Issue 40, 2014

A dual site catalyst for mild, selective nitrile reduction

Abstract

We report a novel ruthenium bis(pyrazolyl)borate scaffold that enables cooperative reduction reactivity in which boron and ruthenium centers work in concert to effect selective nitrile reduction. The pre-catalyst compound [κ3-(1-pz)2HB(N = CHCH3)]Ru(cymene)+ TfO (pz = pyrazolyl) was synthesized using readily-available materials through a straightforward route, thus making it an appealing catalyst for a number of reactions.

Graphical abstract: A dual site catalyst for mild, selective nitrile reduction

Supplementary files

Article information

Article type
Communication
Submitted
27 ruj 2013
Accepted
23 pro 2013
First published
24 pro 2013

Chem. Commun., 2014,50, 5391-5393

Author version available

A dual site catalyst for mild, selective nitrile reduction

Z. Lu and T. J. Williams, Chem. Commun., 2014, 50, 5391 DOI: 10.1039/C3CC47384H

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