Issue 40, 2022

Post-synthetic ligand cyclization in metal–organic frameworks through functional group connection with regioisomerism

Abstract

A covalent connection between two orthogonal functional groups (–NH2 and –OH) in metal–organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66–2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66–2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.

Graphical abstract: Post-synthetic ligand cyclization in metal–organic frameworks through functional group connection with regioisomerism

Supplementary files

Article information

Article type
Communication
Submitted
20 फरवरी 2022
Accepted
06 अप्रैल 2022
First published
07 अप्रैल 2022

Chem. Commun., 2022,58, 5948-5951

Post-synthetic ligand cyclization in metal–organic frameworks through functional group connection with regioisomerism

D. Kim, H. Yoo, K. Kim, D. Kim, K. T. Kim, C. Kim, J. Y. Kim, H. R. Moon and M. Kim, Chem. Commun., 2022, 58, 5948 DOI: 10.1039/D2CC01031C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements