Issue 22, 2022

Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks

Abstract

Novel two-dimensional kagome metal–organic frameworks with mononuclear Zr4+/Hf4+ nodes chelated by benzene-1,4-dihydroxamate linkers were synthesized. The MOFs, namely SUM-1, are chemically robust and kinetically favorable, as confirmed by theoretical and experimental studies. SUM-1(Zr) can be readily made into large (∼100 μm) single crystals and nanoplates (∼50 nm), constituting a versatile MOF platform.

Graphical abstract: Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
13 jan. 2022
Accepted
25 jan. 2022
First published
26 jan. 2022

Chem. Commun., 2022,58, 3601-3604

Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks

Q. Lai, Z. Chu, X. Xiao, D. Dai, T. Song, T. Luo, W. Tang, X. Feng, Z. Zhang, T. Li, H. Xiao, J. Su and C. Liu, Chem. Commun., 2022, 58, 3601 DOI: 10.1039/D2CC00213B

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