Issue 10, 2017

Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

Abstract

The Fe-catalyzed insertion of fluoromethylcarbenes including trifluoromethylcarbene and difluoromethylcarbene generated in situ from sulfonium salts (Ph2S+CH2CF3OTf and Ph2S+CH2CF2H OTf) into X–H (X = Si, C and P) bonds is described. The insertion of both carbenes into the Si–H bond occurred smoothly, and trifluoromethylcarbene could also insert into C–H and P–H bonds.

Graphical abstract: Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

Supplementary files

Article information

Article type
Research Article
Submitted
01 jún. 2017
Accepted
19 jún. 2017
First published
20 jún. 2017

Org. Chem. Front., 2017,4, 1917-1920

Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

Y. Duan, J. Lin, J. Xiao and Y. Gu, Org. Chem. Front., 2017, 4, 1917 DOI: 10.1039/C7QO00430C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements