The synthesis of aryl amines enabled by rearrangement and demethylaromatization of cyclohexadienimines

Xueyu Fang, Hongyan Xie, Hongkun Huang, Yu Wang, Tian Chen, Zhaohua Yan and Hua Yao

Org. Biomol. Chem., 2024, 22, 9041
DOI: 10.1039/D4OB01338G

Synthesis of hydroindoles via desymmetric [3+2] cycloadditions of para-quinamines with photogenerated ketenes

Dan Liu, Bin Shi, Hao Jiang, Ying Cheng, Wen-Jing Xiao and Liang-Qiu Lu

Chem. Commun., 2021, 57, 8496
DOI: 10.1039/D1CC03352B

Rhodium(iii)-catalyzed asymmetric allylic cyclization of cyclohexadienone-tethered allenes

Jian-Wei Zhang, Da-Yu Shi, Ping Tian and Qing-Hua Li

Org. Biomol. Chem., 2025, 23, 3643
DOI: 10.1039/D5OB00220F

Rhodium(iii)-catalyzed oxidative [3+2] annulation of arylboron reagents and 7-azabenzonorbornadienes via transmetalation-initiated C–H activation

Xuejing Yao, Shunle Hu, Lijuan Jv, Ruijie Mi and Xingwei Li

Chem. Commun., 2025, 61, 11231
DOI: 10.1039/D5CC02745D

Asymmetric desymmetrization of 2,5-cyclohexadienones initiated by organocatalytic conjugate addition to 4-nitro-5-styrylisoxazoles

Manisha Sharma and Pankaj Chauhan

Chem. Commun., 2025, 61, 1455
DOI: 10.1039/D4CC06145D

Rhodium catalysed intramolecular benzannulation for the formation of tetracyclic carbazoles

Y Bharath Chaithanya Kumar, Polasani Samatha, Prathama S. Mainkar and Raju Adepu

Org. Biomol. Chem., 2022, 20, 9117
DOI: 10.1039/D2OB01662A

Site-selective and stereoselective transformations on p-quinols & p-quinamines

Satish B. Thopate, Mandalaparthi Phanindrudu, Sandip B. Jadhav and Rambabu Chegondi

Chem. Commun., 2023, 59, 3795
DOI: 10.1039/D3CC00509G

Bridged rings from phenolic feedstocks: regio- and diastereoselective substitution-hemiketalization cyclization of bridged benzoxocin-4-ones with Grignard reagents

Xiaojie Li, Yishuai Fan, Haoran Yang and Ruwei Shen

Org. Chem. Front., 2025, 12, 1858
DOI: 10.1039/D4QO02197E

In situ generation of highly reactive allenes from nitrocyclopropanes: controllable synthesis of enynes and enesters

Zhan-Yu Zhou, Zhong-Yang Xu, Qiao-Yu Shen, Li-Sha Huang, Xing Zhang, Ai-Bao Xia, Dan-Qian Xu and Zhen-Yuan Xu

Chem. Commun., 2021, 57, 6424
DOI: 10.1039/D1CC01573G

Palladium-catalyzed decarboxylation [2 + 2 + 2] annulation approach to chromone-containing polycyclic compounds

Yu-Chen Fang, Jia-He Chen, Ren-Feng Xiu, Li-Ren Zhang, Fang-Hua Zheng, Yong-Zheng Chen, Zi-Wei Gao and Wen-Yong Han

Org. Chem. Front., 2023, 10, 3752
DOI: 10.1039/D3QO00764B

Diastereo- and enantioselective rhodium(iii)-catalyzed reductive cyclization of cyclohexadienone-containing 1,6-dienes

Yun-Xuan Tan, Pei-Ying Peng, Ya-Jie Wang, Xi-Liang Liu, Wenbo Ye, Dingding Gao, Guo-Qiang Lin and Ping Tian

Chem. Commun., 2021, 57, 9724
DOI: 10.1039/D1CC03645A

Asymmetric synthesis of bicyclic pyran scaffolds bearing two oxa-quaternary stereocenters via zinc-catalyzed [5 + 1] annulations

Cui Zhang, Tao Jiang, Yuan-Zhao Hua, Guang-Jian Mei, Min-Can Wang and Shi-Kun Jia

Org. Chem. Front., 2023, 10, 4516
DOI: 10.1039/D3QO00925D

Stereocontrolled desymmetrization of 2,5-cyclohexadienones via organocatalytic domino sulfa-1,6-/1,4-addition or sulfa-1,6-/1,4-/sulfa-1,4-addition reactions

Vanisha Sodhi, Deepak Sharma, Manisha Sharma and Pankaj Chauhan

Org. Chem. Front., 2025, 12, 1144
DOI: 10.1039/D4QO02097A

A Vanadium‐Based Fluoroxide Cathode Material for Lithium‐Ion Storage with High Energy Density

Xiaolong He, Qi Yan, Haiyan He, Jian Shang, Xiaolong Zhou, Narong Chanlek, Sarayut Tunmee, Pinit Kidkhunthod, Wenjiao Yao and Yongbing Tang

Advanced Sustainable Systems, 2022, 6
DOI: 10.1002/adsu.202200122

Enantioselective Divergent Total Syntheses of Cycloaurenones and Dysiherbols

Yu‐Hao Huang, Qing‐Xiu Gu, Qing‐Cen Chao, Han‐Zhi Xiao and Hai‐Hua Lu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202507638

Silver‐Catalyzed [3+2] Cycloaddition for the Diastereoselective Synthesis of anti‐3‐Substituted Hydroindolin‐2‐Imines

Zhongtao Yang, Xiai Luo, Zhipeng Zhang, Xiaoling Luo, Jia Zheng, Hui Luo and Weiguang Yang

Adv Synth Catal, 2022, 364, 4433
DOI: 10.1002/adsc.202200993

Sequential Cu(II)-Catalyzed Multicomponent C–N Coupling, Nucleophilic Addition, and Cyclization Cascade: A Diastereoselective Approach to Carboxamide-Embedded Hexahydrobenzofuran Core

Anchal Saxena and Nayan Ghosh

J. Org. Chem., 2023, 88, 300
DOI: 10.1021/acs.joc.2c02320

A Highly Enantioselective Homoenolate Michael Addition/Esterification Sequence of Cyclohexadienone-Tethered Enals via NHC Catalysis

Ya-Jie Wang, Yi-Fan Wang, Wen-Yu Kang, Wen-Ya Lu, Yu-Hui Wang and Ping Tian

Org. Lett., 2023, 25, 630
DOI: 10.1021/acs.orglett.2c04183

Enantioselective Reductive Cyclization of Alkynyl-Tethered Cyclohexadienones Catalyzed by Rhodium Complexes

Yi-Fan Wang, Feng Wang, Dan-Dan Yang, Prasat Kittakoop, Yun-Xuan Tan and Ping Tian

Org. Lett., 2024, 26, 5614
DOI: 10.1021/acs.orglett.4c01276

An evolved artificial radical cyclase enables the construction of bicyclic terpenoid scaffolds via an H-atom transfer pathway

Dongping Chen, Xiang Zhang, Anastassia Andreevna Vorobieva, Ryo Tachibana, Alina Stein, Roman P. Jakob, Zhi Zou, Damian Alexander Graf, Ang Li, Timm Maier, Bruno E. Correia and Thomas R. Ward

Nat. Chem., 2024, 16, 1656
DOI: 10.1038/s41557-024-01562-5

Divergent Synthesis of Multisubstituted Hydroindole Derivatives via [3+2] Annulations of p‐Quinamines with Nitroalkenes

Hao Qin, Didi Liu, Bingrui Wan, Zhe Liu, Yan Ding, Haonan Zong, Yi Huang, Liang‐Hua Zou and Zengwei Lai

Adv Synth Catal, 2024, 366, 4654
DOI: 10.1002/adsc.202400647

Diastereoselective and Regioselective Tunable Cascade Annulation of Prochiral Enone-Tethered Cyclohexadienones

Ramulu Dhanavath, Tarun Nallamilli, Anandarao Munakala, Jagadeesh Babu Nanubolu and Rambabu Chegondi

Org. Lett., 2025, 27, 7879
DOI: 10.1021/acs.orglett.5c02189

Catalytic Asymmetric Synthesis of Aza-Quaternary Carbon Cyclohexadieneones Enabled by Aminative Dearomatization of Phenols

Yu Chen, Shi-Kun Jia, Xiao Xiao, Min-Can Wang, Lihua Huang and Guang-Jian Mei

Org. Lett., 2023, 25, 4740
DOI: 10.1021/acs.orglett.3c01746

Design and Synthesis of Planar-Chiral Oxazole–Pyridine N,N-Ligands: Application in Palladium-Catalyzed Asymmetric Acetoxylative Cyclization

Yu-Qing Bai, Xin-Wei Wang, Bo Wu, Xiao-Qing Wang, Rong-Zheng Liao, Man Li and Yong-Gui Zhou

ACS Catal., 2023, 13, 9829
DOI: 10.1021/acscatal.3c01163

Access to N-α-quaternary chiral morpholines via Cu-catalyzed asymmetric propargylic amination/desymmetrization strategy

Peng Chen, Mao-Mao Zhang, Li Rao, Yuan-Heng Li, Yue Jia, Ying Tan, Wen-Jing Xiao and Liang-Qiu Lu

Science Bulletin, 2024, 69, 3516
DOI: 10.1016/j.scib.2024.08.005

Cu-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition of N-2,2,2-Trifluoroethylisatin Ketimines Enables the Desymmetrization of N-Arylmaleimides: Access to Enantioenriched F3C-Containing Octahydropyrrolo[3,4-c]pyrroles

Zhen-Hua Wang, Ji-Hong Liu, Yan-Ping Zhang, Jian-Qiang Zhao, Yong You, Ming-Qiang Zhou, Wen-Yong Han and Wei-Cheng Yuan

Org. Lett., 2022, 24, 4052
DOI: 10.1021/acs.orglett.2c01510

Desymmetrization of Cyclohexadienones Containing a Quaternary γ-Carbon Atom by Conjugate Addition of Boron Nucleophiles

Zhi-Yuan Zhao, Ming Cui, Anne A. Poletti, Elisabeth Irran and Martin Oestreich

ACS Catal., 2024, 14, 176
DOI: 10.1021/acscatal.3c04725

Stereodivergent Synthesis of Epoxides and Oxazolidinones via the Halohydrin Dehalogenase-Catalyzed Desymmetrization Strategy

Qin Xu, Kai-Shun Huang, Yuan-Fei Wang, Hui-Hui Wang, Bao-Dong Cui, Wen-Yong Han, Yong-Zheng Chen and Nan-Wei Wan

ACS Catal., 2022, 12, 6285
DOI: 10.1021/acscatal.2c00718

Organocatalytic Enantioselective Intramolecular (Hetero)Michael Additions in Desymmetrization Processes

Marcos Escolano, Daniel Gaviña, Javier Torres, Santiago Díaz‐Oltra and Carlos del Pozo

Eur J Org Chem, 2021, 2021, 2923
DOI: 10.1002/ejoc.202100311

Enantioselective Divergent Total Syntheses of Cycloaurenones and Dysiherbols

Yu‐Hao Huang, Qing‐Xiu Gu, Qing‐Cen Chao, Han‐Zhi Xiao and Hai‐Hua Lu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202507638

One-Pot Synthesis of Chiral Spiro-Imidazolidinone Cyclohexenones

Dung Tien Do

J. Org. Chem., 2025, 90, 529
DOI: 10.1021/acs.joc.4c02459

Enantioselective Desymmetrization of 1,3‐Dicarbonyl Compounds through Transition‐Metal‐Catalyzed Intramolecular Cyclization Reactions

Ren‐Xiao Liang, Jia‐Qi Xie, Hu‐Jie Cai, Shuo Sun, Jia‐Yi Wang, Wei‐Chao Deng and Yi‐Xia Jia

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400947

Enantioselective Desymmetrization Triggered by Iminium‐Enamine Activation: Access to Complex Cyclohepta[b]indoles

Lakshmi Revati Magham, Satish B. Thopate, Abdus Samad and Rambabu Chegondi

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203435

Desymmetrization of 1,4‐Diynes by Allylic Alcohol‐Triggered Redox Enyne Cycloisomerization

Fangyuan Wang, Wenxuan Lin, Chia Hui Yeh, Yu Lan and Yu Zhao

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202421153

Palladium-Catalyzed Asymmetric Desymmetrization for the Simultaneous Construction of Chiral Phosphorus and Quaternary Carbon Stereocenters

Hengrui Zhou, Yiji Xue, Xiang Zhou, Hequan Yao and Aijun Lin

Org. Lett., 2024, 26, 5934
DOI: 10.1021/acs.orglett.4c01863

Rhodium‐Catalyzed Asymmetric Reductive Cyclization of Cyclohexadienone‐Tethered (Z)‐α,β‐Unsaturated Amides

Jian‐Wei Zhang, Shu‐Hui Li, Qing‐Hua Li and Ping Tian

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500052

Silver-Catalyzed Asymmetric Desymmetrization of Cyclohexadienones via Van Leusen Pyrrole Synthesis

Mohamed Ahmed Abozeid, Hun Young Kim and Kyungsoo Oh

Org. Lett., 2022, 24, 1812
DOI: 10.1021/acs.orglett.2c00240

Reactions of Rhenacyclobutadiene Complexes with Allenes

Wei Wei, Xin Xu, Ka-Ho Lee, Ran Lin, Herman H. Y. Sung, Ian D. Williams, Zhenyang Lin and Guochen Jia

Organometallics, 2021, 40, 3753
DOI: 10.1021/acs.organomet.1c00493

DFT-Driven Elucidation of Stereoselectivity in the NHC-Catalyzed Asymmetric Annulation of Cyclohexadienone-Tethered Enal

Zheng-Yang Yi, Donghui Wei, Shihao Sun and Yang Wang

J. Phys. Chem. A, 2025, 129, 6226
DOI: 10.1021/acs.jpca.5c02105

Palladium(II)-Catalyzed Desymmetrization of 2-Alkynylbenzoate-Tethered Cyclohexadienones for the Synthesis of Polycyclic Compounds

Archana Rai, Priyam Bajpai, Rama Krishna Gamidi, Kumar Vanka and Utpal Das

Org. Lett., 2025, 27, 5429
DOI: 10.1021/acs.orglett.5c01396

Polycyclic Pyrazoles from Alkynyl Cyclohexadienones and Nonstabilized Diazoalkanes via [3 + 2]-Cycloaddition/[1,5]-Sigmatropic Rearrangement/Aza-Michael Reaction Cascade

Raj Kumar Patel, Priyankar Jha, Anil Chauhan, Ruchir Kant and Ravindra Kumar

Org. Lett., 2024, 26, 839
DOI: 10.1021/acs.orglett.3c03967

Rhodium(I)/Chiral Diene Complexes Catalyzed Asymmetric Desymmetrization of Alkynyl-Tethered 2,5-Cyclohexadienones Through an Arylative Cyclization Cascade

Yu-Yi Cheng, Ting-Shen Kuo, Ping-Yu Wu, Jen-Chieh Hsieh and Hsyueh-Liang Wu

J. Org. Chem., 2024, 89, 4861
DOI: 10.1021/acs.joc.4c00053

Catalytic Friedel–Crafts Alkylative Desymmetrization of Cyclohexa-2,5-dienones: Access to Linear and Bridged Polycyclic Pyrroles and 3-Arylpyrroles

Raj Kumar Patel, Anil Chauhan, Priyankar Jha, Ruchir Kant and Ravindra Kumar

Org. Lett., 2022, 24, 5422
DOI: 10.1021/acs.orglett.2c02135

N‐Heterocyclic Carbene‐Catalyzed Asymmetric Cyclization of Cyclohexadienone‐Tethered Ynals to Stereodivergent 6,5‐Bicyclic and 6,5,5‐Tricyclic Products

Wen‐Yu Kang, Ya‐Jie Wang, Hong Lin, Xiaodi Yang, Yu‐Hui Wang and Ping Tian

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500305

Transition‐Metal Catalyzed Stereoselective Desymmetrization of Prochiral Cyclohexadienones

Anandarao Munakala, Mandalaparthi Phanindrudu and Rambabu Chegondi

The Chemical Record, 2021, 21, 3689
DOI: 10.1002/tcr.202100136

Rhodium-Catalyzed Enantioselective and Desymmetrizative Pauson–Khand Reaction: Access to Tricyclo[6.2.1.04,11]undecenes

Pengfei Yang, Yaodu Zhang, Ming Chen, Qingyang Zhao, Zhi-Hui Ren and Zheng-Hui Guan

Org. Lett., 2021, 23, 9241
DOI: 10.1021/acs.orglett.1c03589

New 3d multifunctional metal chelates of sulfonamide: Spectral, vibrational, molecular modeling, DFT, medicinal and in silico studies

Abrar Ul Hassan, Sajjad Hussain Sumrra, Muhammad Imran and Zahid Hussain Chohan

Journal of Molecular Structure, 2022, 1254, 132305
DOI: 10.1016/j.molstruc.2021.132305

Enantioselective Synthesis of P-Chiral Phosphine Oxides Bearing an All-Carbon Quaternary Stereogenic Center via Palladium-Catalyzed Domino Heck–Suzuki Reaction

Siyu Zhao, Jiahao Liu, Xunfang Xu, Xuemei Chen, Terumasa Kato, Zhe Wang, Yan Liu and Keiji Maruoka

ACS Catal., 2024, 14, 14762
DOI: 10.1021/acscatal.4c04958

Desymmetrization of 1,4‐Diynes by Allylic Alcohol‐Triggered Redox Enyne Cycloisomerization

Fangyuan Wang, Wenxuan Lin, Chia Hui Yeh, Yu Lan and Yu Zhao

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202421153

Tf2O/2-Chloropyridine-Triggered Synthesis of Benzo[b]thiophene 1,1-Dioxides from Sulfonium α-Acyl Sulfonylmethylides

Duo Fu and Jiaxi Xu

J. Org. Chem., 2024, 89, 3072
DOI: 10.1021/acs.joc.3c02540

Synthesis of Tricyclic Fused 6–5–4 Carbocycles via Acid-Promoted Cascade Intramolecular Cyclization of Allenylsilane-Tethered Cyclohexadienones

Yuka Iwakiri, Ryoma Kishimoto, Kazuhiko Sakaguchi and Takahiro Nishimura

Org. Lett., 2024, 26, 3475
DOI: 10.1021/acs.orglett.4c01108

Rhodium-Catalyzed Desymmetric Arylation of γ,γ-Disubsituted Cyclohexadienones: Asymmetric Synthesis of Chiral All-Carbon Quaternary Centers

Yu Qiao, Shiming Bai, Xiao-Feng Wu, Ying Yang, He Meng and Jialin Ming

Org. Lett., 2022, 24, 1556
DOI: 10.1021/acs.orglett.2c00225

Palladium(0)-Catalyzed Remote Decarboxylative Allylation and Base-Mediated 1,3-Migration

Ashok Donthoju, Anandarao Munakala, Sushma Ellandula and Rambabu Chegondi

J. Org. Chem., 2022, 87, 8267
DOI: 10.1021/acs.joc.2c00961

Enantiodivergent Cyclization of Racemic Cyclohexadienones via Parallel Kinetic Asymmetric Transformation

Xiang Gao, Bei-Bei Li, Yu-Wei Li, Xiao Xiao, Meng-Meng Liu and Guang-Jian Mei

Org. Lett., 2024, 26, 6290
DOI: 10.1021/acs.orglett.4c02396

Visible Light‐Mediated Manipulation of 1,n‐Enynes in Organic Synthesis

Roshan I. Patel, Jitender Singh and Anuj Sharma

ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202200260

Recent Developments in Enantioselective Domino Reactions. Part B: First Row Metal Catalysts

Hélène Pellissier

Adv Synth Catal, 2023, 365, 768
DOI: 10.1002/adsc.202300002

Chiral Phosphoric Acid–Palladium(II) Complex Catalyzed Asymmetric Desymmetrization of Biaryl Compounds by C(sp3)–H Activation

Tatsuhiro Uchikura, Sotaro Kato, Yudai Makino, Megumi J. Fujikawa, Masahiro Yamanaka and Takahiko Akiyama

J. Am. Chem. Soc., 2023, 145, 15906
DOI: 10.1021/jacs.3c03552

Recent Developments in Enantioselective Domino Reactions. Part A: Noble Metal Catalysts

Hélène Pellissier

Adv Synth Catal, 2023, 365, 620
DOI: 10.1002/adsc.202201284

[2 + 3] Cycloaddition of para-Quinamines and para-Quinols with C,N-Cyclic Azomethine Imines: Access to 6/5/6/6-Fused Tetracyclic Pyrazolidines

Zhe Liu, Yan Ding, Mingbin Chen, Feng Lv, Ting Xiao, Wen-Bin Liu, Bingrui Wan, Ling Huang, Yong Rao and Zengwei Lai

Org. Lett., 2025, 27, 6257
DOI: 10.1021/acs.orglett.5c01087

Progress in the Synthesis of Hydrobenzofurans from O-Cyclohexadienone-tethered 1,6-Enynes

Zhiqing Li, Xiaoyang Qiu, Nan Meng and Zhuqing Liu

Chinese Journal of Organic Chemistry, 2021, 41, 4306
DOI: 10.6023/cjoc202105029

Copper‐Catalyzed Olefination of 4‐CF3‐Substituted Cyclohexadienones Using Sulfonylmethyl Isocyanides: An Electrostatic Repulsion‐Controlled Regioselectivity Switch Strategy

Seungwon Lee, Mohamed Ahmed Abozeid, Hun Young Kim and Kyungsoo Oh

Adv Synth Catal, 2023, 365, 600
DOI: 10.1002/adsc.202201333

Rhodium(III)-Catalyzed Asymmetric Reductive Cyclization of Cyclohexadienone-Containing 1,6-Dienes via an Anti-Michael/Michael Cascade Process

Hao Xu, Yun-Xuan Tan, Pei-Pei Xie, Rui Ding, Qi Liao, Jian-Wei Zhang, Qing-Hua Li, Yu-Hui Wang, Xin Hong, Guo-Qiang Lin and Ping Tian

ACS Catal., 2021, 11, 8015
DOI: 10.1021/acscatal.1c02431

Reaction of 4-(Alkynyloxy)cyclohexa-2,5-dienones with Dimethyl Sulfoxide: A Catalyst-Free Formation of 6/5/3-Fused Tricyclic Enones

Archana Rai and Utpal Das

J. Org. Chem., 2025, 90, 653
DOI: 10.1021/acs.joc.4c02553

Enantioselective Allylboration of Acetylene: A Versatile Tool for the Stereodivergent Synthesis of Natural Products

Andrés M. Álvarez‐Constantino, Andrea Chaves‐Pouso and Martín Fañanás‐Mastral

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202407813

Recent Progress in Asymmetric Domino Intramolecular Cyclization/Cascade Reactions of Substituted Olefins

Liang Zou, Yuan Gao, Qiaoman Zhang, Xiang‐Yang Ye, Tian Xie, Li‐Wei Wang and Yang Ye

Chemistry An Asian Journal, 2023, 18
DOI: 10.1002/asia.202300617

Osmium(II)-Induced Rearrangement of Allenols for Metallafuran Complexes

Hau-Lam Shek, King-Ting Tam, Shek-Man Yiu, Man-Kit Tse, Robert H. Morris and Chun-Yuen Wong

Organometallics, 2022, 41, 1931
DOI: 10.1021/acs.organomet.2c00113

Ene-Reductase-Catalyzed Enantioselective Desymmetrization of Cyclohexadienones: Straightforward Access to All-Carbon Quaternary Stereocenters

Xiaofan Wu, Lin Yang, Zhigang Liu, Ke Zhang, Zedu Huang and Fener Chen

ACS Catal., 2024, 14, 6194
DOI: 10.1021/acscatal.4c00239

Catalytic asymmetric dearomatization of phenols via divergent intermolecular (3 + 2) and alkylation reactions

Xiang Gao, Tian-Jiao Han, Bei-Bei Li, Xiao-Xiao Hou, Yuan-Zhao Hua, Shi-Kun Jia, Xiao Xiao, Min-Can Wang, Donghui Wei and Guang-Jian Mei

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-40891-w

Cascade Reaction of 2-Naphthols and Azirines: One-Pot Synthesis of C-3 Naphthol-Substituted Benzo[e]indoles

Fang Xie, Yajun Sun, Hanghang Song, Jie Zhao, Zengpeng Zhang, Yue Duan and Rao Chen

J. Org. Chem., 2021, 86, 15631
DOI: 10.1021/acs.joc.1c02164

Rhodium(III)-catalyzed diastereo- and enantioselective hydrosilylation/cyclization reaction of cyclohexadienone-tethered α,β-unsaturated aldehydes

Yi-Fan Wang, Hao-Yun Yu, Hao Xu, Ya-Jie Wang, Xiaodi Yang, Yu-Hui Wang, Ping Tian and Guo-Qiang Lin

Chinese Chemical Letters, 2024, 35, 109520
DOI: 10.1016/j.cclet.2024.109520

Synthesis of Chiral Polycyclic Indoles via Pd(II)-Catalyzed Sequential Cyclization and Carbonylation

Long Chen, Hengrui Zhou, Yiji Xue, Lingyu Kong, Yi Wang, Xuyao Han, Hequan Yao and Aijun Lin

ACS Catal., 2024, 14, 8739
DOI: 10.1021/acscatal.4c01325

Recent advances towards organocatalytic enantioselective desymmetrizing reactions

Yin Xu, Tong-Yi Zhai, Zhou Xu and Long-Wu Ye

Trends in Chemistry, 2022, 4, 191
DOI: 10.1016/j.trechm.2021.12.010

Pd-Catalyzed Asymmetric Dearomative Arylation of Indoles via a Desymmetrization Strategy

Yu-Han Nie, Masaaki Komatsuda, Ping Yang, Chao Zheng, Junichiro Yamaguchi and Shu-Li You

Org. Lett., 2022, 24, 1481
DOI: 10.1021/acs.orglett.2c00129

Pd(0)-Catalyzed Asymmetric Cyclization/Coupling Cascade of Alkyne-Tethered Unsaturated Carbonyls: Development and Mechanism Elucidation

Yi Zhang, Lei Zhu, Xue Song, Xiao-Jun Wang, Bo Zhu, Qin Ouyang, Wei Du and Ying-Chun Chen

J. Am. Chem. Soc., 2024, 146, 5977
DOI: 10.1021/jacs.3c12685

Steric- and Electronic-Controlled Intramolecular [2 + 2]-Cycloaddition of Cyclohexadienone-Containing 1,7-Enynes

Anandarao Munakala, Tarun Nallamilli, Jagadeesh Babu Nanubolu and Rambabu Chegondi

Org. Lett., 2022, 24, 892
DOI: 10.1021/acs.orglett.1c04232

Enantioselective Allylboration of Acetylene: A Versatile Tool for the Stereodivergent Synthesis of Natural Products

Andrés M. Álvarez‐Constantino, Andrea Chaves‐Pouso and Martín Fañanás‐Mastral

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202407813

Palladium-Catalyzed [3 + 2] Annulation of Aryl Halides with 7-Oxa- and 7-Azabenzonorbornadienes via C(sp2 or sp3)–H Activation

Xiaojiao Li, Xianting Pan, Zisong Qi and Xingwei Li

Org. Lett., 2022, 24, 8964
DOI: 10.1021/acs.orglett.2c03422

Bifunctional Iminophosphorane Catalyzed Amide Enolization for Enantioselective Cyclohexadienone Desymmetrization

Charmaine Y. X. Poh, Daniel Rozsar, Jinchao Yang, Kirsten E. Christensen and Darren J. Dixon

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202315401

Catalytic Desymmetric Dicarbofunctionalization of Unactivated Alkenes

Xianqing Wu, Baixue Luan, Wenyu Zhao, Feng He, Xin‐Yan Wu, Jingping Qu and Yifeng Chen

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202111598

Asymmetric Synthesis of Hydrophenanthrenones Bearing Multiple Stereogenic Centers via Squaramide-Catalyzed Domino 1,4-/1,4-Addition Desymmetrization Sequence

Manisha Sharma, Tamanna and Pankaj Chauhan

Org. Lett., 2023, 25, 7911
DOI: 10.1021/acs.orglett.3c03167

Chiral Ag‐Complex Catalyzed Enantioselective α‐Functionalization of Cyclic Azomethine Ylides with Concomitant Remote‐Controlled Asymmetric Desymmetrization of N‐Arylmaleimides and Cyclopentene‐1,3‐diones

Ji‐Hong Liu, Jian‐Mei Wang, Yan‐Ping Zhang, Zhen‐Hua Wang, Lei Yang, Jian‐Qiang Zhao, Ming‐Qiang Zhou, Yong You and Wei‐Cheng Yuan

Chin. J. Chem., 2025, 43, 2029
DOI: 10.1002/cjoc.70076

Catalyst-Controlled Diastereoselective Synthesis of Bridged [3.3.1] Bis(Indolyl)-Oxanes and Oxepanes via Desymmetrization of Bis(Indolyl)-Cyclohexadienones

Abhishek Kumar Mishra, Anil Chauhan, Santosh Kumar, Ruchir Kant and Ravindra Kumar

Org. Lett., 2023, 25, 3034
DOI: 10.1021/acs.orglett.3c00834

Catalytic desymmetrization reactions to synthesize all-carbon quaternary stereocentres

Pengwei Xu, Feng Zhou, Lei Zhu and Jian Zhou

Nat. Synth, 2023, 2, 1020
DOI: 10.1038/s44160-023-00406-3

Synthesis of Diastereomeric Hydrobenzofurans and Hydronaphthofurans via an Iodine Reagent-Promoted Intramolecular Dearomatization Reaction

Xinkun An, Haoyun Ma, Tingting Zhang, Guoen Cui, Xie He and Mingan Wang

J. Org. Chem., 2025, 90, 2760
DOI: 10.1021/acs.joc.4c02998

Benzocarbazole Synthesis via Visible-Light-Accelerated Rh(III)-Catalyzed C–H Annulation of Aromatic Amines with Bicyclic Alkenes

Yichun Wang, Deyang Jia, Jing Zeng, Yuming Liu, Xiubin Bu and Xiaobo Yang

Org. Lett., 2021, 23, 7740
DOI: 10.1021/acs.orglett.1c02709

Desymmetrization of Cyclohexadienones through Phase-Transfer-Catalyzed Stereoselective Intramolecular Aza-Michael Addition with Chiral Sulfinamide Nucleophiles

Bing-Syuan Wu, Yu-Wei Chao, Hong-Sing Chen and Cheng-Che Tsai

J. Org. Chem., 2023, 88, 12835
DOI: 10.1021/acs.joc.3c01253

Rhodium(I)‐Catalyzed Asymmetric Cascade Reactions

Yu‐Chu Yang, Wei‐Sian Li and Hsyueh‐Liang Wu

The Chemical Record, 2025, 25
DOI: 10.1002/tcr.202400231

Thiourea‐Promoted Cascade Dihalogenation‐Cyclization of Cyclohexadienone‐Containing 1,6‐Enynes

Jia‐Ying Zhao, Qi Liao, Jian‐Wei Zhang, Guo‐Qiang Lin, Zhengtao Wang, Dingding Gao, Qing‐Hua Li and Ping Tian

Adv Synth Catal, 2023, 365, 482
DOI: 10.1002/adsc.202201185

Synthesis of Tetrasubstituted Enamines Using Secondary Amines and In Situ-Generated Allenes from Nitrocyclopropanes

Zhong-Yang Xu, Jian-Sheng Wei, Li Liu, Qing-Bo Hu, Jin-Yao Zhu, Zhan-Yu Zhou, Ai-Bao Xia and Dan-Qian Xu

J. Org. Chem., 2024, 89, 13868
DOI: 10.1021/acs.joc.4c00829

Asymmetric Organocatalyzed Intermolecular Functionalization of Cyclohexanone‐Derived Dienones

Corinne Coutant, Paul De Bonfils, Pierrick Nun and Vincent Coeffard

The Chemical Record, 2023, 23
DOI: 10.1002/tcr.202300042

Bifunctional Iminophosphorane Catalyzed Amide Enolization for Enantioselective Cyclohexadienone Desymmetrization

Charmaine Y. X. Poh, Daniel Rozsar, Jinchao Yang, Kirsten E. Christensen and Darren J. Dixon

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202315401

Recent Advances in Catalytic Nonenzymatic Kinetic Resolution of Tertiary Alcohols

Bo Ding, Qilin Xue, Shihu Jia, Hong-Gang Cheng and Qianghui Zhou

Synthesis, 2022, 54, 1721
DOI: 10.1055/a-1712-0912

Desymmetrization of Cyclic 1,3-Diketones under N -Heterocyclic Carbene Organocatalysis: Access to Organofluorines with Multiple Stereogenic Centers

Guanjie Wang, Min Zhang, Yezhi Guan, Ye Zhang, Xianfang Hong, Chenlong Wei, Pengcheng Zheng, Donghui Wei, Zhenqian Fu, Yonggui Robin Chi and Wei Huang

Research, 2021, 2021
DOI: 10.34133/2021/9867915

Palladium-Catalyzed Asymmetric Tandem Carbonylation–Heck Reaction of Cyclopentenes to Access Chiral Bicyclo[3.2.1]octenes

Pengyun Liu, Hongyue Dong, Baihui Gong, Shang Gao, Aijun Lin and Hequan Yao

Org. Lett., 2024, 26, 8244
DOI: 10.1021/acs.orglett.4c02719

Synthesis of Chiral Heterocycles from Asymmetric Cascade Palladium Catalysis

Hélène Pellissier

COC, 2023, 27, 71
DOI: 10.2174/1385272827666230330084552

Advances in Chiral Pincer Complexes: Insights and Applications in Catalytic Asymmetric Reactions

Sanaa Musa, Yuval Peretz and Gil Dinnar

IJMS, 2024, 25, 10344
DOI: 10.3390/ijms251910344

Copper-Catalyzed Enantioselective Desymmetric Protosilylation of Prochiral Diynes: Access to Optically Functionalized Tertiary Alcohols

Zhi-Yuan Chen, Meng-Wei Yang, Zi-Lu Wang and Yun-He Xu

Org. Lett., 2023, 25, 5242
DOI: 10.1021/acs.orglett.3c01702

Desymmetrisation of meso‐2,4‐Dimethyl‐8‐oxabicyclo[3.2.1]‐oct‐6‐ene‐3‐ol and its Application in Natural Product Syntheses

Krishnaji Tadiparthi, Pragya Anand, Raghavendra Sakirolla, T. Prakash Gupta, Krishna A Jadhav, Sukant Kishore Das and Jhillu Singh Yadav

The Chemical Record, 2022, 22
DOI: 10.1002/tcr.202100286

Catalytic Desymmetric Dicarbofunctionalization of Unactivated Alkenes

Xianqing Wu, Baixue Luan, Wenyu Zhao, Feng He, Xin‐Yan Wu, Jingping Qu and Yifeng Chen

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202111598

Light Induced Diastereoselective Ketoesterification To Access 6,5-Fused Tetrahydrobenzofuranones in Batch and Continuous Flow Conditions

Vadla Shiva Prasad, Dharavath Ravi, Vadithya Ranga Rao, Silari Mohana Krishna, Chelukalapally Anil Kumar and Praveen Reddy Adiyala

J. Org. Chem., 2024, 89, 12628
DOI: 10.1021/acs.joc.4c01552

Solvent-Mediated Enantioselective Rauhut–Currier Cyclization via Iminium and Enamine Activation

Satish B. Thopate, Lakshmi Revati Magham, Shrabani Dinda and Rambabu Chegondi

Org. Lett., 2023, 25, 1072
DOI: 10.1021/acs.orglett.2c04249

Tandem Enantioselective Cycloaromatization/Intramolecular Friedel–Crafts Desymmetrization of Cyclohexadienones

Daniel Gaviña, Marta Durán, Lidia Prieto, Marcos Escolano, Santiago Díaz‐Oltra, María Sánchez‐Roselló and Carlos del Pozo

Adv Synth Catal, 2024
DOI: 10.1002/adsc.202400576

Diastereoselective Formal 1,3-Dipolar Cycloaddition of Trifluoroethyl Amine-Derived Ketimines Enables the Desymmetrization of Cyclopentenediones

Lin-Qiang Li, Jian-Qiang Zhao, Yan-Ping Zhang, Yong You, Zhen-Hua Wang, Zhen-Zhen Ge, Ming-Qiang Zhou and Wei-Cheng Yuan

Molecules, 2023, 28, 5372
DOI: 10.3390/molecules28145372