Enhancing the durability of Au clusters in CO2 photoreduction via encapsulation in Cu-based metal–organic frameworks

Jun Zhang; Xiaofeng Cui; Yu Zhou; Tingting Kong; Yixin Wang; Xianwen Wei; Yujie Xiong

doi:10.1039/D2CC06719F

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Enhancing the durability of Au clusters in CO₂ photoreduction via encapsulation in Cu-based metal–organic frameworks†

Jun Zhang,^a Xiaofeng Cui,*^ac Yu Zhou,^c Tingting Kong,*^a Yixin Wang,^a Xianwen Wei

^a and Yujie Xiong

*^ab

Author affiliations

* Corresponding authors

^a Anhui Engineering Research Center of Carbon Neutrality, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui, P. R. China
E-mail: xfcui@ahnu.edu.cn, ktt@ahnu.edu.cn, yjxiong@ustc.edu.cn

^b School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui, P. R. China

^c School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, Anhui, P. R. China

Abstract

Here, we report the encapsulation of Au₂₅ nanoclusters in a Cu₃(BTC)₂ metal–organic framework (Au₂₅@Cu-BTC), which can achieve CO₂ photoreduction for selective CO production in a gas–solid reaction system at low-concentration CO₂ atmospheres (even to 0.1%), with remarkably enhanced durability up to at least 48 h.

This article is part of the themed collection: Photofunctional Materials and Transformations

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Article information

DOI: https://doi.org/10.1039/D2CC06719F
Article type: Communication
Submitted: 09 pro 2022
Accepted: 30 sij 2023
First published: 30 sij 2023

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Chem. Commun., 2023,59, 2299-2302

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Enhancing the durability of Au clusters in CO₂ photoreduction via encapsulation in Cu-based metal–organic frameworks

J. Zhang, X. Cui, Y. Zhou, T. Kong, Y. Wang, X. Wei and Y. Xiong, Chem. Commun., 2023, 59, 2299 DOI: 10.1039/D2CC06719F

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Chemical Communications