Issue 6, 2018
From the journal:

Dalton Transactions

Homoleptic U(iii) and U(iv) amidate complexes†‡

M. D. Straub, ORCID logo ab   S. Hohloch, ORCID logo ab   S. G. Minasian ORCID logo b  and  J. Arnold ORCID logo ab  

a Department of Chemistry, University of California, Berkeley, CA, USA
E-mail: Arnold@berkeley.edu

b Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA

Abstract

The syntheses of the first homoleptic U(III) and U(IV) amidate complexes are described. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(III) complex to eight in the U(IV) complex in the solid state structures.

Graphical abstract: Homoleptic U(iii) and U(iv) amidate complexes

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Article information

DOI
https://doi.org/10.1039/C7DT04813K
Article type
Communication
Submitted
21 pro 2017
Accepted
10 sij 2018
First published
18 sij 2018

Dalton Trans., 2018,47, 1772-1776

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Homoleptic U(III) and U(IV) amidate complexes

M. D. Straub, S. Hohloch, S. G. Minasian and J. Arnold, Dalton Trans., 2018, 47, 1772 DOI: 10.1039/C7DT04813K

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