Themed collection Magnetic Nanoparticles: From Massart Method to a Cascade of Innovations

48 items
Minireview

Recent advances on high-entropy strategies developed for high-performance NASICON-type cathodes for sodium ion batteries: a mini review

High-entropy strategy has attracted researchers’ attention for obtaining NASICONs with outstanding electrochemical performance while maintaining a simple synthesis route and low costs, paving the way for mass production of sodium ion batteries.

Graphical abstract: Recent advances on high-entropy strategies developed for high-performance NASICON-type cathodes for sodium ion batteries: a mini review
From the themed collection: Recent Review Articles
Open Access Review Article

Massart iron oxide nanoparticles in mechanobiology

Magnetic nanoparticles (MNPs) derived from the Massart coprecipitation method have played a pioneering role in bridging materials science and biology.

Graphical abstract: Massart iron oxide nanoparticles in mechanobiology
Open Access Review Article

Magnetically driven, plant-extract-modified Fe3O4 nanoparticles for sustainable and eco-friendly wastewater detoxification: recent developments

A review of plant extract mediated Fe3O4 nanoparticles, their characterization, pollutant removal efficiency, interaction mechanisms, toxicity, reusability, and effects of interfering ions on water treatment is presented.

Graphical abstract: Magnetically driven, plant-extract-modified Fe3O4 nanoparticles for sustainable and eco-friendly wastewater detoxification: recent developments
Open Access Review Article

Magnetic hyperthermia in focus: emerging non-cancer applications of magnetic nanoparticles

Magnetic hyperthermia extends beyond oncology, harnessing nanoscale heat generation for advanced bioapplications, catalytic processes, and environmental technologies.

Graphical abstract: Magnetic hyperthermia in focus: emerging non-cancer applications of magnetic nanoparticles
Open Access Communication

Tailoring inter-core distance of clustered SPIONs using silica spacers for enhanced magnetic particle imaging (MPI)

Silica spacers tune inter-core interactions in clustered SPIONS, enabling cooperative magnetisation switching and enhanced Magnetic Particle Imaging (MPI) performance.

Graphical abstract: Tailoring inter-core distance of clustered SPIONs using silica spacers for enhanced magnetic particle imaging (MPI)
Open Access Communication

Synthesis and characterization of platinum-decorated iron carbide nanoparticles and their potential for magnetically induced catalysis

Platinum-decorated iron carbide nanoparticles (Pt@ICNPs) are prepared, characterized, and applied in magnetically induced catalysis for the hydrogenation of various functionalities under mild conditions.

Graphical abstract: Synthesis and characterization of platinum-decorated iron carbide nanoparticles and their potential for magnetically induced catalysis
Open Access Communication

How octopod Mn–Fe oxide nanoparticle tracers minimize relaxation time and enhance MPI resolution

25 nm Octopod Mn–Fe oxide nanoparticles reduce crystal anisotropy, leading to faster relaxation times, a narrower MPI point spread function (PSF), and consequently improved spatial resolution.

Graphical abstract: How octopod Mn–Fe oxide nanoparticle tracers minimize relaxation time and enhance MPI resolution
Open Access Accepted Manuscript - Paper

Tuning field amplitude to minimise heat-loss variability in magnetic hyperthermia

Open Access Accepted Manuscript - Paper

Reassessing the Role of Carbon Shells in Magnetite Nanoparticles: A Comparative Adsorption Study of Ionic Dyes

Open Access Accepted Manuscript - Paper

Compositional Control of the Effective Magnetic Anisotropy in Mn and Co Substituted Spinel Nanoparticles

Paper

From degradation to (re)magnetization: magnetic reprogramming of maghemite (Massart), magnetite, cobalt ferrite and ferrihydrite nanoparticles by human stem cells

Structural and magnetic biotransformations of iron-based nanoparticles (maghemite, magnetite, cobalt ferrite, and ferrihydrite) reveal distinct biodegradation and re-magnetization kinetics in cellular models.

Graphical abstract: From degradation to (re)magnetization: magnetic reprogramming of maghemite (Massart), magnetite, cobalt ferrite and ferrihydrite nanoparticles by human stem cells
Open Access Paper

Magnetite nanodiscs as vortex-enhanced MRI contrast agents: a novel approach in medical imaging

Magnetic nanodiscs (MNDs) represent a transformative class of anisotropic magnetic nanoparticles with intrinsic vortex magnetization, enabling multifunctional applications in biomedical imaging and therapy.

Graphical abstract: Magnetite nanodiscs as vortex-enhanced MRI contrast agents: a novel approach in medical imaging
Open Access Paper

Single-particle ICP-MS characterization of magnetoliposomes: toward measurement of the number distribution of encapsulated magnetic nanoparticles

Characterizing the number distribution of encapsulated magnetic nanoparticles in magnetoliposomes using single-particle ICP-MS.

Graphical abstract: Single-particle ICP-MS characterization of magnetoliposomes: toward measurement of the number distribution of encapsulated magnetic nanoparticles
Open Access Accepted Manuscript - Paper

Investigation of the Chemical Structure of Core–Shell Fe₃O₄@Ni1-xCoxFe₂O₄ Nanoparticles and Its Influence on Their Magnetic Properties

Paper

Decoding magnetization and magnetic anisotropy in core@shell ferrite nanoparticles: interplay between cation distribution and spin disorder

The tailoring of magnetic properties in spinel ferrite nanoparticles for theranostic applications relies heavily on the precise control of their chemical composition and crystalline structure.

Graphical abstract: Decoding magnetization and magnetic anisotropy in core@shell ferrite nanoparticles: interplay between cation distribution and spin disorder
Open Access Paper

Smart pH-responsive magnetic iron oxide nanoflower–chitosan nanogels for controlled drug delivery in cancer therapy

This work presents a systematic study comparing several different crosslinking strategies using NaOH, tripolyphosphate and glutaraldehyde to identify the optimum conditions for the best colloidal stability, pH-responsive drug release and suitable size for intratumoral injection.

Graphical abstract: Smart pH-responsive magnetic iron oxide nanoflower–chitosan nanogels for controlled drug delivery in cancer therapy
Open Access Paper

Biomarker-targeted functionalized magnetic nanoparticles: synthesis and aptamer conjugation optimization toward Alzheimer's disease biosensing

Optimized synthesis and aptamer functionalization of hybrid Au@Fe nanoparticles provide a stable magnetic-plasmonic platform with high loading capacity and reproducibility for Alzheimer's disease biomarker detection.

Graphical abstract: Biomarker-targeted functionalized magnetic nanoparticles: synthesis and aptamer conjugation optimization toward Alzheimer's disease biosensing
Open Access Paper

Surfactant-coated iron oxide nanoparticles synthesized by coprecipitation as potential phosphate adsorbents in peritoneal dialysis

Iron oxide nanoparticles (IONPs) are recently shown to be effective phosphate adsorbents for enhancing phosphate removal during peritoneal dialysis (PD) treatment.

Graphical abstract: Surfactant-coated iron oxide nanoparticles synthesized by coprecipitation as potential phosphate adsorbents in peritoneal dialysis
Paper

A Swiss army knife for the treatment of bone cancers: a new multifunctional platform based upon SPIONs@copper-doped bioactive glass core–shell nanoparticles

Mesoporous γ-Fe2O3@SiO2–CaO–CuO nanoparticles were prepared. Their potential as an MRI contrast agent and hyperthermia treatment and under the respectively tested conditions, both antibacterial effect and absence of cytotoxicity were demonstrated.

Graphical abstract: A Swiss army knife for the treatment of bone cancers: a new multifunctional platform based upon SPIONs@copper-doped bioactive glass core–shell nanoparticles
Open Access Paper

Influence of particle size, shape, and magnetic properties on torque-driven biofilm removal using anisotropic magnetic particles

Using rotating magnetic fields and different anisotropic magnetic particles to deliver controlled mechanical stress, persistent Enterococcus faecalis biofilms were disrupted.

Graphical abstract: Influence of particle size, shape, and magnetic properties on torque-driven biofilm removal using anisotropic magnetic particles
Open Access Paper

Translating magnetic fluid hyperthermia toward lung cancer treatment

Magnetic fluid hyperthermia (MFH) emerges as a potential new therapeutic strategy for the treatment of lung cancer.

Graphical abstract: Translating magnetic fluid hyperthermia toward lung cancer treatment
Paper

Amine- and hydroxyl-functionalization of iron nanoparticles for tailoring the properties of Fmoc-FF-based magnetic hydrogels: interfacial design toward biocompatible materials

Magnetic iron nanoparticles functionalized with hydroxyl and amine groups were incorporated into short peptide-based (Fmoc-FF) supramolecular hydrogels, producing biocompatible systems with high potential for advanced biomedical applications.

Graphical abstract: Amine- and hydroxyl-functionalization of iron nanoparticles for tailoring the properties of Fmoc-FF-based magnetic hydrogels: interfacial design toward biocompatible materials
Open Access Paper

Comparison of magnetic nanoparticle immobilization methods using MPS and MRX

This work demonstrates the importance of choosing the proper immobilization method to provide reliable and reproducible magnetic nanoparticle reference samples with defined magnetic properties.

Graphical abstract: Comparison of magnetic nanoparticle immobilization methods using MPS and MRX
Open Access Paper

Integrating green chemistry into SPION development: a theranostic study on prostate cell models

Green-synthesized SP–Au and SP–Au–Gd nanoplatforms integrate Au-enhanced radiosensitization and Gd-driven magnetic hyperthermia with MRI capability. These multifunctional systems enable synergistic, image-guided theranostics for prostate cancer.

Graphical abstract: Integrating green chemistry into SPION development: a theranostic study on prostate cell models
Paper

Effect of synthesis method on the structural properties and magnetic behavior of LnFeO3 (Ln = La, Nd, Sm, and Gd) nanoparticles

Rare-earth orthoferrite (LnFeO3 Ln = La, Nd, Sm, Gd) nanoparticles were synthesized by thermal decomposition and sol–gel methods. The synthesis route strongly affects particle size and their structural and magnetic properties.

Graphical abstract: Effect of synthesis method on the structural properties and magnetic behavior of LnFeO3 (Ln = La, Nd, Sm, and Gd) nanoparticles
Open Access Paper

Hard meets soft: tuning binary ferrofluids

Binary ferrofluids of hard–soft magnetic nanoflowers show composition-controlled hysteresis and aggregation. Experiments and simulations reveal how soft particles suppress chain growth while preserving heating-relevant magnetic losses.

Graphical abstract: Hard meets soft: tuning binary ferrofluids
Open Access Paper

Albumin coating of magnetic nanoparticles for imaging, tracking and delivery through biological barriers

Multiscale validation of BSA-coated magnetic nanoparticles as a theranostic system for crossing biological barriers.

Graphical abstract: Albumin coating of magnetic nanoparticles for imaging, tracking and delivery through biological barriers
Open Access Paper

SLPcalculator: a web-based tool to estimate nanoparticle heating with peak analysis and F-test

Accurately determining the Specific Loss Power (SLP) remains a major challenge in magnetic hyperthermia and photothermal heating. The SLPCalculator is an open access, easy-to-use and reliable tool for the SLP determination.

Graphical abstract: SLPcalculator: a web-based tool to estimate nanoparticle heating with peak analysis and F-test
Open Access Paper

Iron oxide nanocube assembly on silver nanowire templates to enhance magnetic hyperthermia performance

Iron oxide nanocubes are benchmark magnetic nanoparticles that efficiently convert magnetic energy into heat for hyperthermia cancer treatment, and their heating can be enhanced by assembling them into ordered structures.

Graphical abstract: Iron oxide nanocube assembly on silver nanowire templates to enhance magnetic hyperthermia performance
Open Access Paper

Magnetic resorcinol-formaldehyde supported Schiff-base/Cu as a robust and recoverable nanocatalyst for the synthesis of tetrahydrobenzo[b]pyrans

A novel magnetic RF functionalized with Schiff-base/Cu (Mag@RF/SB-Cu) nanocomposite is prepared, characterized and used as a powerful and highly recoverable nanocatalyst for the synthesis of tetrahydrobenzo[b]pyrans in water at 25 °C.

Graphical abstract: Magnetic resorcinol-formaldehyde supported Schiff-base/Cu as a robust and recoverable nanocatalyst for the synthesis of tetrahydrobenzo[b]pyrans
Open Access Paper

Endovascular administration and magnetic retention of nanocapsules for improved brain delivery in large cerebral vascular models

Endovascular brain delivery and magnetic retention of nanocapsules for improved focal delivery.

Graphical abstract: Endovascular administration and magnetic retention of nanocapsules for improved brain delivery in large cerebral vascular models
Open Access Paper

Esterification synthesis of iron oxide nanoparticle tracers for magnetic particle imaging (MPI)

Esterification of iron oleate with oleyl alcohol is an alternative synthesis method for producing iron oxide tracers for magnetic particle imaging (MPI).

Graphical abstract: Esterification synthesis of iron oxide nanoparticle tracers for magnetic particle imaging (MPI)
Open Access Paper

Size effects in magnetic separation for rapid and efficient bacteria removal

Porous magnetic nanoparticles show pronounced size-dependent effects on bacterial removal, providing guidance for designing effective magnetic adsorbents.

Graphical abstract: Size effects in magnetic separation for rapid and efficient bacteria removal
Open Access Paper

Enhancing colloidal stability of anisotropic magnetic nanodiscs through mesoporous silica and P(NIPAM/MAA) copolymer coatings

We present an optimization procedure to obtain a more stable colloidal dispersion of magnetic nanodiscs in aqueous environments. A pathway to obtain silica covered magnetite nanodiscs and their subsequent coating with a polymer is described.

Graphical abstract: Enhancing colloidal stability of anisotropic magnetic nanodiscs through mesoporous silica and P(NIPAM/MAA) copolymer coatings
Paper

Ligand-controlled Fe3O4 nanoparticles as reusable adsorbents for dye removal in the chemical recycling of coloured polyester textiles

Magnetically retrievable hydrophobic-ligand Fe3O4 nanoadsorbents rapidly decolorize PET depolymerization products, enabling recovery of high-purity monomer.

Graphical abstract: Ligand-controlled Fe3O4 nanoparticles as reusable adsorbents for dye removal in the chemical recycling of coloured polyester textiles
Paper

Magnetic nanoparticles as transducers for quick and direct virus detection in clinical samples

Innovative strategies for the rapid diagnosis of viral infections at primary medical assistance are actually of significant relevance. Images supplied by Servier Medical Art, licensed under CCBY4.0 (https://creativecommons.org/licenses/by/4.0/).

Graphical abstract: Magnetic nanoparticles as transducers for quick and direct virus detection in clinical samples
Open Access Paper

Micromagnetic structure of oxidized magnetite nanoparticles: sharp structural versus diffuse magnetic interface

The oxidation of magnetite to maghemite is a naturally occurring process that leads to the degradation of the magnetic properties of magnetite nanoparticles.

Graphical abstract: Micromagnetic structure of oxidized magnetite nanoparticles: sharp structural versus diffuse magnetic interface
Paper

Biodegradable PBAT@CoFe2O4 foils as magnetically active photothermal materials for smart surface heating

Our study is devoted to the development, physicochemical characterization, and NIR energy conversion to heat of biodegradable PBAT@CoFe2O4 composite foil fabricated via the solvent evaporation casting technique.

Graphical abstract: Biodegradable PBAT@CoFe2O4 foils as magnetically active photothermal materials for smart surface heating
Open Access Paper

Influence of coprecipitation synthesis parameters on the physicochemical properties and biological effects of iron oxide nanoparticles

Investigation of coprecipitation parameters on IONP physicochemistry and bioactivity.

Graphical abstract: Influence of coprecipitation synthesis parameters on the physicochemical properties and biological effects of iron oxide nanoparticles
Open Access Paper

Room-temperature acetone gas sensing using Sm-doped Co–Zn ferrite nanoparticles: role of mesoporosity and oxygen vacancies in enhancing sensor response

The study presents the synthesis, structural characterization, and acetone gas sensing by nanocrystalline Co–Zn–Sm ferrites (CZSmF) with the general formula Co0.7Zn0.3SmxFe2−xO4 (x = 0–0.04), synthesized via the sol–gel auto-combustion method.

Graphical abstract: Room-temperature acetone gas sensing using Sm-doped Co–Zn ferrite nanoparticles: role of mesoporosity and oxygen vacancies in enhancing sensor response
Open Access Paper

Palladium-containing magnetic UiO-66–NH2 as a highly powerful and recoverable nanocatalyst for the reduction of nitrobenzenes

A novel magnetic MCM-41@UiO-66 nanocomposite supported Schiff-base/Pd complex (Fe3O4@MCM-41@UiO-66/SB–Pd) is prepared, characterized and used as a powerful and highly recoverable nanocatalyst in the reduction of nitrobenzenes under mild conditions.

Graphical abstract: Palladium-containing magnetic UiO-66–NH2 as a highly powerful and recoverable nanocatalyst for the reduction of nitrobenzenes
Open Access Paper

Dual field magnetic separation for improved size fractionation of magnetic nanoparticles

A dual-field magnetic separation method that significantly enhances size fractionation of magnetic nanoparticles, compared to conventional gradient-based methods.

Graphical abstract: Dual field magnetic separation for improved size fractionation of magnetic nanoparticles
Open Access Paper

Polyoxazoline functionalized magnetic spinel iron oxide nanoparticles for efficient removal of pharmaceuticals and heavy metal ions from water

Novel hybrid Fe3O4 superparamagnetic nanoparticles with polyoxazoline coatings enable the selective adsorption of pollutants and heavy metals, offering a refined and versatile solution for cutting-edge water purification. Graphical abstract background via Canva.com.

Graphical abstract: Polyoxazoline functionalized magnetic spinel iron oxide nanoparticles for efficient removal of pharmaceuticals and heavy metal ions from water
Open Access Paper

Effects of static electric field and temperature on the dynamic dielectric responses of mixed oil-based and bilayer-stabilised magnetic fluids

Dissipation factor as a function of frequency for NF 4323, NF 4325, and NF 4328 magnetic fluids.

Graphical abstract: Effects of static electric field and temperature on the dynamic dielectric responses of mixed oil-based and bilayer-stabilised magnetic fluids
Open Access Paper

Proximity effects, exchange bias and magnetic relaxation in γ-Fe2O3 nanoparticles

Carbon-encapsulated γ-Fe2O3 nanoparticles (NPs) exhibit emerging magnetic proximity effects together with a robust exchange-bias.

Graphical abstract: Proximity effects, exchange bias and magnetic relaxation in γ-Fe2O3 nanoparticles
Open Access Paper

Insights into the formation of free radicals using metal ferrite nanocatalysts (MFe2O4, M = Fe, Mn, Zn, Co) prepared by a highly reproducible microwave-assisted polyol method

A microwave-assisted polyol method yielded metal ferrite nanocatalysts with >95% reproducibility. EPR analysis revealed that Mn promotes ˙OOH formation, Zn suppresses ROS formation via passivation, and acetate buffer masks radical detection.

Graphical abstract: Insights into the formation of free radicals using metal ferrite nanocatalysts (MFe2O4, M = Fe, Mn, Zn, Co) prepared by a highly reproducible microwave-assisted polyol method
Paper

Solution synthesis of antiferromagnetic manganese nanoparticles

Highly electrophilic Mn(0) nanoparticles were synthesized via an organometallic approach. Their magnetic properties indicate antiferromagnetic behaviour, while solution NMR studies unveiled the dynamic nature of weakly coordinated surface ligands.

Graphical abstract: Solution synthesis of antiferromagnetic manganese nanoparticles
Paper

A magnetic hybrid sol–gel ionic network catalyst for direct alcohol esterification under solvent-free conditions

A cross-linked magnetic acidic poly(ionic liquid) network with a high ionic content as an efficient, water-tolerant, and recyclable catalyst for direct esterification.

Graphical abstract: A magnetic hybrid sol–gel ionic network catalyst for direct alcohol esterification under solvent-free conditions
48 items

About this collection

Guest edited by Professors Nguyễn T. K. Thanh (University College London, United Kingdom), Teresa Pellegrino (Italian Institute of Technology, Italy), Ali Abou-Hassan (Sorbonne University, France), Anna Cristina S. Samia (Case Western Reserve University, United States), Olivier Sandre (University of Bordeaux, France) and  Lise-Marie Lacroix (Toulouse University, France).

Magnetic nanoparticles are a class of materials that exhibit unique superparamagnetic properties due to their nanoscale size and high surface-to-volume ratio. The synthesis of magnetic nanoparticles is central to their widespread use, with several methods developed over the years to produce them in a controlled, reproducible manner. One of the most well-known and widely adopted methods is the alkaline co-precipitation method developed by Prof. René Massart in the early 1980s. Originally conducted in water (though it can be adapted to a dispersed state in less polar media), it is a widely used, cost-effective technique for synthesizing magnetic nanoparticles, especially iron oxide (magnetite and maghemite), as well as other spinel-structured metal oxides (e.g., cobalt, manganese, and zinc ferrites). Known for its simplicity, up-scalability, and ability to relatively control particle size and magnetic properties, the Massart process is extensively employed for producing nanomaterials for in biomedical, environmental, and industrial applications due to its efficiency and versatility in producing large quantities of tailored nanoparticles.

This themed collection aims to provide a comprehensive overview of the advances in the field of magnetic nanoparticle research, by covering its different facets ranging from rational design of synthesis processes to improved properties dispersion states, and end applications. In tribute to René Massart, this collection will cover various aspects of magnetic nanoparticles. 


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