Volume 244, 2023

Catalytic templated length-controlled oligomerization

Abstract

Templated synthesis is an intriguing strategy for the length-controlled synthesis of oligomers. Traditionally, such reactions require stoichiometric amounts of the template with respect to the product. Recently we reported catalytic macrocyclic templates that promote oligomerization of a small molecule substrate with a remarkable degree of length control. Herein we present our efforts toward creating linear templates for catalytic length-controlled oligomer synthesis.

Graphical abstract: Catalytic templated length-controlled oligomerization

Associated articles

Article information

Article type
Paper
Submitted
09 jan. 2023
Accepted
23 jan. 2023
First published
30 jan. 2023
This article is Open Access
Creative Commons BY-NC license

Faraday Discuss., 2023,244, 119-133

Catalytic templated length-controlled oligomerization

B. Lewandowski, R. J. B. Schäfer, E. Cotter, D. Harangozo and H. Wennemers, Faraday Discuss., 2023, 244, 119 DOI: 10.1039/D3FD00002H

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