Erhart and Lucy Whalley

J. Phys. Chem. Lett., 2025, 16, 2064
DOI: 10.1021/acs.jpclett.4c03517

Chalcogenide Perovskite, An Emerging Photovoltaic Material: Current Status and Future Perspectives

Rakshita Raj, Riya Singh and Mridula Guin

ChemistrySelect, 2023, 8
DOI: 10.1002/slct.202303550

Structural stabilities, mechanical and thermodynamic properties of chalcogenide perovskite ABS3 (A = Li, Na, K, Rb, Cs; B = Si, Ge, Sn) from first-principles study

Eman Khalafalla Mahmoud, Ahmed A. Farghali, S. I. El-dek and Mohamed Taha

Eur. Phys. J. Plus, 2022, 137
DOI: 10.1140/epjp/s13360-022-03211-7

Perovskite Quantum Dot Solar Cells: Current Status and Future Outlook

Mengmeng Hao, Shanshan Ding, Sabah Gaznaghi, Huiyuan Cheng and Lianzhou Wang

ACS Energy Lett., 2024, 9, 308
DOI: 10.1021/acsenergylett.3c01983

Assessing Carrier Mobility, Dopability, and Defect Tolerance in the Chalcogenide Perovskite BaZrS3

Zhenkun Yuan, Diana Dahliah, Romain Claes, Andrew Pike, David P. Fenning, Gian-Marco Rignanese and Geoffroy Hautier

PRX Energy, 2024, 3
DOI: 10.1103/PRXEnergy.3.033008

Titanium-Doped BaZrS3 Chalcogenide Perovskite for Photovoltaic Applications: Structural, Optical, and Electrical Properties

Adam Musa and Monica Katiyar

Inorg. Chem., 2025, 64, 8492
DOI: 10.1021/acs.inorgchem.4c04620

Indirect-to-direct band gap transition induced by d−d coupling between cations in rare-earth chalcogenide perovskites

Han Zhang, Yichun Pan, Zexin Liu, Biao Zeng, Xiaowei Wu, Chen Ming, Guoqing Xin, Weihang Zhou, Hao Zeng, Shengbai Zhang and Yi-Yang Sun

Phys. Rev. B, 2024, 110
DOI: 10.1103/PhysRevB.110.L041201

Exploring the potential of powder-to-film processing for proof-of-concept BaZrS3 perovskite solar cells

P. Dallas, K. Gkini, A. Kaltzoglou, L. Givalou, M. Konstantakou, S. Orfanoudakis, N. Boukos, E. Sakellis, P. Tsipas, A. Kalafatis, A.G. Karydas, A. Lagogiannis, P. Falaras, V. Psycharis and T. Stergiopoulos

Materials Today Communications, 2024, 39, 108608
DOI: 10.1016/j.mtcomm.2024.108608

Exploring the Defect Landscape and Dopability of Chalcogenide Perovskite BaZrS3

Rushik Desai, Shubhanshu Agarwal, Kiruba Catherine Vincent, Alejandro Strachan, Rakesh Agrawal and Arun Mannodi-Kanakkithodi

J. Phys. Chem. C, 2025, 129, 7967
DOI: 10.1021/acs.jpcc.5c01597

Quantitative Scales for Haliphilicity of Metals: Tailoring the Halide Affinity of Alkaline Earth Metals to Synthesize Chalcogenide Perovskite BaMS3 (M = Zr, and Hf) and Cu2BaSnS4 Compounds

Shubhanshu Agarwal, Kiruba Catherine Vincent and Rakesh Agrawal

ACS Appl. Energy Mater., 2024, 7, 10584
DOI: 10.1021/acsaem.4c02205

Enhanced photoresponse in BaZrS3 thin films via sputtering and flux-assisted sulfurization

Haolei Hui, Lauren Samson, Arif Ullah, Chenyu Wang, Brandon Schoener, Jung-Hun Seo, John Cerne, Andrea Markelz, Yi-Yang Sun, Shengbai Zhang and Hao Zeng

J. Mater. Res., 2025
DOI: 10.1557/s43578-025-01679-4

Modeling of (Ca,Ba)ZrS3 solar cells with next-gen spinel hole transport layers via SCAPS-1D

Eupsy Navis Vincent Mercy, Aruna-Devi Rasu Chettiar, Karthick Sekar, Sownthari Kandasamy and Latha Marasamy

Opt Quant Electron, 2025, 57
DOI: 10.1007/s11082-025-08228-7

High densification of BaZrS3 powder inspired by the cold-sintering process

Stephen Filippone, Samuel Song and R. Jaramillo

Journal of Materials Research, 2021, 36, 4404
DOI: 10.1557/s43578-021-00404-1