Issue 86, 2018

The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Abstract

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs’ valence orbitals are probed by soft X-ray absorption measurements.

Graphical abstract: The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Supplementary files

Article information

Article type
Communication
Submitted
28 lip 2018
Accepted
25 ruj 2018
First published
25 ruj 2018

Chem. Commun., 2018,54, 12206-12209

The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

T. Dumas, D. Guillaumont, P. Moisy, D. K. Shuh, T. Tyliszczak, P. L. Solari and C. Den Auwer, Chem. Commun., 2018, 54, 12206 DOI: 10.1039/C8CC05176C

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