Issue 29, 2013
From the journal:

Chemical Communications

Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions†‡

Ganesh Majji,a   Srimanta Guin,a   Anupal Gogoi,a   Saroj Kumar Routa  and  Bhisma K. Patel*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Guwahati, Assam, India
E-mail: patel@iitg.ernet.in
Fax: +91-3612690762

Abstract

An efficient metal free protocol has been developed for the synthesis of benzylic esters via a cross dehydrogenative coupling (CDC) involving alkylbenzene(s) as a self- or as a cross-coupling partner(s) via the intermediacy of Ar–COOH and the benzylic carbocation obtained from the other half of the alkylbenzene; both symmetrical as well as unsymmetrical esters can be prepared using Bu4NI and TBHP.

Graphical abstract: Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

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Article information

DOI
https://doi.org/10.1039/C3CC40832A
Article type
Communication
Submitted
31 sij 2013
Accepted
25 vlj 2013
First published
25 vlj 2013

Chem. Commun., 2013,49, 3031-3033

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Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

G. Majji, S. Guin, A. Gogoi, S. K. Rout and B. K. Patel, Chem. Commun., 2013, 49, 3031 DOI: 10.1039/C3CC40832A

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